Skip to main content
Log in

EPR spectra of C60 anions

  • Published:
Applied Magnetic Resonance Aims and scope Submit manuscript

Abstract

The broad and sharp EPR signals observed in spectra of C60 and C 3−60 are summarized and proposed assignments are discussed. The sharp signals in samples of C 2−60 are reviewed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Bochvar D.A., Gal’pern E.G.: Dokl. Akad. Nauk SSSR209, 610 (1973)

    Google Scholar 

  2. Haddon R.C., Brus L.E., Raghavachari K: Chem. Phys. Lett.125, 459 (1986)

    Article  ADS  Google Scholar 

  3. Haymet A.D.J.: Chem. Phys. Lett.122, 421 (1985)

    Article  ADS  Google Scholar 

  4. Disch R.L., Schulman J.M.: Chem. Phys. Lett.125, 465 (1986)

    Article  ADS  Google Scholar 

  5. Koga N., Morokuma K.: Chem. Phys. Lett.196, 191 (1992)

    Article  ADS  Google Scholar 

  6. Mistra S.K., Petkov V.: Appl. Magn. Reson.8, 277 (1995)

    Article  Google Scholar 

  7. Khaled M.M., Carlin R.T., Trulove P.C., Eaton G.R., Eaton S.S.: J. Am. Chem. Soc.116, 3465 (1994)

    Article  Google Scholar 

  8. Eaton S.S., Kee A., Konda R., Eaton G.R., Trulove P.C., Carlin R.T.: J. Phys. Chem.100, 6910 (1996)

    Article  Google Scholar 

  9. Mehran F., Schell-Sorokin A.J., Brown C.A.: Phys. Rev. B46, 8579 (1992)

    Article  ADS  Google Scholar 

  10. Chen J., Huang Z.-E., Cai R.-F., Shao Q.-F., Chen S.-M., Ye H.-J.: J. C. S. Chem. Commun.1994, 2177.

  11. Jones M.T., Kadish K.M., Subramanian R., Boulas P., Vijayashree M.N.: Synth Met.70, 1341 (1995)

    Article  Google Scholar 

  12. Moriyama H., Kobayashi H., Kobayashi A., Watanabe T.: J. Am. Chem. Soc.115, 1185 (1993)

    Article  Google Scholar 

  13. Allemand P.-W., Srdanov G., Koch A., Khemani K., Wudl F., Rubin Y., Diederich F., Alvarez M.M., Anz S.J., Whetten R.L.: J. Am. Chem. Soc.113, 2780 (1991)

    Article  Google Scholar 

  14. Chen J., Cai R.-F., Huang Z.-E., Shao Q.-F., Chen S.-M.: Solid State Commun.95, 239 (1995)

    Article  ADS  Google Scholar 

  15. Pénicaud A., Peréz-Benitez A, Gleason R., Muñoz E, Escudero R.: J. Am. Chem. Soc.115, 10392 (1993)

    Article  Google Scholar 

  16. Jones M.T., Kadish K.M., Subramanian R., Boulas P., Vijayashree M.N.: Synth. Met.70, 1341 (1995)

    Article  Google Scholar 

  17. Adams G.B., Sankey O.F., Page J.B., O’Keeffe M: Chem. Phys.176, 61 (1993)

    Article  Google Scholar 

  18. Kato T., Kodama T., Shida T.: Chem. Phys. Lett.205, 405 (1993)

    Article  ADS  Google Scholar 

  19. Pénicaud A., Hsu J., Reed C.A.: J. Am. Chem. Soc.113, 6698 (1991)

    Article  Google Scholar 

  20. Stinchcombe J., Pénicaud A., Bhyrappa P., Boyd P.D.W., Reed C.A.: J. Am. Chem. Soc.115, 5212 (1993)

    Article  Google Scholar 

  21. Schell-Sorokin A.J., Mehran F., Eaton G.R., Eaton S.S., Viehbeck A., O’Toole T.R., Brown C.A.: Chem. Phys. Lett.195, 225 (1992)

    Article  ADS  Google Scholar 

  22. Regev A., Gamliel D., Meiklyar V., Michaeli S., Levanon H.: J. Phys. Chem.97, 3671 (1993)

    Article  Google Scholar 

  23. Kato T., Kodama T., Oyama M., Okazaki S., Shida T., Nakagawa T., Matsui Y., Suzuki S., Shiromaru H., Yamauchi K., Achiba Y.: Chem. Phys. Lett.186, 35 (1991)

    Article  ADS  Google Scholar 

  24. Greaney M.A., Gorun S.M.: J. Phys. Chem.95, 7142 (1991)

    Article  Google Scholar 

  25. Douthwaite R.E., Brough A.R., Green M.L.H.: J. C. S. Chem. Commun.1994, 267.

  26. Krusic P.J., Wasserman E., Parkinson B.A., Malone B., Holler E.R., Jr.: J. Am. Chem. Soc.113, 6274 (1991)

    Article  Google Scholar 

  27. Dubois D., Jones M.T., Kadish K.M.: J. Am. Chem. Soc.114, 6446 (1992)

    Article  Google Scholar 

  28. Boulas P., Kutner W., Jones M.T., Kadish K.M.: J. Phys. Chem.98, 1282 (1994)

    Article  Google Scholar 

  29. Rataiczak R.D., Koh W., Subramanian R., Jones M.T., Kadish K.M.: Synth. Met.55–57, 3137 (1993)

    Article  Google Scholar 

  30. Trulove P.C., Carlin R.T., Eaton G.R., Eaton S.S.: J. Am. Chem. Soc.117, 6265 (1995)

    Article  Google Scholar 

  31. Jones M.T., Subramanian R., Boulas P.L., Rataiczak R., Koh W., Kadish K.M. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 229. The Electrochemical Society, Inc. 1995.

