Abstract
We report herein the synthesis and physicochemical characterization of a new mixed-ligand iron(III) complex of the formula (C5H6ClN2)[Fe(C2O4)2(H2O)2]∙2H2O. This compound is prepared by slow evaporation at room temperature and characterized by single crystal X-ray diffraction. It is characterized by IR and UV-VIS spectra and thermal analysis (TG and DTA). In this compound, the iron ion has a slightly distorted square bipyramidal environment, coordinated by two chelating oxalate ions and two water molecules. Structural cohesion is essentially established by π–π interactions between the rings of pyridine groups and intermolecular hydrogen bonds connecting the ionic entities and uncoordinated water molecules. Magnetic susceptibility measurements exhibit the paramagnetic behavior at high temperatures. However, at low temperatures, the magnetic data show the occurrence of weak antiferromagnetic intermolecular interactions between the local spins.
Similar content being viewed by others
References
A. Haikarainen, J Sipilä, P. Pietikäinen, A. Pajunen, and I. Mutikainen, J Chem. Soc., Dalton Trans., 991 (2001).
M. Ferbinteanu, H. Miyasaka, W. Wernsdorfer, K. Nakata, K. I. Sugiura, M. Yamashita, C. Coulon, and R. Clérac, J. Am. Chem. Soc., 127, 3090 (2005).
H. P. Jia, W. Li, Z. F. Ju, and J Zhang, J. Mol. Struct., 833, 49 (2007).
A. Clearfield, in: Prog. Inorg. Chem., K. D. Karlin(ed.), vol. 47, Wiley, New York (1998), p.371.
K. Maeda, Microporous Mesoporous Mater., 73, 47 (2004).
C. Bellitto, in: Magn.: Mol. Mater. II, J. S. Miller and M. Drillon (eds.), VCH, New York (2001), p.425.
Y. Y. Zhang, Y. Qi, Y. Zhang, Z. Y. Liu, Y. F. Zhao, and Z. M. Liu, Mater. Res. Bull., 42, 1531 (2007).
P. J. Steel, Coord. Chem. Rev., 106, 227 (1990).
H. P. Jia, W. Li, Z. F. Ju, and J Zhang, J. Mol. Struct., 49, 833 (2007).
F. Tuna, G. I. Pascu, J. P. Sutter, M. Andruh, S. Golhen, J Guillevic, and H. Pritzkow, Inorg. Chim. Acta, 131, 342 (2003).
O. Schott, J Ferrando-Soria, A. Bentama, S. E. Stiriba, J Pasán, C. Ruiz-Pérez, M. Andruh, F. Lloret, and M. Julve, Inorg. Chim. Acta, 376, 358 (2011).
F. Holmes, K. M. Jones, and E. G. Torrible, J. Chem. Soc., 4790 (1961).
A. Earnshaw, Introduction to Magnetochemistry, Academic Press, London (1968).
G. M. Sheldrik, Acta Crystallogr., A46, 467 (1990).
G. M. Sheldrick, Program for the Refinement of Crystal Structures, University of Göttingen, Germany (1997).
K. Brandenburg, Visual Crystal Structure Information System. Version 3.0, University of Bonn, Germany (2003).
O. Castillo, A. Luque, and P. Román, J. Mol. Struct., 570, 181 (2001).
M. McCann, M. T. Casey, M. Derveux, M. Curan, and V. McKee, Polyhedron, 16, 2741 (1997).
A. W. Addison, T. N. Rao, J Reedijk, J van Rijn, and G. C. Verschoor, J. Chem. Soc., Dalton Trans., 1349 (1984).
J.-H. Yu, Q. Hou, M.-H. Bi, Z.-L. Lü, X. Zhang, X.-J. Qu, J Lu, and J.-Q. Xu, J. Mol. Struct., 800, 69 (2006).
S. Decurtins, H. W. Schmalle, P. Schneuwly, and H. R. Oswald, Inorg. Chem., 32, 1888 (1993).
J. Abdelhak, S. N. Cherni, M. F. Zid, and A. Driss, Acta Crystallogr., E62, 2394 (2006).
N. Karaa, B. Hamdi, A. Ben Salah, and R. Zouari, J. Mol. Struct., 1049, 48 (2013).
G. Marinescu, D. Visinescu, A. Cucos, M. Andruh, Y. Journaux, V. Kravtsov, Y. A. Simonov, and J Lipkowski, Eur. J. Inorg. Chem., 2914 (2004).
J. T. Wrobleski and D. B. Brown, Inorg. Chem., 18, 2738 (1979).
L. M. Zheng, X. Fang, K. H. Lii, H. H. Song, X. Q. Xin, H. K. Fun, K. Chinnakali, and I. Abdul Razak, J. Chem. Soc., Dalton Trans., 2311 (1999).
F. Lloret, M. Julve, M. Mollar, I. Castro, J Latorre, J Faus, X. Solans, and I. Morgenstern-Badarau, J. Chem. Soc., Dalton Trans., 729 (1989).
D. Czakis-Sulikowska, A. Malinowska, and J Radwañska-Doczekalska, Polish J. Chem., 74, 607 (2000).
I. P. Pozdnyakov, O. V. Kel, V. F. Plyusnin, V. P. Grivin, and N. M. Bazhin, J. Phys. Chem. A, 112, 8316 (2008).
M. D. Snodin, L. Oud-Moussa, U. Wallmann, S. Lecomte, V. Bachler, E. Bill, H. Hummel, T. Weyermüller, P. Hildebrandt, and K. Wiegardt, Chem. Eur. J., 5, 2554 (1999).
O. V. Palamarciuc, P. N. Bourosh, M. D. Revenco, J Lipkowski, Y. A. Simonov, and R. Clérac, Inorg. Chim. Acta, 363, 2561 (2010).
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 4, pp. 702-709, July-August, 2015. Original article submitted November 26, 2013; revised March 9, 2014.
Rights and permissions
About this article
Cite this article
Abdelhak, J., Cherni, S.N., Zid, M.F. et al. Crystal structure, spectroscopic and magnetic properties of a new iron(III) complex. J Struct Chem 56, 654–661 (2015). https://doi.org/10.1134/S0022476615040071
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476615040071