Skip to main content
Log in

A new radiometric titration method based on separation by means of ion exchange

II. The determination of zinc

  • Published:
Journal of radioanalytical chemistry Aims and scope Submit manuscript

Abstract

The determination of zinc with EDTA is chosen as an example for the earlier suggested new radio-complexometric titration procedure, in which phase separation is achieved by means of a strongly basic anion exchanger in the solution. Concentrations of zinc solutions down to 10−6 M have been determined. The reverse titration,viz. of EDTA with zinc solution, which can be used as back-titration in complexometry, is also possible. However, theoretical relations for this latter type of titration are not simple.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Heijink, H. L. Polak,J. Radioanal. Chem., 2 (1969) 235.

    Article  CAS  Google Scholar 

  2. I. M. Korenman, F. R. Sheyanova, H. M. Mezina, M. I. Ostasheva,Z. Anal. Khim., 12 (1957) 48.

    CAS  Google Scholar 

  3. H. Spitzy,Mikrochim. Acta, (1960) 789.

  4. H. Spitzy, I. Dosudil,Mikrochim. Acta, (1962) 119.

  5. J. Tölgyessy, J. Konečný, T. Braun,Nucl. Appl., 3 (1967) 383.

    Google Scholar 

  6. J. Konečný, J. Tölgyessy, T. Braun, Proc. Anal. Chem. Conf., Budapest, 1966, p.471.

  7. T. Braun, I. Maxim, I. Galateanu,Nature, 182 (1958) 936.

    Article  CAS  Google Scholar 

  8. T. Braun,Acta Chim. Acad. Sci. Hung., 41 (1964) 199.

    CAS  Google Scholar 

  9. F. Nelson, R. A. Day Jr., K. A. Kraus,J. Inorg. Nucl. Chem., 15 (1960) 140.

    Article  CAS  Google Scholar 

  10. K. A. Kraus, F. Nelson, The Structure of Electrolytic Solutions, Chapt. 23, J. Wiley, New York, 1949.

    Google Scholar 

  11. R. M. Wheaton, W. C. Bauman,Ind. Eng. Chem., 43 (1951) 43.

    Article  Google Scholar 

  12. A. Heijink, H. L. Polak, To be published.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Heijink, A., Polak, H.L. A new radiometric titration method based on separation by means of ion exchange. J. Radioanal. Chem. 3, 359–368 (1969). https://doi.org/10.1007/BF02513779

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02513779

Keywords

Navigation