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Sustainable approach: Utilizing modified waste Styrofoam as an eco-friendly catalyst for dual treatment of wastewater

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Abstract

Styrofoam waste (WPS) was used to prepare a grafted polymer named WPS-g-MA that was applied as an adsorbent for Ni2+ and Cd2+. The obtained polymer–metal complexes (WPS-g-MA…M, where M = Ni or Cd) were then utilized separately as a photocatalyst to enhance the degradation of methylene blue (MB) dye. The chemical structure of the WPS-g-MA and WPS-g-MA…M was confirmed by their relative functional bands that appear at FTIR chart. Energy-dispersive X-ray (EDX) spectroscopy confirmed the formation of WPS-g-MA (the presence of oxygen) and WPS-g-MA…M (the presence of Ni/Cd). The surface morphology of the polymers was investigated by scanning electron microscope (SEM) measurements. The adsorption of Ni and Cd ions onto the WPS-g-MA surface depended on the pH of the metal ions solution as well as the WPS-g-MA dosage. The adsorption performance of WPS-g-MA was calculated and found to be 70% and 80% for Ni and Cd ions, respectively, at pH = 7. The WPS-g-MA...M was used as a heterogeneous catalyst to activate peroxymonosulfates (PMSs) for the production of the sulfate radicals (the most effective and non-selective catalyst for the oxidation of organic compounds). The WPS-g-MA...M caused enhancement of the catalytic activity of PMS (27%) for MB degradation to 100% after 120 min.

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References

  1. Bai R, Sutanto M (2002) The practice and challenges of solid waste management in Singapore. Waste Manag 22:557–567

    Article  Google Scholar 

  2. Inagaki Y, Kiuchi S (2001) Converting waste polystyrene into a polymer flocculant for wastewater treatment. J Mater Cycles Waste Manag 3:14–19

    CAS  Google Scholar 

  3. AL Andrady 2015 Plastics and environmental sustainability: fact and fiction. Wiley, New York

  4. Al-Salem SM, Lettieri P, Baeyens J (2009) Recycling and recovery routes of plastic solid waste (PSW): a review. Waste Management 29:2625–2643

    Article  CAS  Google Scholar 

  5. Wang Z, Bai R, Ting YP (2008) Conversion of waste polystyrene into porous and functionalized adsorbent and its application in humic acid removal. Ind Eng Chem Res 47:1861–1867. https://doi.org/10.1021/ie070583m

    Article  CAS  Google Scholar 

  6. El-Fawal EM, El-Shamy OAA (2019) Photodegradation enhancement of 2-chlorophenol using ZnO–CdS@CS nanocomposite under visible light. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-019-02249-y

    Article  Google Scholar 

  7. El-Dib FI, Mohamed DE, El-Shamy OAA, Mishrif MR (2019) Study the adsorption properties of magnetite nanoparticles in the presence of different synthesized surfactants for heavy metal ions removal. Egypt J Pet 20:12

    Google Scholar 

  8. El-Shamy OAA, El-Azabawy RE, El-Azabawy O (2019) Synthesis and characterization of magnetite-alginate nanoparticles for enhancement of nickel and cobalt ion adsorption from wastewater. J Nanomater 2019:12.

    Google Scholar 

  9. Nalwa HS (2001) Advanced functional molecules and polymers: electronic and photonic properties. CRC Press, Boca Raton

    Google Scholar 

  10. Prabhakaran D, Subramanian MS (2003) A new chelating sorbent for metal ion extraction under high saline conditions. Talanta 59:1227–1236

    Article  CAS  Google Scholar 

  11. Trzcinka-Ochocka M, Jakubowski M, Razniewska G, Halatek T, Gazewski A (2004) The effects of environmental cadmium exposure on kidney function: the possible influence of age. Environ Res 95:143–150

    Article  CAS  Google Scholar 

  12. Chen M, Xu P, Zeng G, Yang C, Huang D, Zhang J (2015) Bioremediation of soils contaminated with polycyclic aromatic hydrocarbons, petroleum, pesticides, chlorophenols and heavy metals by composting: applications, microbes and future research needs. Biotechnol Adv 33:745–755

