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Synthesis and properties of 6-oxo-3,5-dicyano-1,4,5,6tetrahydrospiro-(4′-r-cyclohexane-1′,4-pyridine)-2thiols and -selenols

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By the interaction of a 4-R-cyclohe.xylidenecyanoacetic ester with cyanothio(seleno)acetainide, 6-oxo-3, 5dicyano-1, 4, 5, 6-tetrahydrospiro-(4′-R-cyclohexane-1 ', 4-pyridine)-2-thiols and -selenols have been obtained; these have also been synthesized from a cyclohexytidenecyanothioacetamide and cyanoacetic ester. These thiols and selenols have been used to prepare the corresponding disulfides, diselenides, and spiro systems, including the fragments alkylthio(seleno)tetrahydropyridine, thieno[2, 3-bjpyridine, and 2, 3-dihydrothiazolopyridine.

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Authors
  1. V. D. Dyachenko
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  2. A. E. Mitroshin
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  3. V. P. Litvinov
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Additional information

T. G. Shevchenko Lugansk State Pedagogical Institute, Lugansk 348011, Ukraine. N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences Moscow 117913. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9 pp. 1235–1242, September, 1996. Original article submitted May 13, 1996.

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Dyachenko, V.D., Mitroshin, A.E. & Litvinov, V.P. Synthesis and properties of 6-oxo-3,5-dicyano-1,4,5,6tetrahydrospiro-(4′-r-cyclohexane-1′,4-pyridine)-2thiols and -selenols. Chem Heterocycl Compd 32, 1058–1065 (1996). https://doi.org/10.1007/BF01164713

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  • DOI: https://doi.org/10.1007/BF01164713

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