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Electron paramagnetic and muon spin resonance studies in fullerenes

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Abstract

This article reviews the various EPR (CW, pulsed and time-resolved) and μSR studies reported in C60/C70/C82 fullerenes. Different techniques for preparing paramagnetic C60/C70 species giving an EPR signal have been included. This literature survey is complete from the beginning of fullerene research (1985) up to middle 1994.

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Abbreviations

A :

hyperfine-interaction parameter

D, E :

second-order parameters of zero-field spin Hamiltonian

ΔH :

width of an EPR line

ΔH p-p :

peak-to-peak width of the first derivative EPR lineshape

FAB:

fast atom bound

ν:

microwave frequency (if the actual value is not known, the frequency band, e.g., X (≈ 9.5 GHz), Q (≈ 35 GHz), L (≈ 3 GHz) is indicated)

g :

g-factor

hfc:

hyperfine coupling

hfi:

hyperfine interactions

hfi/H:

proton hyperfine interactions

hfi/13C:

13C hyperfine interaction

hfi (C/P):

13C/31P hyperfine interaction

hfi (H/D):

proton/deuteron hyperfine interactions

hfs:

hyperfine splitting

I :

spectrum intensity

I tot :

total spectrum intensity

K :

jumping rate

PAH:

polycyclic aromatic hydrocarbon

R :

diffusion rate constant

RT:

room temperature

T :

temperature

UV:

ultraviolet

ZFS:

zero-field splitting.

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    S. K. Misra & V. Petkov

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Misra, S.K., Petkov, V. Electron paramagnetic and muon spin resonance studies in fullerenes. Appl. Magn. Reson. 8, 277–310 (1995). https://doi.org/10.1007/BF03162792

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