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Effect of Lipids on the Stability of Natural Rubber Latex and Tensile Properties of its Films

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Abstract

Lipids extracted from natural rubber latex using chloroform/methanol and their hydrolysis products were analysed by gas chromatography-mass spectrometry. The main long chain fatty acids are a result of hydrolysing phospholipids in lipids. The content of each fatty acid increased as the storage time of natural rubber latex was increased and the total contents of unsaturated fatty acids were higher than those of saturated ones. Phospholipids increased the mechanical stability time of concentrated natural rubber latex. The rate of phospholipids hydrolysis increased with ammonia content in the latex. The mechanical stability time, tensile strength and retention of the tensile strength of the aged films increased with phospholipids content. The effect of phospholipids on the elongation at break of the films however was not significant.

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References

  1. TOKI, S. (2014) TheEffectof Strain-Induced Crystallization (SIC) on the Physical Properties of Natural Rubber (NR). Chem. Manuf. Appl. Nat. Rubber, 135–167.

    Chapter  Google Scholar 

  2. CHEN, Q.Z., LIANG, S.L. AND THOUAS, G.A. (2013) Elastomeric Biomaterials for Tissue Engineering. Prog. Polym. Sci., 38(3–4), 584–671.

    Article  CAS  Google Scholar 

  3. SILER, D.J. AND CORNISH, K. (1995) Measurement of Protein in Natural Rubber Latex. Anal. Biochem., 229(2), 278–281.

    Article  CAS  Google Scholar 

  4. YIP, E., SCA, D. AND CACIOLI, P. (2002) The Manufacture of Gloves from Natural Rubber Latex. J. Allergy Clin. Immunol 110(2), S3–S14.

    Article  CAS  Google Scholar 

  5. FARNHAM, J.J., TOMAZIC-JEZIC, V.J. AND STRATMEYER, M.E. (2002) Regulatory Initiatives for Natural Latex Allergy: US Perspectives. Methods, 27(1), 87–92.

    Article  CAS  Google Scholar 

  6. SHTMAMURA, Y. (1992) Development of Optical Laser Balloon and Drainage from Radiation Vulcanized Natural Rubber Latex. Int. J. Radial Appl. Instrum., 39(6), 505–507.

    Google Scholar 

  7. MANSHOL, W. AND ZIN, B.W. (1998) Semi Industrial Scale RVNRL Preparation, Products Manufacturing and Properties. Radiat. Phys. Chem., 52(1–6), 611–616.

    Google Scholar 

  8. ODOZI, T.O. AND OTAIGBE, J.O.E. (1987) Stoved Paint from Epoxidised Natural Rubber (Hevea brasiliensis) Waste-Natural Rubber Thread. Biol. Waste., 19(2), 153–156.

    Article  CAS  Google Scholar 

  9. OLIVEIRA SALMAZO, L., LOPEZ GIL, A., SILVA BELLUCCI, F., JOB, A.E. AND RODRIGUEZ PEREZ, M.A. (2016) Natural Rubber Foams with Anisotropic Cellular Structures: Mechanical Properties and Modeling. Ind. Crop. Prod, 80, 26–35.

    Article  CAS  Google Scholar 

  10. NOR, H.M. AND EBDON J.R. (1998) Telechelic Liquid Natural Rubber: A Review. Prog. Polym. Sci., 23(2), 143–177.

    Article  CAS  Google Scholar 

  11. LIAO, X., WU, C., LIAO, S. AND CHEN, R. (2011) Research Progress of Components and Properties of Natural Rubber Latex on Tapping System. Chinese Agr. Sci. Bull., 27(10), 8–11.

    Google Scholar 

  12. LI, P. (2004) Effect of Excess-Stimulation Tapping on the Properties of Natural Rubber Latex and its Vulcanized Films. Hainan: South China University of Tropical Agriculture, 15–39

    Google Scholar 

  13. CHEN, S.F. ANDNG, C.S. (1984) The Natural Higher Fatty Acid Soaps in Natural Rubber Latex and Their Effect on the Mechanical Stability of the Latex. Rubber Chem. Technol., 57(2), 243–253.

