Abstract
A theoretical model for relaxation in glassy materials, in particular metallic glasses, based on a spectrum of available processes distributed in activation energy is presented. The model is used to discuss “In t” kinetics, “reversibility” and “crossover” effects which have been observed experimentally. Where direct comparison is possible between the theory and experiment the agreement is good over all these various observed phenomena.
Similar content being viewed by others
References
T. Mizoguchi, H. Kato, N. Akutsu and S. Hatta, Proceedings of the 4th International Conference on Rapidly Quenched Metals, Sendai, 1981, edited by T. Masumoto and K. Suzuki, Vol. 2 (Japan Institute of Metals, 1982) p. 1173.
A. L. Greer and F. Spaepen, Ann. New York Acad. Sci. 371 (1981) 218.
A. L. Greer and J. A. Leake, J. Non-Cryst. Solids 33 (1979) 291.
M. G. Scott, R.W. Cahn, A. Kursumovć, E. Girt and N. B. Njuhovć, Proceedings of the 4th Internatinal Conference on Rapidly Quenched Metals, Sendai, 1981, edited by T. Masumoto and K. Suzuki, Vol. 2 (Japan Institute of Metals, 1982) p. 469.
E. Woldt, Diploma, Institut A für Physik der Technischen Universität Carolo-Wilhelmina, Braunschweig (1980).
T. Egami, J. Mater. Sci. 13 (1978) 2587.
J. R. Cost and J. T. Stanley, Scripta Metall. 15 (1981) 407.
W. Chambron and A. Chamberod, Sol. Stat. Commun. 33 (1980) 157.
H. S. Chen, J. Appl. Phys. 52 (1981) 1868.
L. Boesch, A. Napolitano and P. B. Macedo, J. Amer. Ceram. Soc. 53 (1970) 148.
D. Kuhlmann, Z. Physik 124 (1948) 468.
A. S. Argon and H. Y. Kuo, J. Non-Cryst. Solids 37 (1980) 241.
E. Woldt and H. Neuhäser, J. Phys. C8 41 (1980) 846.
W. Primak, Phys. Rev. 100 (1955) 1677.
T. Egami, Ann. New York Acad. Sci. 371 (1981) 238.
M. R. J. Gibbs and J. E. Evetts, Proceedings of the 4th International Conference on Rapidly Quenched Metals, Sendai, 1981, edited by T. Masumoto and K. Suzuki, Vol. 2, (Japan Institute of Metals, 1982) p. 479.
J. A. Leake, M. R. J. Gibbs and J. E. Evetts, ibid, p. 513.
K. Bothe and H. Neuhäuser, Scripta Metall. submitted.
M. R. J. Gibbs, Proceedings of the Conference on Metallic Glasses Science and Technology, Budapest, 1980, edited by C. Hargitai, I. Bakonyi and T. Kemeny, Vol. 2 (Central Research Institute for Physics, Budapest, 1980) p. 37.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gibbs, M.R.J., Evetts, J.E. & Leake, J.A. Activation energy spectra and relaxation in amorphous materials. J Mater Sci 18, 278–288 (1983). https://doi.org/10.1007/BF00543836
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00543836