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A New Radiometric Titration Method Based on Separation by Means of Ion Exchange, I

Mathematical Expressions for the Titration Curves in Complexometry and Oxidimetry

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Abstract

A new radiometric titration procedure is proposed, which is based on phase separation by means of an ion exchanger in the solution. The method can be applied in both complexometry and oxidimetry. A mathematical expression has been derived for the titration curves in both cases. In complexometry, a straight line is possible depending on the concentration, the mass-distribution coefficient and the complex constant, while the titration curve in oxidimetry should always be a straight line.

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References

  1. T. Braun, J. Tölgyessy, Radiometric Titrations, Pergamon Press, London, 1967.

    Google Scholar 

  2. R. R. Ruch, J. R. De Voe,Anal. Chem., 39 (1967) 1333.

    Article  CAS  Google Scholar 

  3. E. Schumacher, W. Friedli,Helv. Chim. Acta, 43 (1964) 1013.

    Article  Google Scholar 

  4. J. Starý, J. Růžička, A. Zeman,Talanta, 11 (1964) 481.

    Article  Google Scholar 

  5. J. Konečny, J. Tölgyessy, T. Braun,Proc. Anal. Chem. Conf., Budapest, 1966, p. 471.

  6. K. A. Kraus, F. Nelson, The Structure of Electrolytic Solutions, Chapter 23, J. Wiley, New York, 1949.

    Google Scholar 

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Authors and Affiliations

  1. Laboratory for Analytical Chemistry, University of Amsterdam, Amsterdam, The Netherlands

    A. Heijink & H. L. Polak

Authors
  1. A. Heijink
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  2. H. L. Polak
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Heijink, A., Polak, H.L. A New Radiometric Titration Method Based on Separation by Means of Ion Exchange, I. J. Radioanal. Chem. 2, 235–241 (1969). https://doi.org/10.1007/BF02513735

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  • DOI: https://doi.org/10.1007/BF02513735

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