    Article  CAS  Google Scholar 

  14. PENDLE, T.D. AND GORTON, A.D.T. (1978) The Mechanical Stability of Natural Rubber Latexes. Rubber Chem. Technol., 51(5), 986–1005.

    Article  CAS  Google Scholar 

  15. MOOIBROEK, H. AND CORNISH, K. (2000) Alternative Sources of Natural Rubber. Appl. Microbiol. Biotechnol, 53(4), 355–365.

    Article  CAS  Google Scholar 

  16. SANSATSADEEKUL, J., SAKDAPIPANICH, J. AND ROJRUTHAI, P. (2011) Characterization of Associated Proteins and Phospholipids in Natural Rubber Latex. J. Biosci. Bioeng., 111(6), 628–634.

    Article  CAS  Google Scholar 

  17. SANTIPANUSOPON, S. AND RIYAJAN, S.A. (2009) Effect of Field Natural Rubber Latex with Different Ammonia Contents and Storage Period on Physical Properties of Latex Concentrate, Stability of Skim Latex and Dipped Film. Phys. Procedia, 2(1), 127–134.

    Article  CAS  Google Scholar 

  18. NAWAMAWAT, K., SAKDAPIPANICH, J. AND CHEE, C.H. (2011) Surface Nanostructure of Hevea brasiliensis Natural Rubber Latex Particles. Colloid Surface A, 390(1–3), 157–166.

    Article  CAS  Google Scholar 

  19. HASMA, H. (1984) Lipids in the Latex and Rubber of Hevea brasiliensis and their Effect on Some Properties of Natural Rubber. PhD Thesis for University of Ghent. Ghent: University of Ghent.

    Google Scholar 

  20. KAWAHARA, S., KAKUBO, T., SAKDAPIPANICH, I.T., ISONO, Y. AND TANAKA, Y. (2004) Characterization of Fatty Acids Linked to Natural Rubber-Role of Linked Fatty Acids on Crystallization of the Rubber. Polym., 41(20), 7483–7488.

    Article  Google Scholar 

  21. CHEN, S.F. ANDNG, C.S. (1984) The Natural Higher Fatty Acid Soaps in Natural Rubber Latex and their Effect on the Mechanical Stability of the Latex. Rubber Chem. Technol., 57(2), 243–253.

    Article  CAS  Google Scholar 

  22. LIENGPRAYOON, S., CHAIYUT, J. AND SRIROTH, K. (2013) Lipid Compositions of Latex and Sheet Rubber from Hevea brasiliensis Depend on Clonal Origin. Eur J. Lipid Sci. Technol., 115, 1021–1031.

    Article  CAS  Google Scholar 

  23. CHRISTIE, W.W. (2003) Lipid Analysis-Isolation, Separation, Identification and Structural Analysis of Lipids. Bridgewater, England: The Oily Press, 3–36.

    Google Scholar 

  24. LIENGPRAYOON, S., BONFILS, F. AND JEROME S.B. (2008) Development of a New Procedure for Lipid Extraction from Hevea brasiliensis Natural Rubber. Eur. J. Lipid Sci. Technol., 110(6), 563–569.

    Article  CAS  Google Scholar 

  25. BONFILS, F., EHABE, E.E. AND AYMARD, C. (2007) Enhanced Solvent Extraction of Polar Lipids Associated with Rubber Particles from Hevea Brasiliensis. Phytochem. Anal., 18, 103–108.

    Article  CAS  Google Scholar 

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Yu, H., Wang, Q., Li, J. et al. Effect of Lipids on the Stability of Natural Rubber Latex and Tensile Properties of its Films. J Rubber Res 20, 213–222 (2017). https://doi.org/10.1007/BF03449153

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  • DOI: https://doi.org/10.1007/BF03449153

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