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The Williams-Watts dependence as a common phenomenological approach to relaxation processes in condensed matter

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Abstract

The Williams-Watts (WW) relaxation function has been widely used to describe the relaxation behaviour of many systems. In the present work the range of applicability of the WW response was extensively tested by the analysis of experiments in both the time and the frequency domains. On the other hand, the analysed experiments covered a wide time-scale for the characteristic relaxation times. Some related topics were also considered, i.e. our procedures in obtaining the associated activation energy spectra or the distribution of relaxation times. The relationship between time-domain and frequency-domain relaxation responses was also analysed. In light of our results the universality of the WW response, appears to be good at least for the time-scales and the different probes covered by our experiments.

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References

  1. K. S. Cole andR. H. Cole,J. Chem. Phys. 9 (1941) 341.

    Article  CAS  Google Scholar 

  2. D. W. Davidson andR. H. Cole,ibid. 19 (1951) 1484.

    Article  CAS  Google Scholar 

  3. G. Williams andD. C. Watts,Trans. Faraday Soc. 66 (1970) 80.

    Article  CAS  Google Scholar 

  4. C. T. Moynihan, L. P. Boesch andN. L. Laberge,Phys. Chem. Glasses 14 (1973) 122.

    CAS  Google Scholar 

  5. J. T. Bendler andK. L. Ngai,Macromolecules 17 (1984) 1174.

    Article  CAS  Google Scholar 

  6. A. Muñoz andF. L. Cumbrera,Therm. Acta 196 (1992) 137.

    Article  Google Scholar 

  7. K. L. Ngai, A. K. Rajagopal andC. Y. Huang,J. Appl. Phys. 55 (1984) 15.

    Article  Google Scholar 

  8. C. De Dominicis, H. Orland andF. Lainee,J. Phys. Lett. 46 (1985) L463.

    Article  Google Scholar 

  9. E. W. Montroll andJ. T. Bendler,J. Stat. Phs. 34 (1984) 129.

    Article  Google Scholar 

  10. J. R. MacDonald,J. Appl. Phys. 62 (1987) R51.

    Article  CAS  Google Scholar 

  11. A. Agrawal andR. L. Zhang,Phys. Chem. Glasses 29 (1988) 141.

    CAS  Google Scholar 

  12. W. Primak,Phys. Rev. 100 (1955) 1677.

    Article  CAS  Google Scholar 

  13. J. Castaing, M. Spendel, J. Philibert, A. Dominguez-Rodriguez andR. Marquez,Rev. Phys. Appl. 15 (1980) 277.

    Article  CAS  Google Scholar 

  14. F. Guiberteau, M. Jimenez-Melendo, A. Dominguez-Rodriguez, R. Marquez andJ. Castaing,Cryst. Latt. Def. Amorph. Mater. 16 (1987) 91.

    CAS  Google Scholar 

  15. A. Muñoz, F. L. Cumbrera andR. Marquez, “Current Topics on Non-Crystalline Solids” (World Scientific, Singapore 1986) p. 211.

    Google Scholar 

  16. F. L. Cumbrera andA. Muñoz,Therm. Acta 144 (1989) 123.

    Article  Google Scholar 

  17. R. B. Stephens,J. Appl. Phys. 49 (1978) 5855.

    Article  CAS  Google Scholar 

  18. J. Grenet, J. P. Larmagnac, P. Michon andC. Vautier,Thin Solid Films 76 (1981) 53.

    Article  CAS  Google Scholar 

  19. F. Alvarez, A. Alegria andJ. Colmenero,Phys. Rev. B 44 (1991) 7306.

    Article  CAS  Google Scholar 

  20. D. W. Marquardt.J. Soc. Ind. Appl. Math. 11 (1963) 431.

    Article  Google Scholar 

  21. J. C. Li,J. Phys. 45 (1967) 493.

    CAS  Google Scholar 

  22. D. J. Lloyd, P. J. Worthington andJ. D. Embury,Philos. Mag. 22 (1970) 1147.

    Article  CAS  Google Scholar 

  23. F. C. Aifantis andW. W. Gerberich,Mater. Sci. Eng. 21 (1975) 107.

    Article  Google Scholar 

  24. M. Grosbras, E. Dedieu andM. Cahoreau,Phys. Status Solidi (a) 42 (1977) 449.

    Article  CAS  Google Scholar 

  25. G. Schoeck,ibid. 87 (1985) 571.

    Article  Google Scholar 

  26. K. K. Ray andA. K. Mallik,Mater. Sci. Eng. 59 (1983) 59.

    Article  CAS  Google Scholar 

  27. P. Feltham, J. Inst. Metals89 (1961) 210.

    CAS  Google Scholar 

  28. A. G. Evans andR. D. Rawlings,Phys. Status Solids 34 (1969) 9.

    Article  CAS  Google Scholar 

  29. P. Sarkar andP. Nicholson,J. Am. Ceram. Soc. 72 (1989) 1447.

    Article  CAS  Google Scholar 

  30. P. B. Macedo, C. T. Moynihan andR. Bose,Phys. Chem. Glasses 13 (1972) 171.

    CAS  Google Scholar 

  31. J. D. Ferry, “Viscoelastic properties of Polymers” (Wiley, New York, 1961).

    Book  Google Scholar 

  32. H. Pollard, Bull. Am. Math. Soc.52 (1946) 908.

    Article  Google Scholar 

  33. J. D. Ferry andM. L. Williams,J. Colloid. Sci. 7 (1952) 347.

    Article  CAS  Google Scholar 

  34. N. W. Tschoegl, “The theory of linear viscoelastic behaviour” (Academic Press, New York, 1981).

    Google Scholar 

  35. L. Schwarzl andA. J. Staverman,Appl. Sci. Res. 4 (1953) 127.

    Article  Google Scholar 

  36. M. R. J. Gibbs, J. E. Evetts andJ. A. Leake,J. Mater Sci. 18 (1983) 278.

    Article  CAS  Google Scholar 

  37. A. Muñoz, F. L. Cumbrera andR. Marquez,Mater. Chem. Phys. 21 (1989) 279.

    Article  Google Scholar 

  38. B. C. Cook,Nucl. Instrum. Meth. 24 (1963) 256.

    Article  Google Scholar 

  39. De Ceuninck, Z. Ruyan, G. Knuyt, L. Schepper andL. M. Stals,Mater. Sci. Eng. 97 (1988) 545.

    Article  Google Scholar 

  40. J. Perez,J. de Phys. C10 (1985) 427.

    Google Scholar 

  41. idem, Rev. Phys. Appl. 21 (1986) 93.

    Article  CAS  Google Scholar 

  42. A. Dominguez-Rodriguez, J. Castaing, H. Koisumi andT. Suzuki,ibid. 23 (1988) 1361.

    Article  CAS  Google Scholar 

  43. J. Colmenero, A. Alegria, J. M. Alberdi, F. Alvarez andB. Frick,Phys. Rev. B 44 (1991) 7321.

    Article  CAS  Google Scholar 

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Cumbrera, F.L., Sanchez-Bajo, F., Guiberteau, F. et al. The Williams-Watts dependence as a common phenomenological approach to relaxation processes in condensed matter. J Mater Sci 28, 5387–5396 (1993). https://doi.org/10.1007/BF00570095

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