Abstract
Single pellet experiments have been carried out in a nitrogen atmosphere to study the reduction of hematite by graphite in the temperature range 925 to 1060°C. The effect of variables such as c/Fe2O3 molar ratio, pellet size, and so forth, has been investigated. Gas analysis data show a continuous decrease in CO2/CO ratio during reduction, the values being far away from Fe/FeO equilibrium for wustite reduction by CO. The activation energies associated with different degrees of reduction appear to be widely different suggesting a possible changeover in reaction mechanism during the progress of reduction. X-ray diffraction studies confirm the stepwise nature of hematite reduction.
Similar content being viewed by others
References
B. G. Baldwin:J. Iron Steel Inst. London, 1955, vol. 179, pp. 30–36.
T. S. Yun:Trans. ASM, 1961, vol. 54, pp. 129–42.
A. Prasad and R. H. Tupkary:Ind. J. Technol, 1973, vol. 11, pp. 245–49.
H. K. Kohl and B. Marincek:Arch. Eisenhuettenw., 1965, Vol. 36, pp. 851–59.
V. I. Arkharov and V. N. Bogoslouski:Zh. Fiz. Khim., 1955, vol. 29, p. 272.
H. K. Kohl and H. J. Engell:Arch. Eisenhuettenw., 1963, vol. 34, p. 411.
R. Eck:Berg. Huettenmaenn.Monatsh., 1968, vol. 113, pp. 11–26.
K. Otsuka and D. Kunii:J. Chem. Eng. Jap., 1969, vol. 2, pp. 46–50.
P. C. Ghosh and S. N. Tiwari:J. Iron Steel Inst. London, 1970, vol. 208, pp. 255–57.
H. Ree and M. Tate:Tetsu To Hagane, 1971, vol. 57, pp. 465–84.
Y. K. Rao:Met. Trans., 1972, vol. 3, pp. 1439–47.
N. S. Srinivasan: Ph.D. Thesis, Indian Institute of Science, April, 1976.
T. Sugata {iret al}:Trans. Iron Steel Inst. Jap., 1974, vol. 14, pp. 88.
T.E.Dancey:J. Iron Steel Inst., 1951,vol. 169, pp. 17–24.
D. R. MacRae:J. Metals, 1965, vol. 17, pp. 1391–95.
Author information
Authors and Affiliations
Additional information
Formerly Research Scholar in the Department of Metallurgy, Indian Institute of Science, Bangalore-560012, India,
Rights and permissions
About this article
Cite this article
Srinivasan, N.S., Lahiri, A.K. Studies on the reduction of hematite by carbon. Metall Trans B 8, 175–178 (1977). https://doi.org/10.1007/BF02656367
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02656367