Abstract
The paper considers multilayer composite nano-structured modified Ti-TiCN-(Ti,Al)CN coatings for metal-cutting tools. The coatings under the study have identical elemental composition (Al 30 at.%, Ti 70 at.%) and thickness (5 μm), but differ in the thicknesses of the nanolayers. The mechanical characteristics of the coatings were studied, and the tool life tests were carried out for carbide tools with the above coatings for dry turning of steel C45 at v c = 300, 350, and 400 m/min. Microstructural studies (using SEM) of the nature of wear and failure of metal-cutting tools with the coatings under study were conducted. It was found that, with the same strength of adhesion bond to the substrate, a coating with thicker sub-nanolayers has a greater tendency toward interlayer and inter-sublayer delamination. A tool with a coating characterized by a lower thickness of sub-nanolayers showed the longest tool life at all cutting speeds.
Similar content being viewed by others
References
A.S. Vereschaka, Working capacity of the cutting tool with wear resistant coatings. Mashinostroenie. Moscow, 1993 (in Russian).
Bouzakis KD, Michailidis N, Skordaris G, Bouzakis E, Biermann D, M’Saoubi R (2012) Cutting with coated tools: coating technologies, characterization methods and performance optimization. CIRP Ann Manuf Technol 61:703–723. https://doi.org/10.1016/j.cirp.2012.05.006
Tkadletz M, Schalk N, Daniel R, Keckes J, Czettl C, Mitterer C (2016) Advanced characterization methods for wear resistant hard coatings: a review on recent progress. Surf Coatings Technol 285:31–46. https://doi.org/10.1016/j.surfcoat.2015.11.016
Baker MA, Klose S, Rebholz C, Leyland A, Matthews A (2002) Evaluating the microstructure and performance of nanocomposite PVD TiAlBN coatings. Surf.Coat.Technol. 151–152:338–343
Skordaris G, Bouzakis K-D, Charalampous P, Bouzakis E, Paraskevopoulou R, Lemmer O, Bolz S (2014) Brittleness and fatigue effect of mono- and multi-layer PVD films on the cutting performance of coated cemented carbide inserts. CIRPAnn.Manuf.Technol 63:93–96
Zhang S, Sun D, Yongqing F, Hejun D (2003) Recent advances of superhard nanocomposite coatings: a review. SurfCoatTechnol 167:113–119
Singh J, Wolfe DE (2005) Nanostructured component fabrication by electron beam-physical vapor deposition. J.Mater.Eng.Perform 14:448–459
Leyland A, Matthews A (2000) On the significance of the H/E ratio in wear control: a nano-composite coating approach to optimized tribological behavior. Wear 246:1–11
Vereschaka AA, Volosova MA, Grigoriev SN, Vereschaka AS (2013) Development of wear-resistant complex for high-speed steel tool when using process of combined cathodic vacuum arc deposition, in. Procedia CIRP 9:8–12. https://doi.org/10.1016/j.procir.2013.06.159
Vereschaka A, Volosova MA, Batako AD, Vereshchaka AS, Mokritskii BY (2016) Development of wear-resistant coatings compounds for high-speed steel tool using a combined cathodic vacuum arc deposition. Int J Adv Manuf Technol 84:1471–1482. https://doi.org/10.1007/s00170-015-7808-5.
Vereschaka AA, Vereschaka AS, Batako AD, Hojaev OK, Mokritskii BY (2016) Development and research of nanostructured multilayer composite coatings for tungsten-free carbides with extended area of technological applications. Int J Adv Manuf Technol 87:3449–3457. https://doi.org/10.1007/s00170-016-8739-5
Vereshchaka AA, Vereshchaka AS, Mgaloblishvili O, Morgan MN, Batako AD (2014) Nano-scale multilayered-composite coatings for the cutting tools. Int J Adv Manuf Technol 72(1):303–317. https://doi.org/10.1007/s00170-014-5673-2
Vereschaka AA, Vereschaka AS, Bublikov JI, Aksenenko AY, Sitnikov NN (2016) Study of properties of nanostructured multilayer composite coatings of Ti-TiN-(TiCrAl)N and Zr-ZrN-(ZrNbCrAl)N. J Nano Res 40:90–98. https://doi.org/10.4028/www.scientific.net/JNanoR.40.90
Volkhonskii AO, Vereshchaka AA, Blinkov IV, Vereshchaka AS, BatakoA AD (2016) Filtered cathodic vacuum arc deposition of nano-layered composite coatings for machining hard-to-cut materials. Int J Adv Manuf Technol 84:1647–1660. https://doi.org/10.1007/s00170-015-7821-8
Hovsepian PE, Lewis DB, Luo Q, Munz W-D, Mayrhofer PH, Mitterer C, Zhou Z, Rainforth WM (2005) TiAlN based nanoscale multilayer coatings designed to adapt their tribological properties at elevated temperatures. Thin Solid Films 485:160–168
M.Antonov,I.Hussainova,F.Sergejev,P.Kulu,A.Gregor (2009) Assessment of gradient and nanogradient PVD coatings behavior under erosive, abrasive and impact wear conditions. Wear 267:898–906
Vereschaka AA, Grigoriev SN (2017) Study of cracking mechanisms in multilayer composite nano-structured coatings. Wear 378-379:43–57. https://doi.org/10.1016/j.wear.2017.01.101
Vereschaka AA, Vereschaka AS, Batako AD, Hojaev OKH, Mokritskii BY (2016) Development and research of nanostructured multilayer composite coatings for tungsten-free carbides with extended area of technological applications. Int J Adv Manuf Technol 87:3449–3457
Vereschaka AA, Vereschaka AS, Bublikov JI, Aksenenko AY, Sitnikov NN (2016) Study of properties of nanostructured multilayer composite coatings of Ti-TiN-(TiCrAl)N and Zr-ZrN-(ZrNbCrAl)N. J. Nano Res 40:90–98
Vereschaka AA, Grigoriev SN, Sitnikov NN, Batako ADL (2017) Delamination and longitudinal cracking in multi-layered composite nano-structured coatings and their influence on cutting tool life. Wear 390–391:209–219. https://doi.org/10.1016/j.wear.2017.07.021
Zeng Y, Qiu Y, Mao X, Tan S, Tan Z, Zhang X, Chen J, Jiang J (2015) Superhard TiAlCN coatings prepared by radio frequency magnetron sputtering, Thin Solid Films 584:283–288. https://doi.org/10.1016/j.tsf.2015.02.068.
