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Structure and acid-basic properties of the surface of titanium oxides modified by phosphorus and aluminum and prepared by the alkoxo method

1. Structural organization of modified titanate systems

  • General and Inorganic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

An alkoxo method for the preparatio of single-phase titanium oxides modified by phosphorus and aluminum is proposed and the mechanism of oxide formation is investigated. Structural studies showed that the sizes of the anatase microcrystallite grains and mesopores in the systems are characterized by a uniform distribution. The nature of the modifying agent and the conditions of synthesis influence the interatomic distances and the dimension ofc, the tetragonal unit cell constant of anatase.

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References

  1. A. Corma, M. I. Juan-Rajadell, J. M. Lopez-Nieto, A. Martinez, and C. Martinez,Appl. Catal., A, 1994,3 175.

    Article  Google Scholar 

  2. A. E. Kapustin,Usp. Khim., 1991,60, 2685, [Russ. Chem. Rev., 1991,60 (Engl. Transl.)].

    CAS  Google Scholar 

  3. A. Corma,Chem. Rev., 1995,95, 559.

    Article  CAS  Google Scholar 

  4. V. F. Shvets,Inzhenerno-khimicheskaya nauka dlya peredovykh tekhnologii [Chemical Engineering Science for Advanced Technologies]. Tr. Tre'ei Sessii Kazan', May 26–30. 1997, Ed. V. A. Makhlin, Kazan', 1997, p. 163.

  5. R. Winnerberg, M. A. Pradera, and J. A. Navio,Langmuir, 1997,13, 2373.

    Article  Google Scholar 

  6. Yu. V. Maksimov, M. V. Tsodikov, O. G. Ellert, and V. V. Matveev,J. Catalysis, 1994,148, 119.

    Article  CAS  Google Scholar 

  7. M. V. Tsodikov, V. Ya. Kugel, E. V. Slivinskii, G. N. Bondarenko, Yu. V. Maksimov, M. A. Alvarez, M. C. Hidalgo and J. A. Navio,Appl. Catal., A: General, 2000.193, 237.

    Article  CAS  Google Scholar 

  8. B. F. Ormont,Struktury neorganicheskikh soedinenii [Structure of Inorganic Compounds], Gostekhteorizdat, Moscow. 1950, p. 458 (in Russian).

    Google Scholar 

  9. S. S. Gorelik, L. N. Rastorguev, and Yu. A. Skakov,Rentgenograficheskii i elektronoopticheskii analiz [X-Ray Diffraction and Electrooptical Analysis], Metallurgiya, Moscow. 1970, p. 83; p. 145.

    Google Scholar 

  10. J. L. Hebrard, P. Nortier, M. Pijolab, and M. Soustelle,J. Am. Ceram. Soc., 1990,73, 79.

    Article  CAS  Google Scholar 

  11. D. I. Kochubei,EXAFS-Spektroskopiya katalizatorov [EXAFS Spectroscopy of Catalysts] Nauka, Novosibirsk, 1992. 355pp.

    Google Scholar 

  12. N. Binsted, J. V. Campbell, S. J. Gurman, and P. C. Stephenson,SERC Daresbury Laboratory EXCURV92 Program, 1991.

  13. M. V. Tsodikov, O. V. Bukhtenko, O. G. Ellert, V. M. Sheherbakov, and D. I. Kochubey.Mater. Sci., 1995,30, 1087.

    Article  CAS  Google Scholar 

  14. S. J. Gregg and K. S. W. Sing,Adsorbtion, Surface Area and Porosity, Academic Press, London, 1982.

    Google Scholar 

  15. Joint Committee on Powder Diffraction Standards, 1995. Card No. 21-1272.

  16. Inorganic Chemistry. Principles and Elements, Cornell University. W. A. Benjamin. Inc., New York-Amsterdam, 1965.

  17. R. Sh. Mikhail, S. Brunaucr, and E. E. Bodor,J. Colloid Interface Sci., 1968,26, 45;26, 54.

    Article  CAS  Google Scholar 

  18. A. F. Bol'shakov, N. V. Variamov, and A. O. Dmitrienko,Rentgenofazovyi analiz materialov elektronnoi tekhniki [X-Ray Diffraction Analysis of Material for Electronics], Izd-vo Saratov. Univ., Saratov, 1990, 162 pp. (in Russian).

    Google Scholar 

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117915, Moscow, Russian Federation

    M. V. Tsodikov, O. V. Bukhtenko, E. V. Slivinskii & L. N. Slastikhina

  2. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation

    A. M. Voloshchuk

  3. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 6 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. V. Kriventsov

  4. Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    L. E. Kitaev

Authors
  1. M. V. Tsodikov
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  2. O. V. Bukhtenko
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  3. E. V. Slivinskii
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  4. L. N. Slastikhina
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  5. A. M. Voloshchuk
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  6. V. V. Kriventsov
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  7. L. E. Kitaev
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Additional information

Published inIzvestiya Akademiii Nauk. seriya Khimicheskaya, No. 11, pp 1829–1834, November, 2000.

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Tsodikov, M.V., Bukhtenko, O.V., Slivinskii, E.V. et al. Structure and acid-basic properties of the surface of titanium oxides modified by phosphorus and aluminum and prepared by the alkoxo method. Russ Chem Bull 49, 1803–1807 (2000). https://doi.org/10.1007/BF02494913

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  • DOI: https://doi.org/10.1007/BF02494913

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