  32. Boulas P., Jones M.T., Kadish K.M., Ruoff R.S., Lorents D.C., Tse D.S. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 995. The Electrochemical Society, Inc. 1995.

  33. Boulas P., Subramanian R., Kutner W., Jones M.T., Kadish K.M.: J. Electrochem. Soc.140, L130 (1993)

    Article  Google Scholar 

  34. Chen J., Shao Q.-F., Huang Z.-E., Cai R.-F., Chen S.-M.: Chem. Phys. Lett.235, 570 (1995)

    Article  ADS  Google Scholar 

  35. Kosaka M., Tanigaki K., Tanaka T., Atake T., Lappas A., Prassides K.: Phys. Rev. B51, 12018 (1995)

    Article  ADS  Google Scholar 

  36. Pekker S., Gránásy L., Oszlányi G., Bortel G., Faigel G., Tegze M., Chauvet O., Follo L., Stephens P.W., Jáanossy A. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 245. The Electrochemical Society, Inc. 1995.

  37. Lichtblau A., Ehlend A., Hausen A.-D., Kaim W.: Chem. Ber.128, 745 (1995)

    Article  Google Scholar 

  38. Hase H., Miyatake Y.: Chem. Phys. Lett.245, 95 (1995)

    Article  ADS  Google Scholar 

  39. Friedrich J., Schweitzer P., Dinse K.-P., Rapta P., Stasko A.: Appl. Magn. Reson.7, 415 (1994)

    Article  Google Scholar 

  40. Stasko A., Brezová V., Biskupic S., Dinse K.-P., Schweitzer P., Baumgarten M.: J. Phys. Chem.99, 8782 (1995)

    Article  Google Scholar 

  41. Brezová V., Stasko A., Rapta P., Domschke G., Bartl A., Dunsch L.: J. Phys. Chem.99, 44 (1995)

    Article  Google Scholar 

  42. Skiebe A., Hirsch A., Klos H., Gotschy B.: Chem. Phys. Lett.220, 138 (1994)

    Article  ADS  Google Scholar 

  43. Keizer P.N., Morton J.R., Preston K.F., Sugden A.K.: J. Phys. Chem.95, 7117 (1991)

    Article  Google Scholar 

  44. Hase H., Miyatake Y.: Chem. Phys. Lett.229, 593 (1994)

    Article  ADS  Google Scholar 

  45. Krusic P.J., Wasserman E., Keizer P.N., Morton J.R., Preston K.F.: Science254, 1183 (1991)

    Article  ADS  Google Scholar 

  46. Howard J.A., Tomietto M., Wilkinson D.A.: J. Am. Chem. Soc.113, 7870 (1991)

    Article  Google Scholar 

  47. Motyakin M.V., Spitchina N.G.: Chem. Phys. Lett.216, 63 (1993)

    Article  ADS  Google Scholar 

  48. Pace M.D., Christidis T.C., Yin J.J., Milliken J.: J. Phys. Chem.96, 6855 (1992)

    Article  Google Scholar 

  49. Howard J.A.: Chem. Phys. Lett.203, 540 (1993)

    Article  ADS  Google Scholar 

  50. Morton J.R., Preston K.F., Krusic P.J., Knight J.B., Jr.: Chem. Phys. Lett.204, 481 (1993)

    Article  ADS  Google Scholar 

  51. Boulas P., D’Souza F., Henderson C.C., Cahill P.A., Jones M.T., Kadish K.M.: J. Phys. Chem.97, 13435 (1993)

    Article  Google Scholar 

  52. Krusic P.J., Roe D.C., Johnston E., Morton J.R., Preston K.F.: J. Phys. Chem.97, 1736 (1993)

    Article  Google Scholar 

  53. Morton J.R., Preston K.F., Krusic P.J., Hill S.A., Wasserman E.: J. Am. Chem. Soc.114, 5454 (1992)

    Article  Google Scholar 

  54. Gherghel L., Baumgarten M.: Synth Met.70, 1389 (1995)

    Article  Google Scholar 

  55. Kadish K.M., Boulas P.L., Viyayshree N., Subramanian R., Gao X., Mead S., Tan Z., Jones M.T. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 213. The Electrochemichal Society, Inc. 1995.

