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Physicochemical properties of the surfaces of silica species

  • Nanomaterials and Environment
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Abstract

The results from studying the physicochemical characteristics of the adsorption of n-alkanes, arenes, and acetonitrile on silicas of different origins, silica gels, and silochromes are presented. It is shown that increasing the concentration of silanol groups reduces the role of dispersion interactions accompanied by the intensification of specific interactions on silica gels, compared to silochromes. According to diffuse reflectance FTIR spectroscopy data, the acidity of silanol groups on silica gel is in this case less pronounced.

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References

  1. A. V. Kiselev, Intermolecular Interactions in Adsorption and Chromatography (Vysshaya Shkola, Moscow, 1986) [in Russian].

    Google Scholar 

  2. A. V. Kiselev, D. P. Poshkus, and Ya. I. Yashin, Molecular Foundations of Adsorptional Chromatography (Khimiya, Moscow, 1986) [in Russian].

    Google Scholar 

  3. Chemistry of Graft Surface Compounds, Ed. by G. V. Lisichkin (Fizmatlit, Moscow, 2003) [in Russian].

  4. K. K. Unger, Porous Silica: Its Properties and Use as Support in Column Liquid Chromatography (Elsevier, Amsterdam, 1979), Vol.16.

  5. V. A. Tertykh and L. A. Belyakova, Chemical Reactions Involving Silica Surface (Naukova Dumka, Kiev, 1991) [in Russian].

    Google Scholar 

  6. Medicinal Chemistry and Clinical Application of Silicon Dioxide, Ed. by A. A. Chuiko (Naukova dumka, Kiev, 2003) [in Russian].

  7. Ya. I. Yashin and A. Ya. Yashin, Zh. Ros. Khim. Obshch. Mendeleeva 47, 64 (2003).

    CAS  Google Scholar 

  8. Yu. I. Tarasevich, Surface Phenomena on Dispersed and Porous Materials (Naukova dumka, Kiev, 2011) [in Russian].

    Google Scholar 

  9. A. V. Kiselev and V. I. Lygin, Infrared Spectra of Surface Compounds (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

  10. A. P. Karnaukhov, Adsorption. Texture of Dispersed and Porous Materials (Nauka, Novosibirsk, 1999) [in Russian].

    Google Scholar 

  11. F. Bernardoni, M. Kouba, and A. Fadeev, Chem. Mater. 20, 382 (2008).

    Article  CAS  Google Scholar 

  12. I. E. Neimark and R. Yu. Sheinfain, Silica Gel, Its Production, Properties, and Application (Naukova Dumka, Kiev, 1973) [in Russian].

    Google Scholar 

  13. O. Isaienko and E. Borguet, Langmuir 29, 7885 (2013).

    Article  CAS  Google Scholar 

  14. A. Bagaturyants and M. Alfimov, Chemical Sensors: Simulation and Modeling, Vol. 4: Optical Sensors, Ed. by G. Korotchenkov (Momentum Press, New York, 2013).

  15. Yu. I. Tarasevich, V. E. Polyakov, A. A. Serdan, and G. V. Lisichkin, Colloid. J. 67, 592 (2005).

    Article  Google Scholar 

  16. L. T. Zhuravlev, Langmuir 3, 316 (1987).

    Article  CAS  Google Scholar 

  17. S. Leonardelli, L. Faccini, C. Fretigni, et al., J. Am. Chem. Soc. 114, 6412 (1992).

    Article  CAS  Google Scholar 

  18. V. I. Lygin, Zh. Ros. Khim. Obshch. Mendeleeva 46 (3), 12 (2002).

    CAS  Google Scholar 

  19. A. V. Kiselev, V. I. Lygin, and K. L. Shchepalin, Zh. Fiz. Khim. 60, 1701 (1986).

    CAS  Google Scholar 

  20. R. Iler, The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica (Wiley, New York, 1979; Mir, Moscow, 1982), Vol.2.

