Abstract
In this study, natural rubber latex was prevulcanised at two different temperatures i.e. room temperature (PVRT) and at 60°C (PV60). Mechanical properties of the dried films were measured. The effect of different sulphur levels on mechanical properties of the films were evaluated. The tensile modulus at 300 % elongation (M300) increased when sulphur levels rose from 0.25 p.h.r. to 0.75 p.h.r. and 1.50 p.h.r. However, when the sulphur level rose to 2.00 p.h.r. there was no further increase in tensile modulus of both PVRT and PV60 films. An increase in sulphur level resulted in better tensile strength of the films. Conversely, tensile strength of the films can be influenced by either prevulcanisation and drying processes or the leaching treatment. In this study, transmission electron microscopy was used to visualise the nature of crosslinking in the films where, homogenous intra-particle crosslinked regions were observed in each rubber particle. It is found that, PVRT films possess higher inter-particle crosslink density compared to PV60 films, which is believed to enhance tensile strength. The sulphur-probe treatment indicated that, most of the inter-particle crosslinks are poly-sulphidic crosslinks.
Similar content being viewed by others
References
LOH, A. C. P. (1982)Further Investigations of the Prevulcanisation of Natural Rubber Latex. Master Thesis, London: The North London Polytechnic.
CHONG, K. L. (1977) The Chemistry of Sulphur Vulcanisation of Natural Rubber Latex. PhD thesis, London: The North London Polytechnic.
MA’ZPAM, M. S. (1989) Peroxide Prevulcanisation of Natural Rubber Latex. PhD thesis, London: The North London Polytechnic.
BLACKLEY, D. C. (1997) Polymer Lattices Science and Technology: Volume 2 Types of Latices (2nd ed.) 441–509. London: Chapman and Hall.
AMIR HASHIM, M. Y. and MORRIS, M. D. (1999) NR Latex Vulcanisation - and Postvulcanisation of Dipped NR Latex Films. J. Rubb. Res., 2(2), 78–87.
ABI SANTHOSH, A., KURUVILA, J. and SABU, T. (2005) Recent Development in Crosslinking of Elastomers. Rubb. Chem. Technol., 78(3), 458–488.
SASIDHARAN, K. K., JOSEPH, R, PALATY, S., GOPALAKRISHNAN, K. S, RAJAMMAL, G. and PILLAI, P. V. (2005) Effect of the Vulcanisation Time and Storage on the Stability and Physical Properties of Sulfur-Prevulcanised Natural Rubber Latex. J. App. Polym. Sc., 97(5), 1804–1811.
JOBISH, J., CHAROEN, N., ANOMA, T and PAIROTE, K. (2012) Method to Vulcanise Natural Rubber from Medium Ammonia Latex by using Glutaraldehyde. Rubb. Chem. Technol., 85(4), 565–575.
DAVIES, R. T. and GAZELEY, K. F. (1993) Peroxide Prevulcanisation of Natural Rubber Latex with T-Butyl Hydroperoxide. J. Rubb. Res., 8(3), 176–189.
COOK, S., CUDBY, P. E. R, DAVIES, R. T. and MORRIS, M. D. (1997) The Microstructure of Natural Rubber Latex Films. Rubb. Chem. Technol., 70(4), 549–559.
ROSLIM, R., JEFRI, J., MANROSHAN, S. and AMIR HASHIM, M. Y (2014) Physical Properties and Fatigue Life-Cycles of Natural Rubber Latex Gloves. Adv. Environ. Biol, 8(8), 2714–2722.
TINKER, A. J. and JONES, K. P. (1998) Blends of Natural Rubber: Novel Techniques for Belnding with Specialty Polymers. 21–39. London: Chapman & Hall.
ASRUL, M., DAVIES, R.T. and IKRAM, A. (2003) Visualisation of the Network Structure in Some Environmentally Degraded Natural Rubber Gloves. J. Rubb. Res., 6(2), 84–93.
DAZYLAH, D., MA’ZAM, M. S. and AMIR HASHIM, M. Y. (2007) Changes in the Micro-Structure and Tensile Properties of Peroxide Prevulcanised Natural Rubber Latex Films During Thermal Oxidative Ageing. J. Rubb. Res., 10(4), 222–234.
AMIR HASHIM, M. Y., MORRIS, M. D., O’BRIEN, M. G. and FARID, A. S. (1998) Effect of Leaching and Humidity on Prevulcanised NR Latex Films. Rubb. Chem. Technol., 70(4), 1–12.
PENDLE, T. D. (1992) Prevucanized Natural Rubber Latex: Its Important to the Industry and Its Future Prospects. Paper Presented at the Symposium on Natural and Synthetic Latices, Ohio: University of Akron.
ROSLIM, R. (2015) Characterising Physical Properties and Morphological Structures of Peroxide-Vulcanised and Sulphur-Vulcanised Natural Rubber Latex Films. Master Thesis, Malaysia: Universiti Teknologi MARA.
FLORY, P. J., and REHNER, J. (1943) Statistical Mechanics Of Cross-linked Polymer Networks. Part I: Rubber-like Elasticity. J. Chem. Phys., 11, 512–526.
INTERNATIONAL ORGANIZATION FOR STANDARDIZATION (2005) ISO 37: Rubber, Vulcanised or Thermoplastic Determination of Tensile Stress Strain Properties. Geneva, Switzerland: International Organization for Standardisation.
ZAHARAH, W. (1998) Potential for Process Improvement of the Rubber Glove Manufacturing Process - An Industrial Case Study. PhD Thesis, England: Newcastle University.
ROSLIM, R. and AMIR HASHIM, M. Y (2010) Effect of Filler on Physical Properties and Surface Morphology of Natural Rubber Latex Films. J. Rubb. Res., 13(2), 125–138.
PORTER, M. R. and WONG, W. S. (1989) Factors Influencing the Strength Properties of Prevulcanised and Postvulcanised Latex Films and of Bulk Rubber Vulcanisates. Paper presented at the Polymer Latex III International Conference, London.
CAMPBELL, D. S., CHAPMAN, A. V, GODCHILD, I. R. and FULTON, W. S. (1992) Experimental Determination of the Mooney-Rivlin Constant for Natural Rubber Vulcanisates. J. Rubb. Res., 7(3), 168–180.
CAMPBELL, D. S. and CHAPMAN, A. V. (1990) Relationships Between Structure and Performance of Vulcanisates. J. Rubb. Res., 5(4), 246–258.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Roslim, R., Tan, K.S. & Jefri, J. Study on Morphological Structures and Mechanical Properties of Natural Rubber Latex Films Prepared at Different Prevulcanisation and Drying Temperatures. J Rubber Res 21, 1–16 (2018). https://doi.org/10.1007/BF03449158
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03449158