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Synthesis of deoxynivalenol-glucosides and their characterization using a QTrap LC-MS/MS

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Abstract

Deoxynivalenol (DON)-glucosides were successfully synthesized in a two-step reaction from 1-β-Bromo-1-deoxy-2,3,4,6-tetra-O-acetyl-α-D-gluco-pyranose and 3-Acetyl-DON or 15-Acetyl-DON. After purification of the reaction products, the mycotoxin conjugates were for the first time characterized by means of a triple quadrupole mass spectrometer in combination with a linear ion trap. Due to different fragmentation behaviour it was also possible to distinguish between the two glucosides.

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Authors and Affiliations

  1. Christian Doppler Laboratory for Mycotoxin Research, IFA-Tulln, Konrad Lorenz Str. 20, 3430, Tulln, Austria

    F. Berthiller, R. Schuhmacher, G. Buttinger & R. Krska

  2. biopure Referenzsubstanzen GmbH, Konrad Lorenz Str. 20, 3430, Tulln, Austria

    M. Freudenschuss

  3. Center of Applied Genetics, University of Agricultural Sciences, Muthgasse 18, 1190, Wien, Austria

    G. Adam

Authors
  1. F. Berthiller
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  2. R. Schuhmacher
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  3. G. Buttinger
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  4. M. Freudenschuss
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  5. G. Adam
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  6. R. Krska
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Berthiller, F., Schuhmacher, R., Buttinger, G. et al. Synthesis of deoxynivalenol-glucosides and their characterization using a QTrap LC-MS/MS. Mycotox Res 19, 47–50 (2003). https://doi.org/10.1007/BF02940092

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  • DOI: https://doi.org/10.1007/BF02940092

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