Abstract
Layered double hydroxides (LDH) with brucite like structure was modified with various anionic surfactants containing sulfonate, carboxyl, phosphonate and sulfate end group through ion-exchange method. XRD reports indicated that the sulfonate group containing surfactants led to an adsorption process whereas the sulfate, carboxyl and phosphonate group containing surfactant led to an intercalation process. This can be evidenced from the change in basal spacing of LDH. The presence of anionic surfactants in the LDH was supported by FTIR spectroscopy. The FTIR spectrum indicated that complete removal of carbonate anion from the inter layer space of LDH is very difficult. The phosphonate intercalated HT showed less thermal stability than pristine LDH.
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References
Aisawa S, Hirahara H and Narita E 2004Chem. Lett. 33 306
Arco M, Carriazo D, Martin C and Rives V 2004Inorg. Chem. 43 375
Battacharjee S and Anderson J A 2004Chem. Commun. 554
Choy J H, Jung J S, Oh J M and Han O J 2004Biomaterials 25 3059
Friedrich H B, Khan F, Singh N and Staden M 2001Synlett. 6 869
Friedrich H B, Govender M and Onani M O 2003 Chem. Commun. 2922
Greenwell C, Jones W and Coveney P V 2003J. Mol. Struct. 647 75
He L, Yin S and Sato T 2003Solid State Chem. 77 51
Isupov V P and Chupakhina L E 2001Solid State Ionics 141 231
Kakiuchi N, Nishimura T and Uemura S 2001Bull. Chem. Soc. Jpn 74 165
Kooli F, Cjisem C, Vucelic M and Jones W 1996Chem. Mater. 8 1969
Lee J H, Ree S W and Jung D Y 2003Chem. Commun. 2740
Lukashin V, Vertegel A and Tretyakov D 2003J. Nanopart. Res. 5 455
Matsushita T, Ebitani K and Kaneda K 1999Chem. Commun. 265
Pavan P C, Crepaldi E L and Valim J B 2000J. Colloid Inter. Sci. 229 346
Prevot V, Forano C and Besse P 1998Inorg. Chem. 37 4293
Xu Z P and Braterman P S 2003J. Mater. Chem. 13 268
Yuan Q, Wei M, Wang Z and Duan X 2004Clays Clay Miner. 52 40
You Y, Zhao H and Vance G F 2002J. Mater. Chem. 12 907
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Anbarasan, R., Lee, W.D. & Im, S.S. Adsorption and intercalation of anionic surfactants onto layered double hydroxides—XRD study. Bull Mater Sci 28, 145–149 (2005). https://doi.org/10.1007/BF02704234
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DOI: https://doi.org/10.1007/BF02704234