Abstract
Solidus temperatures have been determined for minimum melt compositions in the system Qz(SiO2)-Ab(NaAlSi3O8)-Or(KAlSi3O8) at P(fluid)=2,5 and 10 kbar and at various water activities. The dry solidus was investigated in a dry argon environment. Water activities (aH2O) between 0.0 and 1.0 were obtained by using H2O-CO2 mixtures. The Or/Ab+Or ratio of first melts increases considerably with decreasing water activity. At 10 kbar it is 0.28 in the water-saturated system and 0.56 at water activity 0.1. The Qz-content does not change with changing water activities. The Ab-content of minimum melts formed at high pressures and low aH2O may remain almost constant in ascending magmas that are cooling and crystallizing. Qz-content increases at the expense of the Or-component. Solidus temperatures decrease considerably when aH2O increases slightly from zero. At 10 kbar, the temperature difference between dry melting and the solidus for aH2O=0.1 is 120°C. The influence of pure CO2 on the solidus is very limited in the investigated P-T range. The solidus is approximatively 760°C at aH2O=0.5 between 2 and 10 kbar and approximatively 830°C at aH2O=0.3. This means that melting of quartz-feldspar assemblages may induce dehydration reactions at P-T conditions of the granulite facies.
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References
Boettcher AL (1984) The system SiO2-H2O-CO2: melting, solubility mechanisms of carbon, and liquid structure to high pressures. Am Mineral 69:823–833
Bohlen SR, Boettcher AL, Wall VJ (1982) The system albite-H2O-CO2: a model for melting and activities of water at high pressure. Am Mineral 67:451–462
Bohlen SR, Boettcher AL, Wall VJ, Clemens JD (1983) Stability of phlogopite-quartz and sanidine-quartz: a model for melting in the lower crust. Contrib Mineral Petrol 83:270–277
Clemens JD (1984) Water contents of silicic to intermediate magmas. Lithos 17:273–287
Clemens JD, Vielzeuf D (1987) Constraints on melting and magma production in the crust. Earth Planet Sci Lett 86:287–306
Clemens JD, Wall VJ (1981) Origin and crystallization of some peraluminous (S-type) granitic magmas. Can Mineral 19:111–131
Conrad WK, Nicholls IA, Wall VJ (1988) Water-saturated and-undersaturated melting of metaluminous and peraluminous crustal compositions at 10 kb: evidence for the origin of silicic magmas in the Taupo volcanic zone, New Zealand, and other occurrences. J Petrology 29:765–803
Ebadi A, Ziegenbein D, Johannes W (1987) Schmelzbildung im Granitsystem Qz-Ab-Or bei Wasseraktivitäten kleiner 1. Fortschr der Mineral 65:41
Fyfe WS (1973) The granulite facies, partial melting and the Archaean crust. Philos Trans R Soc London A 273:457–461
Grant JA (1985) Phase equilibria in partial melting of pelitic rocks. In: Ashworth JR (ed) Migmatites. Blackie, Glasgow, pp 86–144
Green TH (1976) Experimental generation of cordierite- or garnetbearing granitic liquids from a pelitic composition. Geology 4:85–88
Greenwood HJ (1967) Mineral equilibria in the system MgO-SiO2-H2O-CO2. In: Abelson (ed) Research in Geochemistry 2:542–567
Holt F, Barbey P, Johannes W, Pichavant M (1989) Composition and temperature at the minimum point in the Qz-Ab-Or system for H2O-undersaturated conditions. Experimental investigation. Terra Cognita 1:271–272
Holtz F, Pichavant M, Barbey P, Johannes W (1991) Experimental investigation of H2O-saturated and H2O-undersaturated liquidus phase relations in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O-CO2 at 2 and 5 kbar. (In prep)
Huang WL, Wyllie PJ (1975) Melting reactions in the system NaAlSi3O8-KAlSi3O8-SiO2 to 35 kilobars, dry and with excess water. J Geol 83:737–748
Huang WL, Wyllie PJ (1986) Phase relationships of gabbro-tonalite-granite-water at 15 kbar with applications to differentiation and anatexis. Am Mineral 71:301–316
Johannes W (1978) Melting of plagioclase in the system Ab-An-H2O and Qz-Ab-An-H2O at PH2O=5 kbar, an equilibrium problem. Contrib Mineral Petrol 66:295–303
Johannes W (1984) Beginning of melting in the granite system Qz-Ab-Or-An-H2O. Contrib Mineral Petrol 84:264–273
Johannes W (1985) The significance of experimental studies for the formation of migmatites. In: Ashworth JR (ed) Migmatites. Blackie, Glasgow, pp 36–85
Keppler H (1989) The influence of the fluid phase composition on the solidus temperatures in the haplogranite system NaAlSi3O8-KAlSi3O8-SiO2-H2O-CO2. Contrib Mineral Petrol 102:321–327
Kerrick DM, Jacobs GK (1981) A modified redlich-kwong equation for H2O, CO2 and H2O-CO2 mixtures at elevated pressures and temperatures. Am J Sci 281:735–767
