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Influence of chromium on119Sn site hyperfine fields in Fe−Cr alloys

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Abstract

By diffusing119Sn probe atoms into a range of Fe−Cr alloys and carrying out Mössbauer effect measurements it has been shown that Sn site hyperfine fields exhibit the same dependence on chromium concentration as Fe site fields do. It has also been shown that the change in the Sn site field produced by Cr atoms situated in the first or in the second coordination sphere is the same as the corresponding change in the Fe site field. This shows that all the change in the hyperfine field caused by substitution of chromium into an iron matrix is due to conduction electron polarization contributions.

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Dubiel, S.M. Influence of chromium on119Sn site hyperfine fields in Fe−Cr alloys. Hyperfine Interact 8, 291–304 (1980). https://doi.org/10.1007/BF01026878

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  • DOI: https://doi.org/10.1007/BF01026878

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