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Acetone intercalation/de-intercalation processes in the HUP (H3OUO2PO4·3H2O) framework: A model for electrochemical degradation

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Abstract

Intercalation of acetone molecules in the H3OUO2PO4 · 3H2O framework has been studied by X-ray diffraction, differential scanning calorimetry and IR and Raman spectroscopies. The influence of water traces in acetone is pointed out. Four main phases are observed in the course of the rehydration/de-intercalation process. The nature of proton bonding with the (UO2PO4) n slab and its evolution are discussed (H3O+, PO 3−4 , HPO 2−4 , HPO 2−4 ...). The presence of defects in the sub-stoichiometric HUP is demonstrated. Comparison is made with similar partially dehydrated material obtained under electric field action in electrochemical solid state devices.

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References

  1. M. G. Shilton andA. T. Howe,Mater. Res. Bull. 12 (1977) 701.

    Google Scholar 

  2. M. A. R. deBenyacar andH. L. deDussel,Ferroelectrics 9 (1975) 241.

    Google Scholar 

  3. M. Ross andH. T. Evans,Amer. Mineral. 49 (1964) 1578.

    Google Scholar 

  4. Ph. Colomban andM. Pham-Thi,Rev. Chim. Minérale 22 (1985) 143.

    Google Scholar 

  5. A. T. Howe, S. H. Sheffield, P. E. Childs andM. G. Shilton,Thin Solid Films 67 (1980) 365

    Google Scholar 

  6. M. Pham-Thi andG. Velasco,Solid State Ionics 14 (1984) 217

    Google Scholar 

  7. G. Velasco, H. Perthuis andPh. Colomban, in Proceedings of the International Meeting on Chemical Sensors, Fukuoka, Japan, September 1983, edited by T. Seiyama, K. Fueki, J. Shiokawa and S. Suziki, (Elsevier, 1983) p. 239.

  8. J. S. Lundgaard, J. Malling andM. L. S. Birchall,Solid State Ionics 7 (1982) 53.

    Google Scholar 

  9. G. Velasco, M. Pham-Thi andPh. Colomban, French Patent No. 8509653 (1985).

  10. M. Pham-Thi, Ph. Adet, G. Velasco and Ph.Colomban,Appl. Phys. Lett. in press.

  11. M. Pham-Thi and Ph.Colomban,J. Less-Common Metals 108 (1985) 189.

    Google Scholar 

  12. K. D. Kreuer, W. Weppner andA. Rabenau,Solid State Ionics 3/4 (1981) 353.

    Google Scholar 

  13. H. Kahil, M. Forestier andJ. Guitton, in “Solid State Protonic Conductors III”, edited by J. B. Goodenough, A. Potier and J. Jensen (Odense University Press, 1985) p. 356.

  14. M. Pham-Thi, Ph. Colomban andA. Novak,J. Phys. Chem. Solids. 46 (1985) 565.

    Google Scholar 

  15. A. V. Weiss, K. Hartl andU. Hofmann,Z. Nat. Forsch. 12b (1957) 669.

    Google Scholar 

  16. I. Kh. Moroz, A. A. Valueva, E. A. Sidorenko, L. G. Shiltosava andL. N. Korpova,Geokhimya (1973) 210.

  17. V. Ross,Amer. Mineral. 40 (1955) 917.

    Google Scholar 

  18. G. R. Williams,Bull. Inst. Geochem. Astrom. Univ. Sao Paulo 2 (1971) 83.

    Google Scholar 

  19. P. V. Huong andG. Noel,Spectrochim. Acta 32A (1978) B31.

    Google Scholar 

  20. D. Hadzi, S. Bratos, in “The Hydrogen Bonds”, edited by P. Schuster, G. Zundel and C. Sandorfy, (North-Holland, Amsterdam, 1976) p. 565.

    Google Scholar 

  21. R. Mercier, M. Pham Thi and Ph.Colomban,Solid State Ionics 15 (1985) 113.

    Google Scholar 

  22. P. Piret andM. Deliens,Bull. Mineral. 105 (1982) 125.

    Google Scholar 

  23. Ph. Colomban, M. Pham-Thi andA. Novak,Solid State Commun. 53 (1985) 747.

    Google Scholar 

  24. J. P. Boilot andPh. Colomban,J. Mater. Sci. Lett. 4 (1985) 22.

    Google Scholar 

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Author notes

  1. M. Pham-Thi

    Present address: Laboratoire d'Analyse Physique, LCR Thomson-CSF, Domaine de Corbeville, 91401, Orsay, France

Authors and Affiliations

  1. Laboratoire de Physico-Chimie et Dispositifs Ioniques, LCR Thomson-CSF, Domaine de Corbeville 91401, Orsay, France

    M. Pham-Thi

  2. Groupe de Chimie du Solide, LPMC, Ecole Polytechnique, 91128, Palaiseau, France

    Ph. Colomban

Authors
  1. M. Pham-Thi
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  2. Ph. Colomban
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Pham-Thi, M., Colomban, P. Acetone intercalation/de-intercalation processes in the HUP (H3OUO2PO4·3H2O) framework: A model for electrochemical degradation. J Mater Sci 21, 1591–1600 (1986). https://doi.org/10.1007/BF01114713

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  • DOI: https://doi.org/10.1007/BF01114713

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