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Recent Trends in Ironmaking Blast Furnace Technology to Mitigate CO2 Emissions: Top Charging Materials

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Ironmaking and Steelmaking Processes

Abstract

The iron- and steelmaking is the largest energy consuming in the industrial sectors. The high energy consumption is associated with emission of CO2 and other pollutants. The most common ironmaking process used in the world is the blast furnace which contributes around 70 % of the world’s steel production. Recently, blast furnace has undergone tremendous modifications and improvements to reduce the energy consumption and CO2 emissions. The modifications are being focused on two main approaches: (1) development of top charging materials and (2) injections of auxiliary fuels through blast furnace tuyeres. The present chapter will discuss the recent modifications and development in the top charging burden and how it could participate in minimizing the energy consumption and CO2 emissions for more efficient and sustainable iron and steel industry. The injection of auxiliary fuels will be discussed in details in another chapter. The enhancement of burden material quality and its charging mode into the blast furnace has resulted in a smooth and efficient operation. Recently, the usage of nut coke in the modern blast furnace is accompanied by higher production and lower reducing agent rates. An efficient recycling of in-plant fines by its conversion into briquettes with proper mechanical strength is applied in some blast furnaces to exploit the iron- and carbon-rich residues. Nowadays, novel composite agglomerates consist of iron ores and alternative carbonaceous materials represent a new trend for low-carbon blast furnace with lower dependence on the conventional burden materials. The recent investigations demonstrated that the novel composites are able to reduce the thermal reserve zone temperature in the blast furnace and consequently enhance the carbon utilization through its higher reactivity compared to fossil fuels. The top charging of bio-reducers and hydrogen-rich materials into the blast furnace is one of interesting innovations to mitigate the CO2 emissions. Although some of previous approaches are recently applied in the modern blast furnace, others are still under intensive discussions to enhance its implementations.

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References

  • Adolfsson D, Robinson R, Blagojevic J et al (2008) Assessment of ladle slag as binder alternative for cold bonded briquettes. In: Global symposium on recycling, waste treatment and clean technology, Cancun, Mexico, October 12–15, 2008 Minerals, Metals & Materials Society, pp 117–123

    Google Scholar 

  • Ahmed HM, Viswanathan N, Bjorkman B (2014) Composite pellets–a potential raw material for iron‐making. Steel Res Int 85(3):293–306

    Google Scholar 

  • Ariyama T, Murai R, Ishii J et al (2005) Reduction of CO2 emissions from integrated steel works and its subjects for a future study. ISIJ Int 45(10):1371–1378

    Article  Google Scholar 

  • Assis SP, Calixto OK, Vasques FI et al (2015) Economical feasibility of the use of biogas in iron- and steelmaking. In: AISTech (ed) The iron and steel technology conference and exposition, AISTech and ICSTI, 4–7 May 2015, pp 652–655

    Google Scholar 

  • Austin PR, Nogami H, Yagi J (1997) A mathematical model for blast furnace reaction analysis based on the four fluid model. ISIJ Int 37(8):748–755

    Article  Google Scholar 

  • Austin PR, Nogami H, Yagi J (1998) Analysis of actual blast furnace operations and evaluation of static liquid holdup effects by the four fluid model. ISIJ Int 38(3):246–255

    Article  Google Scholar 

  • Babich A, Senk D, Yaroshevskiy S et al (2008) Effect of nut coke on blast furnace shaft permeability. In: Proc. 3rd international conference on process development in iron and steelmaking (SCANMET III), 8–11 June 2008, Lulea, Sweden, vol 2, pp 227–236

    Google Scholar 

  • Babich A, Senk D, Gudenau HW (2009) Effect of coke reactivity and nut coke on blast furnace operation. Ironmaking Steelmaking 36(3):222–229. doi:10.1179/174328108x378242

    Google Scholar 

  • Biswas AK (1981) Principles of blast furnace ironmaking: theory and practice. Cootha Publishing House, Australia, 528 pp

    Google Scholar 

  • Butterworth P, Linsley K, Aumonier J (1996) Hydrocyclone treatment of blast furnace slurry within British Steel. Revue de Metallurgie Cahiers d’Informations Techniques (France) 93(6):807–815

