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Study of the effect of ammonium sulfate additives on the structure and photocatalytic activity of titanium dioxide

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Thermal hydrolysis of titanium hydrochloride in the presence of ammonium sulfate added in a Ti: SO 2−4 = 20: 1 ratio was used to obtain samples of mesoporous titanium dioxide with anatase structure, stable in a wide temperature range. The phase composition, porous structure, and morphology of the synthesized titanium dioxide powders were examined by X-ray phase analysis, IR spectroscopy, scanning electron microscopy, and low-temperature adsorption of nitrogen. The role played by sulfate ions in how the microstructure of titanium dioxide is formed was determined. The effect of the hydrolysis temperature on the structure of titanium dioxide being obtained and on its photocatalytic activity in the reaction of decomposition of Methyl Orange dye was examined.

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References

  1. Zhang, W.-G., Zhang, L.-L., Li, R.-Q., et al., Mater. Chem. Phys., 2007, vol. 105, pp. 414–418.

    Article  CAS  Google Scholar 

  2. Gavrilov, V.Yu., Kinet. Kataliz, 1997, vol. 38, no. 5, pp. 762–767.

    Google Scholar 

  3. Tarasov, A.V., Metallurgiya titana (Metallurgy of Titanium), Moscow: Akademkniga, 2003.

    Google Scholar 

  4. RF Patent 2486134, 2011.

  5. Dobrovol’skii, I.P., Khimiya i tekhnologiya oksidnykh soedinenii titana (Chemistry and Technology of Oxide Compounds of Titanium), Sverdlovsk: Ural. Otd. Akad. Nauk SSSR, 1988.

    Google Scholar 

  6. Zhang, Q., Gao, L., and Guo, J., J. Eur. Ceram. Soc., 2000, vol. 20, pp. 2153–2158.

    Article  CAS  Google Scholar 

  7. Kozlov, D.V. and Vorontsov, A.V., J. Catal., 2008, vol. 258, pp. 87–94.

    Article  CAS  Google Scholar 

  8. Ma, Z., Yue, Y., Deng, X., and Gao, Z., J. Molec. Catal. A, 2002, vol. 178, pp. 97–104.

    Article  CAS  Google Scholar 

  9. Gao, L. and Zhang, Q., Mater. Trans., 2001, vol. 42, no. 8, pp. 1676–1680.

    Article  CAS  Google Scholar 

  10. Ohtani, B., Ogawa, V., and Nishimoto, S.-I., J. Phys. Chem. B, 1997, vol. 101, pp. 3746–3752.

    Article  CAS  Google Scholar 

  11. Li, Y., Lee, N.-H., Hwang, D.-S., et al., Langmuir, 2004, vol. 20, no. 5, pp. 10838–10844.

    Article  CAS  Google Scholar 

  12. Ivanov, V.K., Maksimov, V.D., Shaporev, A.S., et al., Russ. J. Inorg. Chem., 2010, vol. 55, no. 2, pp. 150–154.

    Article  CAS  Google Scholar 

  13. Gavrilov, V.Yu. and Zenkovets, G.A., Kinet. Kataliz, 1990, vol. 31, no. 1, pp. 168–173.

    CAS  Google Scholar 

  14. Zhang, Q., Gao, L., and Guo, J., J. Eur. Ceram. Soc., 2000, vol. 20, pp. 2153–2158.

    Article  CAS  Google Scholar 

  15. Dolmatov, Yu.D., Zh. Prikl. Khim., 1969, vol. 42, no. 8, pp. 1725–1732.

    CAS  Google Scholar 

  16. Peak, D., Ford, R.G., and Sparks, D.L., J. Colloid Interface Sci., 1999, vol. 218, pp. 289–299.

    Article  CAS  Google Scholar 

  17. Pervushin, V.Yu., Denisova, T.A., Tolchev, A.V., et al., Zh. Neorg. Khim., 1985, vol. 30, no. 4, pp. 855–859.

    CAS  Google Scholar 

  18. Gusev, V.B., Kleshchev, D.G., and Kalinichenko, I.I., Zh. Prikl. Khim., 1985, vol. 58, no. 1, pp. 33–36.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, ul. Akademika Koroleva 3, Perm, 614013, Russia

    I. I. Lebedeva, I. P. Sizeneva, D. M. Kisel’kov & V. A. Val’tsifer

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  1. I. I. Lebedeva
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  2. I. P. Sizeneva
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  3. D. M. Kisel’kov
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  4. V. A. Val’tsifer
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Correspondence to I. I. Lebedeva.

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Original Russian Text © I.I. Lebedeva, I.P. Sizeneva, D.M. Kisel’kov, V.A. Val’tsifer, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 554–562.

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Lebedeva, I.I., Sizeneva, I.P., Kisel’kov, D.M. et al. Study of the effect of ammonium sulfate additives on the structure and photocatalytic activity of titanium dioxide. Russ J Appl Chem 87, 547–554 (2014). https://doi.org/10.1134/S1070427214050024

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  • DOI: https://doi.org/10.1134/S1070427214050024

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