  21. T. Bernstein, D. Michel, and H. Pfeifer, J. Colloid Interface Sci. 84, 310 (1981).

    Article  CAS  Google Scholar 

  22. V. Marko and K. Radova, J. Liq. Chromatogr. 14, 1645 (1991).

    Article  CAS  Google Scholar 

  23. V. N. Zaitsev, Complex Forming Silicas: Synthesis, Structures of Grafted Layer and Surface Chemistry (Folio, Kharkov, 1997) [in Russian].

    Google Scholar 

  24. T. M. Roshchina, N. K. Shoniya, O. Ya. Tayakina, F. Bernardoni, and A. Y. Fadeev, Prot. Met. Phys. Chem. Surf. 50, 304 (2014).

    Article  CAS  Google Scholar 

  25. T. D. Khokhlova, Vestn. Mosk. Univ., Ser. Khim. 43, 144 (2002).

    CAS  Google Scholar 

  26. T. M. Roshchina, N. K. Shoniya, O. Ya. Tegina, O. P. Tkachenko, and L. M. Kustov, Russ. J. Phys. Chem. A 90, 191 (2016).

    Article  CAS  Google Scholar 

  27. Experimental Methods in Adsorption and Molecular Chromatography, Ed. by Yu. S. Nikitin and R. S. Petrova (Mosk. Gos. Univ., Moscow, 1990) [in Russian].

  28. K. B. Gurevich, T. M. Roshchina, N. K. Shonia, et al., J. Colloid Interface Sci. 254, 39 (2002).

    Article  CAS  Google Scholar 

  29. V. Yu. Borovkov, Doctoral (Chem.) Dissertation (N. D. Zelinsky Inst. Organic Chemistry RAS, Moscow, 1988).

    Google Scholar 

  30. L. M. Kustov, Top. Catal. 4, 131 (1995).

    Article  Google Scholar 

  31. T. M. Miller, in CRC Handbook of Chemistry and Physics, Ed. by D. R. Lide, 83rd ed. (CRC, Boca Raton, Fl, 2002).

  32. A. V. Kiselev, Ya. I. Yashin, A. V. Iogansen, et al., Physicochemical Application of Gas Chromatography (Khimiya, Moscow, 1973), p. 36 [in Russian].

    Google Scholar 

  33. M. A. Haney and J. L. Franklin, J. Phys. Chem. 73, 4328 (1969).

    Article  CAS  Google Scholar 

  34. T. M. Roshchina, N. K. Shoniya, M. S. Lagutova, V. Yu. Borovkov, L. M. Kustov, and A. Yu. Fadeev, Russ. J. Phys. Chem. A 81, 1128 (2007).

    Article  CAS  Google Scholar 

  35. A. S. Medin, V. Yu. Borovkov, V. B. Kazansky, et al., Zeolites 10, 668 (1990).

    Article  CAS  Google Scholar 

  36. C. L. Angell and M. V. Howell, J. Phys. Chem. 73, 2551 (1969).

    Article  CAS  Google Scholar 

  37. K. F. Purcell and R. S. Grado, J. Am. Chem. Soc. 88, 919 (1966).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119992, Russia

    T. M. Roshchina, N. K. Shoniya, O. Ya. Tegina & L. M. Kustov

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. P. Tkachenko & L. M. Kustov

Authors
  1. T. M. Roshchina
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  2. N. K. Shoniya
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  3. O. Ya. Tegina
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  4. O. P. Tkachenko
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  5. L. M. Kustov
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Correspondence to T. M. Roshchina.

Additional information

Original Russian Text © T.M. Roshchina, N.K. Shoniya, O.Ya. Tegina, O.P. Tkachenko, L.M. Kustov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 2, pp. 217–226.

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Roshchina, T.M., Shoniya, N.K., Tegina, O.Y. et al. Physicochemical properties of the surfaces of silica species. Russ. J. Phys. Chem. 91, 217–225 (2017). https://doi.org/10.1134/S003602441702025X

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  • DOI: https://doi.org/10.1134/S003602441702025X

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