    Article  CAS  Google Scholar 

  13. Nguyen TAH, Ngo HH, Guo WS, Zhang J, Liang S, Yue QY, Li Q, Nguyen TV (2013) Applicability of agricultural waste and by-products for adsorptive removal of heavy metals from wastewater. Bioresour Technol 148:574–585

    Article  CAS  Google Scholar 

  14. Nancharaiah YV, Mohan SV, Lens PNL (2015) Metals removal and recovery in bioelectrochemical systems: a review. Bioresour Technol 195:102–114

    Article  CAS  Google Scholar 

  15. El-Sharaky EA, Mishrif MR, El-Shamy OAA (2018) Synthesis and evaluation of a new trianionic surfactant for the removal of Pb(II) by flotation method. Tenside Surfactants Deterg 55:148–152. https://doi.org/10.3139/113.110545

    Article  CAS  Google Scholar 

  16. Tang W-W, Zeng G-M, Gong J-L, Liang J, Xu P, Zhang C, Huang B-B (2014) Impact of humic/fulvic acid on the removal of heavy metals from aqueous solutions using nanomaterials: a review. Sci Total Environ 468:1014–1027

    Article  Google Scholar 

  17. Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 211:317–331

    Article  Google Scholar 

  18. El Feky AA, Shalaby MN, El-Shamy OAA, Selim SA (2010) Adsorption of some surfactants onto polyvinyl alcohol as hydrophobic polymer surface. J Dispers Sci Technol 31:1091–1099

    Article  Google Scholar 

  19. El-Feky AA, Shalaby MN, El-Shamy OAA (2009) Polymers as hydrophobic adsorbent surface for some surfactants. J Dispers Sci Technol 30:445–450

    Article  CAS  Google Scholar 

  20. Abbas M, Trari M (2015) Kinetic, equilibrium and thermodynamic study on the removal of Congo Red from aqueous solutions by adsorption onto apricot stone. Process Saf Environ Prot 98:424–436

    Article  CAS  Google Scholar 

  21. Chan S-L, Tan YP, Abdullah AH, Ong S-T (2016) Equilibrium, kinetic and thermodynamic studies of a new potential biosorbent for the removal of Basic Blue 3 and Congo Red dyes: pineapple (Ananas comosus) plant stem. J Taiwan Inst Chem Eng 61:306–315

    Article  CAS  Google Scholar 

  22. Zare K, Sadegh H, Shahryari-Ghoshekandi R, Maazinejad B, Ali V, Tyagi I, Agarwal S, Gupta VK (2015) Enhanced removal of toxic Congo red dye using multi walled carbon nanotubes: kinetic, equilibrium studies and its comparison with other adsorbents. J Mol Liq 212:266–271

    Article  CAS  Google Scholar 

  23. Yehia FZ, Kandile NG, Badawi AM, Mady AH (2012) Glutamic acid modified Fenton system for degradation of BTEX contamination, CLEAN–Soil. Air Water 40:692–697

    Article  CAS  Google Scholar 

  24. Alekseeva OV, Bagrovskaya NA, Noskov AV (2016) Sorption of heavy metal ions by fullerene and polystyrene/fullerene film compositions. Prot Metals Phys Chem Surf 52:443–447

    Article  CAS  Google Scholar 

  25. Naseem K, Begum R, Wu W, Usman M, Irfan A, Al-Sehemi AG, Farooqi ZH (2019) Adsorptive removal of heavy metal ions using polystyrene-poly (N-isopropylmethacrylamide-acrylic acid) core/shell gel particles: adsorption isotherms and kinetic study. J Mol Liq 277:522–531

    Article  CAS  Google Scholar 

  26. McManamon C, Burke AM, Holmes JD, Morris MA (2012) Amine-functionalised SBA-15 of tailored pore size for heavy metal adsorption. J Colloid Interface Sci 369:330–337

    Article  CAS  Google Scholar 

  27. Peng Q, Liu Y, Zeng G, Xu W, Yang C, Zhang J (2010) Biosorption of copper (II) by immobilizing Saccharomyces cerevisiae on the surface of chitosan-coated magnetic nanoparticles from aqueous solution. J Hazard Mater 177:676–682

