Abstract
Heterogeneous and homogeneous non-equilibrium plasma chemistry offers a range of potential advantages compared to conventional thermal activation and synthesis methods. Some examples of how such low temperature electrical discharges can be effectively utilised for selective chemical reaction pathways are given. These include the fluorination of C-H bonds, the synthesis of polyozonides, selective ring opening polymerisation, and the conversion of alkali metal halides to nitrates using air.
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References
S. Veprek, Plasma Chem. Plasma Process. 9 (1989) 29S.
B. Eliasson and U. Kogelschatz, IEEE Trans. Plasma Sci. 19 (1991) 309.
K. Honda and Y. Naito, J. Phys. Soc. Jpn. 10 (1955) 1007.
J.M. Meek and J.D. Craggs,Electrical Breakdown of Gases (Wiley, New York, 1978) ch. 1.
M.S. Strobel, S. Corn and G.A. Korba, J. Polym. Sci. Polym. Chem. Ed. 3 (1985) 1125.
S.S. Shepelev, H.D. Gesser and N.R. Hunter, Plasma Chem. Plasma Process. 13 (1993) 479.
S.L. Suib and R.P. Zerger, J. Catal. 139 (1993) 383.
A. Oumghar, J.C. Legrand, A.M. Diamy and N. Turillon, Plasma Chem. Plasma Process. 15 (1995) 87.
M.S. Ioffe, S.D. Pollington and J.K.S. Wan, J. Catal. 151 (1995) 349.
S. Tanaka, H. Uyama and O. Matsumoto, Plasma Chem. Plasma Process. 14 (1994) 491.
K. Kunimori, M. Osumi, S. Kameoka and S. Ito, Catal. Lett. 16 (1992) 443.
B. Eliasson, M. Hirth and U. Kogelschatz, Appl. Phys. B 46 (1988) 29.
S. Veprek, D.L. Cocke, S. Kehl and H.R. Oswald, J. Catal. 100 (1986) 250.
L. Rouleau, R. Bacaud, M. Breysse and J. Dufour, Appl. Catal. A 104 (1993) 137.
E.A. Dadashova, T.V. Yagodovskaya, E.S. Shpiro, L.A. Beilin, V.V. Lunin and V.V. Kiselev, Kinet. Katal. 34 (1993) 746.
H.V. Boenig,Fundamentals of Plasma Chemistry and Technology (Technomic, Lancaster, PA, 1988).
J. Jopkins and J.P.S. Badyal, J. Phys. Chem. 99 (1995) 4261.
E.A. Truesdale and G. Smolinsky, J. Appl. Phys. 50 (1979) 6594.
E. Occhiello, M. Morra, F. Garbassi and J. Bargon, Appl. Surf. Sci. 36 (1989) 285.
D. Edelson and D.L. Flamm, J. Appl. Phys. 56 (1984) 1522.
Y. Iriyama and H. Yasuda, J. Polym. Sci. Chem. Ed. 30 (1992) 1731.
E. Kay,Proc. Int. Ion Engineering Congress — ISIAT83 & IPAT83, Kyoto (1983) p. 1657.
D.T. Clark, D.B. Adams, A. Dilks, J. Peeling and H.R. Thomas, J. Electron Spectry. 8 (1976) 51.
S.R. Cain, F.D. Egitto and F. Emmi, J. Vac. Sci. Technol. A 5 (1987) 1578.
R. d’Agostino, F. Cramarossa, F. Fracassi and F. Illuzzi, in:Plasma Deposition, Treatment, and Etching of Polymers, ed. R. d’Agostino (Academic Press, San Diego, 1990) ch. 2.
W.A. Sheppard and C.M. Sharts, in:Organic Fluorine Chemistry (Benjamin, New York, 1969).
S.R. Cain, F.D. Egitto and F. Emmi, J. Vac. Sci. Technol. A 5 (1987) 1578.
B. Eliasson and U. Kogelschatz, IEEE Trans. Plasma Sci. 19 (1991) 309.
O.D. Greenwood, S. Tasker and J.P.S. Badyal, J. Polym. Sci. Polym. Chem. Ed. 32 (1994) 2479.
R. Criegee, Adv. Chem. Ser. 21 (1959) 133.
P.S. Bailey,Ozonation in Organic Chemistry, Vol. 1 (Academic Press, New York, 1978).
R.L. Kuczkowski, Chem. Soc. Rev. 21 (1992) 79.
K.W. Ho, J. Polym. Sci. Polym. Chem. Ed. 24 (1986) 2467.
J.M.G. Cowie,Polymers: Chemistry and Physics of Modern Materials, 2nd Ed. (Blackie, Glasgow, 1991).
H. Yasuda,Plasma Polymerization (Academic Press, Orlando, 1985).
I. Llewellyn and N. Rimmer, Thin Solid Films 191 (1990) 135.
C.R. Savage, R.B. Timmons and J.W. Lin, Chem. Mater. 3 (1991) 575.
R.D. Chambers,Fluorine in Organic Chemistry (Wiley, New York, 1973).
M.S. Kellou and G. Jenner, Eur. Polym. J. 12 (1976) 883.
D. Braun, U. Kuchler and G. Pietsch, Pure Appl. Chem. 60 (1988) 741.
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Badyal, J.P.S. Catalysis and plasma chemistry at solid surfaces. Top Catal 3, 255–264 (1996). https://doi.org/10.1007/BF02431188
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DOI: https://doi.org/10.1007/BF02431188