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Preparation, characterization and Mössbauer spectra of the iron(III) complexes of some dihydroxamic acids and amino monohydroxamic acids

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Summary

FeIII complexes have been prepared from the dihydroxamic acids (CH2)n[CON(R)OH]2 (n=2, 3, 4, 6, 8; R=H, Ph,o-tolyl,p-tolyl) (H2L) and the amino monohydroxamic acids H2NCH(R)CONHOH (R=H, Me) (HL′) and XC6H4CONHOH (X=o-NH2,p-NH2) (HL″). Based on elemental analyses, molecular weight data, and electronic and i.r. spectra, the complexes have been formulated as Fe2(LH)2L2, Fe2L2O and Fe2L3 for the dihydroxamic acids, and Fe(OH)4L′2(H2O)2 and FeL″3 for the amino monohydroxamic acids. The57Fe Mossbauer spectra are discussed.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, 700032, Calcutta, India

    Mrinal K. Das, Kinshuk Chaudhury, Nita Roy & Phuljhuri Sarkar

  2. Department of Physics, Indian Association for the Cultivation of Science, 700032, Calcutta, India

    Kinshuk Chaudhury

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  1. Mrinal K. Das
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  2. Kinshuk Chaudhury
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  3. Nita Roy
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  4. Phuljhuri Sarkar
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The author is née Bose

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Das, M.K., Chaudhury, K., Roy, N. et al. Preparation, characterization and Mössbauer spectra of the iron(III) complexes of some dihydroxamic acids and amino monohydroxamic acids. Transition Met Chem 15, 468–472 (1990). https://doi.org/10.1007/BF01040778

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  • DOI: https://doi.org/10.1007/BF01040778

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