    Google Scholar 

  • Castro JAd, Nogami H, Yagi J (2000) Transient mathematical model of blast furnace based on multi-fluid concept, with application to high PCI operation. ISIJ Int 40(7):637–646

    Google Scholar 

  • Chu M, Nogami H, Yagi J (2004) Numerical analysis on charging carbon composite agglomerates into blast furnace. ISIJ Int 44(3):510–517

    Article  Google Scholar 

  • Dutta SK, Ghosh A (1994) Study of nonisothermal reduction of iron ore-coal/char composite pellet. MMTB 25(1):15–26. doi:10.1007/bf02663174

    Article  Google Scholar 

  • Fruehan RJ (1977) The rate of reduction of iron oxides by carbon. MTB 8(1):279–286. doi:10.1007/bf02657657

    Article  Google Scholar 

  • Greedes M, Toxopeus H, van der Vliet C (2009) Modern blast furnace ironmaking-an introduction. IOS Press BV, The Netherlands

    Google Scholar 

  • Grip C (2005) Steel and sustainability: Scandinavian perspective. Ironmaking Steelmaking 32(3):235–241

    Article  Google Scholar 

  • Hata Y, Purwanto H, Hosokai S et al (2009) Biotar ironmaking using wooden biomass and nanoporous iron ore. Energy Fuel 23(2):1128–1131. doi:10.1021/ef800967h

    Article  Google Scholar 

  • Hayashi S (2009) Reaction behavior of coal composite iron ore hot briquettes in a laboratory scale blast furnace simulator. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 423–427

    Google Scholar 

  • Heerema RH, Kortmann H, Kater T et al (1989) Improvements of acid, olivine and dolomite fluxed iron ore pellets using an organic binder. In: The 5th international symposium on agglomeration, Brighton, p 227

    Google Scholar 

  • Heijwegen C, Kat W (1984) Beneficiation of blast furnace sludge. World Steel Metalwork Exp Man, pp 35–39

    Google Scholar 

  • Huang BH, Lu WK (1993) Kinetics and mechanisms of reactions in iron ore/coal composites. ISIJ Int 33(10):1055–1061

    Article  Google Scholar 

  • Iguchi Y, Takada Y (2004) Rate of direct reactions measured in vacuum of iron ore-carbon composite pellets heated at high temperatures: influence of carbonaceous materials, oxidation degree of iron oxides and temperature. ISIJ Int 44(4):673–681

    Article  Google Scholar 

  • Itoh Y, Fieser A (1982) Zinc removal from blast furnace dust. Iron Steel Eng 59(8):33–36

    Google Scholar 

  • Janiana M, Eduardo O, Antonio V et al (2009) Study of the behavior of biomass, coal and mixtures at their injection into blast furnace. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 804–808

    Google Scholar 

  • Kasai A, Matsui Y (2004) Lowering of thermal reserve zone temperature in blast furnace by adjoining carbonaceous material and iron ore. ISIJ Int 44(12):2073–2078

    Google Scholar 

  • Kashiwaya Y, Kanbe M, Ishii K (2001) Reaction behavior of facing pair between hematite and graphite: a coupling phenomenon of reduction and gasification. ISIJ Int 41(8):818–826. doi:10.2355/isijinternational.41.818

    Google Scholar 

  • Khaki JV, Kashiwaya Y, Ishii K et al (2002) Intensive improvement of reduction rate of hematite–graphite mixture by mechanical milling. ISIJ Int 42(1):13–22

    Article  Google Scholar 

  • Lacroix P, Dauwels G, Dufresne P et al (2001) High blast furnaces productivity operations with low coke rates in the European Union. Revue de Métallurgie 98(03):259–268

    Article  Google Scholar 

  • Loginov V, Berin A, Solomatin S (1977) Effect of mixing burden with coke on blast furnace fluid mechanics and operation parameters. Stal 5:391

    Google Scholar 

  • Loginov V, Solomatin S, Korzh A (1976) Experimental melts with blast furnaces charged with mixture of coke and sinter. Metallurgist 20(4):245–250