    Article  CAS  Google Scholar 

  28. Qin L, Yan L, Chen J, Liu T, Yu H, Du B (2016) Enhanced removal of Pb2+, Cu2+, and Cd2+ by amino-functionalized magnetite/kaolin clay. Ind Eng Chem Res 55:7344–7354

    Article  CAS  Google Scholar 

  29. Li H-M, Chen H, Shen Z-G, Lin S (2002) Preparation and characterization of maleic anhydride-functionalized syndiotactic polystyrene. Polymer 43:5455–5461

    Article  CAS  Google Scholar 

  30. Aglan RF, Hamed MM (2014) Optimization of environmental friendly process for removal of cadmium from wastewater. Russ J Appl Chem 87:373–382

    Article  CAS  Google Scholar 

  31. Soares MR, Casagrande JC, Mouta ER (2011) Nickel adsorption by variable charge soils: effect of pH and ionic strength. Braz Arch Biol Technol 54:207–220

    Article  CAS  Google Scholar 

  32. Gonte R, Balasubramanian K (2016) Heavy and toxic metal uptake by mesoporous hypercrosslinked SMA beads: isotherms and kinetics. J Saudi Chem Soc 20:S579–S590

    Article  CAS  Google Scholar 

  33. Ajmal M, Rao RAK, Anwar S, Ahmad J, Ahmad R (2003) Adsorption studies on rice husk: removal and recovery of Cd(II) from wastewater. Bioresour Technol 86:147–149

    Article  CAS  Google Scholar 

  34. Alshabanat M (2019) Removal of heavy metal ions using polystyrene nanocomposite thin films. Egypt J Chem 62:149–156

    Google Scholar 

  35. Khairy M, Zakaria W (2014) Effect of metal-doping of TiO2 nanoparticles on their photocatalytic activities toward removal of organic dyes. Egypt J Pet 23:419–426. https://doi.org/10.1016/j.ejpe.2014.09.010

    Article  Google Scholar 

  36. Ji F, Li C, Wei X, Yu J (2013) Efficient performance of porous Fe2O3in heterogeneous activation of peroxymonosulfate for decolorization of Rhodamine B. Chem Eng J 231:434–440. https://doi.org/10.1016/j.cej.2013.07.053

    Article  CAS  Google Scholar 

  37. Saputra E, Muhammad S, Sun H, Ang HM, Tade MO, Wang S (2013) Different crystallographic one-dimensional MnO2 nanomaterials and their superior performance in catalytic phenol degradation. Environ Sci Technol 47:5882–5887

    Article  CAS  Google Scholar 

  38. Chen X, Chen J, Qiao X, Wang D, Cai X (2008) Performance of nano-Co3O4/peroxymonosulfate system: kinetics and mechanism study using Acid Orange 7 as a model compound. Appl Catal B Environ 80:116–121

    Article  CAS  Google Scholar 

  39. Ji F, Li C, Deng L (2011) Performance of CuO/Oxone system: Heterogeneous catalytic oxidation of phenol at ambient conditions. Chem Eng J 178:239–243

    Article  CAS  Google Scholar 

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Acknowledgements

The author thanks Egyptian Petroleum Research Institute Central Lab.

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Authors and Affiliations

  1. Egyptian Petroleum Research Institute, Nasr City, Cairo, 11727, Egypt

    Amira E. El-Tabey, Amr H. Mady, Omnia A. A. El-Shamy & A. A. Ragab

  2. School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk, 38541, Republic of Korea

    Amr H. Mady

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  1. Amira E. El-Tabey
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  2. Amr H. Mady
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  3. Omnia A. A. El-Shamy
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  4. A. A. Ragab
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El-Tabey, A.E., Mady, A.H., El-Shamy, O.A.A. et al. Sustainable approach: Utilizing modified waste Styrofoam as an eco-friendly catalyst for dual treatment of wastewater. Polym. Bull. 78, 951–963 (2021). https://doi.org/10.1007/s00289-020-03135-1

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  • DOI: https://doi.org/10.1007/s00289-020-03135-1

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