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Silica surface controversies, strong adsorption sites, their blockage and removal. Part I

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Summary

The review describes many different controversies concerning the surface chemistry of silica. The first part concerns the variable nature of alkyl bonded phases for HPLC, the physical requirements for silica and the role of silanols as adsorption centres. The existence of a small population of strong adsorption sites is pointed out and the reasons for the strong and undesirable adsorption discussed; the part played by trace metals in the silica matrix is emphasised.

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  1. Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780, Poznań, Poland

    J. Nawrocki

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Nawrocki, J. Silica surface controversies, strong adsorption sites, their blockage and removal. Part I. Chromatographia 31, 177–192 (1991). https://doi.org/10.1007/BF02274570

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