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Selective suspension of single layer graphene mechanochemically exfoliated from carbon nanofibres

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Abstract

This paper presents the first report of the successful ball-milling exfoliation of graphitic filaments (GANF® carbon nanofibres) into single layer graphene. The addition of small amounts of solvent during the milling process makes it possible to enhance the intercalation of the exfoliating agent (melamine) between the graphene layers, thus promoting exceptional exfoliation. Advantage has also been taken of the fact that the Hansen solubility parameters of graphene are different from those of carbon fibres, which allows single and few-layer graphene to be suspended in a particular solvent, thus discriminating them from poorly exfoliated carbon nanofibres.

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Authors and Affiliations

  1. Departamento de Química Orgánica, Facultad de Ciencias y Tecnologías Químicas-IRICA, Universidad de Castilla-La Mancha, 13071, Ciudad Real, Spain

    Antonio Esaú Del Rio-Castillo, Enrique Díez-Barra & Ester Vázquez

  2. Grupo Antolín Ingeniería, S.A. Burgos, E09007, Spain

    César Merino

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  1. Antonio Esaú Del Rio-Castillo
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  2. César Merino
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  3. Enrique Díez-Barra
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Correspondence to Ester Vázquez.

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Del Rio-Castillo, A.E., Merino, C., Díez-Barra, E. et al. Selective suspension of single layer graphene mechanochemically exfoliated from carbon nanofibres. Nano Res. 7, 963–972 (2014). https://doi.org/10.1007/s12274-014-0457-4

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  • DOI: https://doi.org/10.1007/s12274-014-0457-4

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