  56. Eastman M.P., Wyse C.L., Abe J.P., Zoellner R.W., Kooser R.G.: J. Org. Chem.59, 7128 (1994)

    Article  Google Scholar 

  57. Klemt R., Roduner E., Fischer H.: J. Am. Chem. Soc.117, 8019 (1995)

    Article  Google Scholar 

  58. Curl R.F., Smalley R.E.: Science242, 1017 (1988)

    Article  ADS  Google Scholar 

  59. Juha L., Hamplová V., Engst P., Kubát P., Koudoumas E., Couris S.: J. Phys. Chem.99, 8200 (1995)

    Article  Google Scholar 

  60. Bennati M., Grupp A., Bäuerle P., Mehring M.: Chem. Phys.185, 221 (1994)

    Article  ADS  Google Scholar 

  61. Lawson, G.E., Kitaygorodskiy A., Ma B., Bunker C.A., Sun Y.-P.: J. Chem. Soc. Chem. Commun.1995, 2225.

  62. Mihailovic D., Arcon D., Venturini P., Blinc R., Omerzu A., Cevc P.: Science268, 400 (1995)

    Article  ADS  Google Scholar 

  63. Yoshizawa K., Sato T., Tanaka K., Yamabe T., Okahara K.: Chem. Phys. Lett.213, 498 (1993)

    Article  ADS  Google Scholar 

  64. Morton J.R., Preston K.F., Krusic P.J., Wasserman E.: J. Chem. Soc. Perkin Trans2, 1425 (1992)

    Google Scholar 

  65. Strout D.L., Murry R.L., Xu C., Eckhoff W.C., Odom G.K., Scuseria G.E.: Chem. Phys. Lett.214, 576 (1993)

    Article  ADS  Google Scholar 

  66. Oszlányi G., Bortel G., Faigel G., Tegze M., Gránásy L., Pekker S., Stephens P.W., Bendele G., Dinnebier R., Mihály G., Jánossy A., Chauvet O., Forró A.: Phys. Rev. B51, 12228 (1995)

    Article  ADS  Google Scholar 

  67. Heinze J., Smie A. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 1117 The Electrochemical Society, Inc. 1995.

  68. Bhyrappa P., Paul P., Stinchcombe J., Boyd P.D.W., Reed C.A.: J. Am. Chem. Soc.115, 11004 (1993)

    Article  Google Scholar 

  69. Kaneto K., Mizue M., Takashima W.: Synth. Met.55–57, 3080 (1993)

    Article  Google Scholar 

  70. Boyd P.D.W., Bhyrappa P., Paul P., Stinchcombe J., Bolskar R.D., Sun Y., Reed C.A.: J. Am. Chem. Soc.117, 2907 (1995)

    Article  Google Scholar 

  71. Trulove P.C., Carlin R.T., Eaton G.R., Eaton S.S. in: Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials (Ruoff R.S., Kadish K.M., eds.), vol. 2, p. 191. The Electrochemical Society, Inc. 1995.

  72. Wang D.M., Bramley R., Dinse K.-P.: Physica C217, 16 (1993)

    Article  ADS  Google Scholar 

  73. Jánossy A., Chauvet O., Pekker S., Cooper J.R., Forró L.: Phys. Rev. Lett.71, 1091 (1993)

    Article  ADS  Google Scholar 

  74. Bensebaa F., Xiang B., Kevan L.: J. Phys. Chem.96, 10258 (1992)

    Article  Google Scholar 

  75. Schlueter J.A., Welp U., Wang H.H., Geiser U., Williams J.M., Bauer M.J., Cho J.M., Smart J.L., Taha S.A.: Physica C216, 305 (1993)

    Article  ADS  Google Scholar 

  76. Bossard C., Rigaut S., Astruc D., Delville M.-H., Félix G., Février-Bouvier A., Amiell J., Flandrois S., Delhaès J.: J. C. S. Chem. Commun.1993, 333.

  77. Husted R., Du J.-L., Eaton G.R., Eaton S.S.: Magn. Reson. Chem.33, 566 (1995)

    Article  Google Scholar 

  78. Konda R., Du J.-L., Eaton S.S., Eaton G.R.: Appl. Magn. Reson7, 185 (1994)

    Article  Google Scholar 

  79. Du J.-L., Eaton G.R., Eaton S.S.: J. Magn. Reson.A119, 240 (1996)

    Google Scholar 

  80. Baumgarten M., Gügel, Gherghel L. Adv. Mater.5, 458 (1993)

    Article  Google Scholar 

  81. Ruebsam M., Dinse K.-P., Plueschau M., Fink J., Kraetschmer W., Fostiropoulos, Taliani C.: J. Am. Chem. Soc.114, 10059 (1992)

    Article  Google Scholar 

  82. Dubois D., Kadish K.M., Flanagan S., Haufler R.E., Chibante L.P.F., Wilson L.J.: J. Am. Chem. Soc.113, 4363 (1991)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eaton, S.S., Eaton, G.R. EPR spectra of C60 anions. Appl. Magn. Reson. 11, 155–170 (1996). https://doi.org/10.1007/BF03162051

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03162051

Keywords

Navigation