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IR spectra of nitro compounds

Communication 1. The relationship of frequencies to structure

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An analysis of the dependence of the position of the frequencies of the valence vibration of the NO2 group on the structure of the substituent was conducted in a series of nitro compounds. The inductive and steric effects, as well as the effect of conjugation, influence the position of the band of the antisymmetrical valence vibration of the NO2 group.

  2. 2.

    A linear dependence of the band of the antisymmetrical valence vibration on the induction constant (σ*) of the substituent was found. The position of the band of the symmetrical vibration of the NO2 group is determined chiefly by the steric hindrances of the substituent.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. I. Slovetskii

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  1. V. I. Slovetskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2215–2221, October, 1970.

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Slovetskii, V.I. IR spectra of nitro compounds. Russ Chem Bull 19, 2086–2091 (1970). https://doi.org/10.1007/BF00861473

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