PalDey S, Deevi SC (2003) Single layer and multilayer wear resistant coatings of (Ti, Al)N: a review. Mater Sci Eng A 3(42):58
Zhang X, Jiang JQ, Zeng YQ, Lin JL, Wang F, Moore JJ (2008) Effect of carbon on TiAlCN coatings deposited by reactive magnetron sputtering. Surf Coat Technol 203:594. https://doi.org/10.1016/j.surfcoat.2008.06.175
Lackner JM, Waldhauser W, Ebner R, Bakker RJ, Schoberl T, Major B (2004) Room temperature pulsed laser deposited (Ti, Al)CxN1− x coatings—chemical, structural, mechanical and tribological properties. Thin Solid Films 468:125
Shieh J, Hon MH (2002) Plasma-enhanced chemical-vapor deposition of titanium aluminum carbonitride/amorphous-carbon nanocomposite thin films. J Vac Sci Technol A 20:87
Stueber M, Barna PB, Simmonds MC, Albers U, Leiste H, Ziebert C, Holleck H, Kovács A, Hovsepian P, Gee I (2005) Constitution and microstructure of magnetron sputtered nanocomposite coatings in the system Ti–Al–N–C. Thin Solid Films 493:104
Choe HJ, Kwon SH, Lee JJ (2013) Tribological properties and thermal stability of TiAlCN coatings deposited by ICP-assisted sputtering. Surf Coat Technol 228:282. https://doi.org/10.1016/j.surfcoat.2013.04.041
Köpf A, Keckes J, Todt J, Pitonak R, Weissenbacher R (2017) Nanostructured coatings for tooling applications. Int. J. Refractory Metals Hard Mater 62:219–224
Jambu J, Latha S, Bera P, Hosakoppa N, Barshilia H (2016) Optimization of process parameters to achieve spectrally selective TiAlC/TiAlCN/TiAlSiCN/TiAlSiCO/TiAlSiO high temperature solar absorber coating. Sol Energy 139:58–67
Hovsepian PE, Ehiasarian AP, Deeming A, Schimpf C (2008) Novel TiAlCN/VCN nanoscale multilayer PVD coatings deposited by the combined high-power impulse magnetron sputtering/unbalanced magnetron sputtering (HIPIMS/UBM) technology. Vacuum 82:1312–1317. https://doi.org/10.1016/j.vacuum.2008.03.064
W. Hume-Rothery, Atomic theory for students of metallurgy, The Institute of Metals, London, 1969 (fifth reprint).
Oliver WC, Pharr GM (1992) An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation. J. Mater. Res 7:1564–1583
Faga MG, Gautier G, Calzavarini R, Perucca M, Boot EA, Cartasegna F, Settineri L (2007) AlSiTiN nanocomposite coatings developed via Arc Cathodic PVD: evaluation of wear resistance via tribological analysis and high speed machining operations. Wear 263:1306–1314. https://doi.org/10.1016/j.wear.2007.01.109
Skordaris G, Bouzakis K-D, Charalampous P, Bouzakis E, Paraskevopoulou R, Lemmer O, Bolz S (2014) Brittleness and fatigue effect of mono- and multi-layer PVD films on the cutting performance of coated cemented carbide inserts. CIRP Annals – Manu Technol 63:93–96
Acknowledgments
The authors are very grateful to the late Professor Anatoly Stepanovich Vereschaka of Moscow State Technological University STANKIN for his valuable contributions to this work. He is remembered with affection by the authors and by all those who enjoyed and were touched by his company during his lifetime.
Funding
This study was supported by the Mimistry of Education and Science of Russian Federation (leading researchers, 16.9575.2017/6.7.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Vereschaka, A.A., Bublikov, J.I., Sitnikov, N.N. et al. Influence of nanolayer thickness on the performance properties of multilayer composite nano-structured modified coatings for metal-cutting tools. Int J Adv Manuf Technol 95, 2625–2640 (2018). https://doi.org/10.1007/s00170-017-1325-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00170-017-1325-7