Abstract
Oxidation of antimony implanted silver single crystals at 550 K has been studied by Mössbauer spectroscopy and ion beam analysis, using the18O(p,α)15N reaction. The depth distribution measured for18O matched the Sb implantation profile. Strong evidence was found for the existence of an inward moving oxidation front. SbOn clusters with n=2,4 were observed, the oxygen atoms occupying octahedral interstitial sites.
Similar content being viewed by others
References
C. Wagner, Z. Electrochem.63 (1959) 772.
R.A. Rapp, Corrosion21 (1965) 382.
G.R. Wallwork, Rep. Prog. Phys.39 (1976) 401.
G.P. Huffman and H.H. Podgurski, Acta Metall.21 (1973) 449.
H. Andreasen, S. Damgaard, H.L. Nielsen and G. Weyer, Hyp. Int.15/16 (1983) 375; Hyp. Int.23 (1985) 43.
L. Niesen and H. de Waard, Hyp. Int.15/16 (1983) 455.
F.H. Sanchez, R.C. Mercader, A.F. Pasquevich, A.G. Bibiloni and A. Lopez García, Hyp. Int.20 (1984) 295.
G. Weyer, Nucl. Instr. Meth.186 (1981) 201.
G. Amsel and D. Samuel, Anal. Chem.39 (1967) 1689.
C.T. Tomizuka and L. Slifkin, Phys. Rev.96 (1954) 610.
P.J.M. Smulders, to be published.
W. Bolse, P. Wodniecki, H. Schröder, M. Uhrmacher and K.P. Lieb, Phys. Lett.93A (1983) 429.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Segeth, W., Andreasen, H., Boerma, D.O. et al. Internal oxidation of Sb impurities in silver. Hyperfine Interact 29, 1271–1274 (1986). https://doi.org/10.1007/BF02399466
Issue Date:
DOI: https://doi.org/10.1007/BF02399466