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Effect of Bombardment with Oxygen Ions on the Surface Composition of Polycrystalline Silver

  • PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
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Abstract

Surface layers of polycrystalline silver bombarded with oxygen ions having energies from 100 to 300 eV are studied via Auger electron and X-ray photoelectron spectroscopies. Atomic and molecular oxygen together with silver in the zero-valence state are found in AgO and Ag2O after such treatment in silver surface layers. In addition, there is positive displacement of the Ag 3d3/2 peak by 0.5 eV, indicating an increase in spin-orbit splitting for Ag 3d5/2–Ag 3d3/2.

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ACKNOWLEDGMENTS

This work was performed as part of a State Task of the RF Ministry of Education and Science for North Ossetian State University, project 3.9281.2017. It was supported by the Russian Foundation for Basic Research, project nos. 16-02-00138-а and 17-42-150110-r_а.

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Correspondence to O. G. Ashkhotov.

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Translated by A. Tulyabaev

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Ashkhotov, O.G., Khubezhov, S.A., Aleroev, M.A. et al. Effect of Bombardment with Oxygen Ions on the Surface Composition of Polycrystalline Silver. Russ. J. Phys. Chem. 92, 1382–1385 (2018). https://doi.org/10.1134/S003602441807004X

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  • DOI: https://doi.org/10.1134/S003602441807004X

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