    Article  Google Scholar 

  • Luengen HB, Peters M, Schmoele P (2012) Ironmaking in Western Europe. Iron Steel Technol 9(3):63–69

    Google Scholar 

  • Mantovani MC, Takano C (2000) The strength and the high temperature behaviors of self-reducing pellets containing EAF dust. ISIJ Int 40(3):224–230

    Article  Google Scholar 

  • Matsui K, Hata Y, Hosokai S et al (2009) Biotar ironmaking using wooden biomass and nano-porous iron ore. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 1292–1296

    Google Scholar 

  • Matsui Y, Sawayama M, Kasai A et al (2003) Reduction behavior of carbon composite iron ore hot Briquette in shaft furnace and scope on blast furnace performance reinforcement. ISIJ Int 43(12):1904–1912

    Article  Google Scholar 

  • Matsumura T, Ichida M, Nagasaka T et al (2008) Carbonization behaviour of woody biomass and resulting metallurgical coke properties. ISIJ Int 48(5):572–577. doi:10.2355/isijinternational.48.572

    Google Scholar 

  • Michishita H, Tanaka H (2010) Prospects for coal-based direct reduction process. Kobelco Technol Rev 69(29):76

    Google Scholar 

  • Min G, Xiao-hui F, Zhen-hui Z et al (2009) Fundamental research on applying organic binder SHN to oxidized pellets. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 327–331

    Google Scholar 

  • Mousa E, Senk D, Babich A (2010) Reduction of Pellets‐Nut coke mixture under simulating blast furnace conditions. Steel Res Int 81(9):706–715

    Google Scholar 

  • Mousa E, Senk D, Babich A et al (2010) Influence of nut coke on iron ore sinter reducibility under simulated blast furnace conditions. Ironmaking Steelmaking 37(3):219–228

    Google Scholar 

  • Mousa E (2010) Reduction of iron ore burden materials mixed with nut coke under simulated blast furnace conditions. PhD thesis, RWTH Aachen University, Shaker verlag, Aachen

    Google Scholar 

  • Mousa EA, Babich A, Senk D (2011) Effect of nut coke-sinter mixture on the blast furnace performance. ISIJ Int 51(3):350–358

    Article  Google Scholar 

  • Naito M, Okamoto A, Yamaguchi K et al (2006) Improvement of blast furnace reaction efficiency by temperature control of thermal reserve zone (UDC 669.162.263)

    Google Scholar 

  • Ng KW, Giroux L, MacPhee T et al (2012) Combustibility of charcoal for direct injection in blast furnace ironmaking. Iron Steel Technol 9(3):70–76

    Google Scholar 

  • Nikitin L, Mar’yasov M, Gorbachev V et al (1999) Blast-furnace operation with coke fines. Metallurgist 43(1):30–33

    Article  Google Scholar 

  • Nishioka K, Osuga K, Ueki Y et al (2009) Effect of iron and coal properties on reduction and gasification behavior of carbon composite iron ore briquette. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 1326–1330

    Google Scholar 

  • Nomura S, Ayukawa H, Kitaguchi H et al (2005) Improvement in blast furnace reaction efficiency through the use of highly reactive calcium rich coke. ISIJ Int 45(3):316–324

    Article  Google Scholar 

  • Nomura S, Kitaguchi H, Yamaguchi K et al (2007) The characteristics of catalyst-coated highly reactive coke. ISIJ Int 47(2):245–253

    Article  Google Scholar 

  • Ökvist LS, Brandell C, Lundgren M (1999) Impact of activated nut coke on energy efficiency in the blast furnace. In: AISTech (ed) The iron and steel technology conference and exposition. AISTech, Indianapolis

    Google Scholar 

  • Pandey B, Yadav U (1999) Blast furnace performance as influenced by burden distribution. Ironmaking Steelmaking 26(3):187–192

    Article  Google Scholar 

  • Peacey JG, Davenport WG (1979) The iron blast furnace: theory and practice. Pergamon, New York

    Google Scholar 

  • Podkorytov A, Kuznetsov A, Dymchenko E et al (2009) Theoretical and experimental foundations for preparing coke for blast-furnace smelting. Metallurgist 53(5–6):322–328