Kohn SC, Dupree R, Smith ME (1989) A multinuclear magnetic resonance study of the structure of hydrous albite glasses. Geochim Cosmochim Acta 53:2925–2935
Kroll H (1973) Estimation of the Al, Si distribution of feldspars from the lattice translations Tr(110) and Tr(110). I. alkali feldspars. Contrib Mineral Petrol 39:141–156
Lamb WM, Valley JW (1984) Metamorphism of reduced granulites in low-CO2 vapour-free environment. Nature 312:56–58
Lamb WM, Valley JW (1988) Granulite facies amphibole and biotite equilibria, and calculated peak-metamorphic water activities. Contrib Mineral Petrol 100:349–360
Le Breton N, Thompson AB (1988) Fluid-absent (dehydration) melting of biotite in metapelites in the early stages of crustal anatexis. Contrib Mineral Petrol 99:226–237
Luth WC (1969) The systems NaAlSi3O8-SiO2 and KAlSi3O8-SiO2 to 20 kb and the relationship between H2O-content, PH2O, and Ptotal in granitic magmas. Am J Sci A 267:325fx–341
Luth WC, Jahns RH, Tuttle OF (1964) The granite system at pressures of 4 to 10 kilobars. J Geophys Res 69:759–773
Luth WR, Boettcher AL (1986) Hydrogen and the melting of silicates. Am Mineral 71:264–276
Maaloe S, Wyllie PJ (1975) Water content of a granite magma deduced from the sequence of crystallization determined experimentally with water-undersaturated conditions. Contrib Mineral Petrol 52:175–191
Mc Millan P, Holloway JR (1987) Water solubility in aluminium silicate melts. Contrib Mineral Petrol 97:320–332
Mysen BO (1986) Volatiles in silicate melts at high pressure and temperature. Interaction between OH groups and Si4+, Al3+, Ca2+, Na+ and H+. Chem Geol 57:303–331
Naney MT (1983) Phase equilibria of rock-forming ferromagnesian silicates in granitic systems. Am J Sci 283:993–1033
Nekvasil H (1988) Calculated effect of anorthite component on the crystallization paths of H2O-undersaturated haplogranitic melts. Am Mineral 73:966–981
Orville PM (1963) Alkali ion exchange between vapor and feldspar phases. Am J Sci 261:201–237
Peterson JW, Newton RC (1989) CO2-enhanced melting of biotitebearing rocks at deep-crustal pressure-temperature conditions. Nature 340:378–380
Powers RE, Bohlen SR (1985) The role of synmetamorphic igneous rocks in the metamorphism and partial melting of metasediments, Northwest Adirondacks. Contrib Mineral Petrol 90:401–409
Ribbe PH (1983) Aluminium-silicon order in feldspars: domain textures and diffraction patterns. Reviews in Mineral 2, 2nd edn, pp 21–30
Silver L, Stolper EM (1989) Water in albitic glasses. J Petrology 30:667–710
Stern CR, Wyllie PJ (1981) Phase relationships of I-type granite with H2O to 35 kilobars: The Dinkey Lakes Biotite-Granite from the Sierra Nevada Batholith. J Geophys Res 86:10412–10422
Thompson AB (1982) Dehydration melting of pelitic rocks and the generation of H2O-undersaturated granitic liquids. Am J Sci 282:1567–1595
Tuttle OF, Bowen NL (1958) Origin of granite in the light of experimental studies in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O. Geol Soc Am Mem 74
Vielzeuf D, Holloway JR (1988) Experimental determination of the fluid-absent melting relations in the pelitic system. Consequences for crustal differentiation. Contrib Mineral Petrol 98:257–276
Wendland RT (1981) Influence of CO2 on melting of model granulite facies assemblages: a model for the genesis of charnockites. Am Mineral 66:1164–1174
White BS, Brearley M, Montana A (1989) Solubility of argon in silicate liquids at high pressures. Am Mineral 74:513–529
Whitney JA (1975) The effects of pressure, temperature and XH2O on phase assemblages in four synthetic rock compositions. J Geol 83:1–31
Whitney JA (1988) The origin of granite: The role and source of water in the evolution of granitic magmas. Geol Soc Am Bull 100:1886–1897
Winkler HGF (1979) Petrogenesis of metamorphic rocks, 5th edn. Springer, Berlin Heidelberg New York Tokyo
Ziegenbein D, Johannes W (1977) Gas chromatographic analysis of experimental high pressure hydrothermal fluids. Neues Jahrb Mineral Abh 130:145–149
Ziegenbein D, Johannes W (1982) Activities of CO2 in supercritical CO2-H2O mixtures derived from high-pressure mineral equilibrium data. In: Schreyer W (ed) High-Press Res Geosci, Schweizerbart, Stuttgart, pp 493–500
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Ebadi, A., Johannes, W. Beginning of melting and composition of first melts in the system Qz-Ab-Or-H2O-CO2 . Contr Mineral Petrol 106, 286–295 (1991). https://doi.org/10.1007/BF00324558
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DOI: https://doi.org/10.1007/BF00324558