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Physicochemical properties of surfaces of SBA-15 silicas, according to adsorption-static, gas-chromatographic, and IR spectroscopic data

  • Physical Chemistry of Surface Phenomena
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Abstract

Interaction between vapors of organic compounds and water with surfaces of mesoporous silica SBA-15 and silica SBA-15 modified with n-C6F13(CH2)2Si(CH3)2Cl via adsorption under static conditions is studied by means of gas chromatography and IR diffuse reflectance spectroscopy. It is shown that modification notably reduces the energy of disperse and specific interactions, along with the acidity of adsorption centers. Even low concentrations of the grafted groups (0.76 nm–2) allows us to obtain highly hydrophobic coatings on SBA-15 surfaces.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    T. M. Roshchina, N. K. Shoniya & O. Ya. Tegina

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. P. Tkachenko & L. M. Kustov

Authors
  1. T. M. Roshchina
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  2. N. K. Shoniya
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  3. O. Ya. Tegina
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  4. O. P. Tkachenko
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  5. L. M. Kustov
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Correspondence to T. M. Roshchina.

Additional information

Original Russian Text © T.M. Roshchina, N.K. Shoniya, O.Ya. Tegina, O.P. Tkachenko, L.M. Kustov, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 1, pp. 123–133.

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Roshchina, T.M., Shoniya, N.K., Tegina, O.Y. et al. Physicochemical properties of surfaces of SBA-15 silicas, according to adsorption-static, gas-chromatographic, and IR spectroscopic data. Russ. J. Phys. Chem. 90, 191–200 (2016). https://doi.org/10.1134/S0036024416010258

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  • DOI: https://doi.org/10.1134/S0036024416010258

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