    Article  Google Scholar 

  • Qiu G, Jiang T, Li H et al (2003) Functions and molecular structure of organic binders for iron ore pelletization. Colloids Surf A Physicochem Eng Asp 224(1–3):11–22. doi:10.1016/S0927-7757(03)00264-4

    Google Scholar 

  • Ranade M, Chaubal P (2004) An intensive course—blast furnace ironmaking. McMaster University, Hamilton, pp 9–1

    Google Scholar 

  • Rao YK (1971) The kinetics of reduction of hematite by carbon. MT 2(5):1439–1447. doi:10.1007/bf02913373

    Google Scholar 

  • Rao YK, Han HG (1984) Catalysis by alkali carbonates of carbothermic reduction of magnetite concentrates. Ironmaking Steelmaking 11(6):308–318

    Google Scholar 

  • Reddy GV, Sharma T, Chakravorty S (1991) Kinetic rate equation for direct reduction of iron ore by non-coking coal. Ironmaking Steelmaking 18(3):211–215

    Google Scholar 

  • Rist A, Bonnivard G (1963) Reduction of an iron oxide bed with a gas. Rev Metal 60:23–38

    Google Scholar 

  • Robinson R (2005) High temperature properties of by-product cold bonded pellets containing blast furnace flue dust. Thermochim Acta 432(1):112–123. doi:10.1016/j.tca.2005.04.015

    Google Scholar 

  • Robinson R (2008) Studies in low temperature self-reduction of by-products from integrated iron and steelmaking. PhD thesis, Luleå University of Technology, Luleå, 69 pp

    Google Scholar 

  • Sawayama M, Miyagawa K, Nozawa K, Matsui Y, Shibata K (2009a) Low coke rate operation of blast furnace by controlling size of coke mixed into ore layer. In Proceedings of the 5th international congress on the science and technology of ironmaking, ICSTI 09, 20–22 October 2009, pp 663–667, Shanghai

    Google Scholar 

  • Sawayama M, Miyagawa K, Nozawa K et al (2009b) Low coke rate operation of blast furnace by controlling size of coke mixed into ore layer. In: The 5th international congress on the science and technology of ironmaking, Baosteel Research Institute, Shanghai, China, pp 659–663

    Google Scholar 

  • Schmöle P, Lüngen H-B (2005) Ecological hot metal production using the coke plant and blast furnace route. Rev Metal 102(03):171–182. doi:10.1051/metal:2005140

    Google Scholar 

  • Seaton CE, Foster JS, Velasco J (1983) Reduction kinetics of hematite and magnetite pellets containing coal char. Trans Iron Steel Inst Jpn 23(6):490–496

    Article  Google Scholar 

  • Sharma T (1997) Reduction of double layered iron ore pellets. Int J Mineral Process 49(3–4):201–206. doi:10.1016/S0301-7516(96)00020-8

    Google Scholar 

  • Singh M (2002) Studies on the cement-bonded briquettes of iron and steel plant by-products as burden material for blast furnace. PhD thesis, Luleå University of Technology, Lulrå. ISSN 1402–1544

    Google Scholar 

  • Souza RPd, Mendonca CFd, Kater T (1984) Production of acid iron ore pellet for direct reduction, using an organic binder. Mining Eng 36:1437

    Google Scholar 

  • Srinivasan NS, Lahiri AK (1977) Studies on the reduction of hematite by carbon. MTB 8(1):175–178. doi:10.1007/bf02656367

    Article  Google Scholar 

  • Srivastava U, Kawatra SK, Eisele TC (2013) Production of pig iron by utilizing biomass as a reducing agent. Int J Miner Process 119:51–57

    Article  Google Scholar 

  • Steer JM, Griffiths AJ (2013) Investigation of carboxylic acids and non-aqueous solvents for the selective leaching of zinc from blast furnace dust slurry. Hydrometallurgy 140:34–41

    Article  Google Scholar 

  • Strezov V (2006) Iron ore reduction using sawdust: experimental analysis and kinetic modelling. Renew Energy 31(12):1892–1905

    Article  Google Scholar 

  • Su F, Lampinen H, Robinson R (2004) Recycling of sludge and dust to the BOF converter by cold bonded pelletizing. ISIJ Int 44(4):770–776

    Article  Google Scholar 

  • Sun S, Lu WK (1999a) Building of a mathematical model for the reduction of iron ore in ore/coal composites. ISIJ Int 39(2):130–138

    Article  Google Scholar 

  • Sun S, Lu WK (1999b) A theoretical investigation of kinetics and mechanisms of iron ore reduction in an ore/coal composite. ISIJ Int 39(2):123–129

    Article  Google Scholar 

  • Takano C, Mourao MB (2001) Comparison of high temperature behavior of self-reducing pellets produced from iron ore with that of dust from sintering plant. ISIJ Int 41(Suppl):S22–S26

    Article  Google Scholar 

  • Ueda S, Yanagiya K, Watanabe K et al (2009a) Reaction model and reduction behavior of carbon iron ore composite in blast furnace. ISIJ Int 49(6):827–836

    Article  Google Scholar 

  • Ueda S, Watanabe K, Yanagiya K et al (2009b) Improvement of reactivity of carbon iron ore composite with biomass char for blast furnace. ISIJ Int 49(10):1505–1512

    Article  Google Scholar 

  • Ueki Y, Yoshiie R, Naruse I et al (2013) Reaction behavior during heating biomass materials and iron oxide composites. Fuel 104(0):58–61. doi:10.1016/j.fuel.2010.09.019

    Google Scholar 

  • Van Herck P, Vandecasteele C, Swennen R et al (2000) Zinc and lead removal from blast furnace sludge with a hydrometallurgical process. Environ Sci Technol 34(17):3802–3808

    Article  Google Scholar 

  • Vereš J, Lovás M, Jakabský Š et al (2012) Characterization of blast furnace sludge and removal of zinc by microwave assisted extraction. Hydrometallurgy 129:67–73

    Google Scholar 

  • Watakabe S, Takeda K, Nishimura H et al (2006) Development of high ratio coke mixed charging technique to the blast furnace. ISIJ Int 46(4):513–522

    Article  Google Scholar 

  • Yaroshevskii S, Nozdrachev V, Chebotarev A et al (2000) Efficiency of using coke fractions smaller than 40 mm in a blast furnace. Metallurgist 44(11):598–605

    Article  Google Scholar 

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Acknowledgment

The partial financial support from the Centre of Advanced Mining and Metallurgy (CAMM) at Luleå University of Technology and the Postdoc grant at Swerea MEFOS funded by Swedish Research Council Formas are greatly acknowledged.

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Authors and Affiliations

  1. MiMeR-Minerals and Metallurgical Engineering, Luleå University of Technology, SE-971 87, Luleå, Sweden

    Hesham M. Ahmed

  2. Minerals Technology Division, Central Metallurgical Research and Development Institute, 87-Helwan, Cairo, Egypt

    Hesham M. Ahmed & E. A. Mousa

  3. Process Integration Department, Swerea MEFOS, SE-971 25, Luleå, Sweden

    E. A. Mousa & M. Larsson

  4. Energy Engineering, Department of Engineering and Mathematics, Luleå University of Technology, 971 87, Luleå, Sweden

    M. Larsson

  5. Department of Metallurgical Engineering and Materials Science, Centre of Excellence in Steel Technology (CoEST), IIT Bombay, Mumbai, 400076, India

    N. N. Viswanathan

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  1. Hesham M. Ahmed
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Correspondence to E. A. Mousa .

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  1. Department of Innovation Engineering, University of Salento, Lecce, Italy

    Pasquale Cavaliere

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Ahmed, H.M., Mousa, E.A., Larsson, M., Viswanathan, N.N. (2016). Recent Trends in Ironmaking Blast Furnace Technology to Mitigate CO2 Emissions: Top Charging Materials. In: Cavaliere, P. (eds) Ironmaking and Steelmaking Processes. Springer, Cham. https://doi.org/10.1007/978-3-319-39529-6_6

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