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N-Tris[(2-aminoethyl)-2-(diphenylphosphoryl) acetamide)] — novel CMPO tripodand: synthesis, extraction studies and luminescent properties of lanthanide complexes

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Central European Journal of Chemistry

Abstract

A ligand system containing three carbamoylmethylphosphine oxide (CMPO) moieties attached to a tripodal platform with a central nitrogen atom has been synthesized for metal complexation and extraction from neutral and nitric acid solutions. Liquid-liquid extractions performed for Ln(III), both from neutral and acidic media, show excellent extraction properties which exceeded those for the known mono- and di-CMPO derivatives as well as the related tripodands. A considerable enhancement of the DLn values was observed in the presence of IL ([bmim][Tf2N]) in the organic phase towards lanthanide ions from 3M HNO3 solutions. The protonation of the central amine nitrogen atom of the ligand 1 in the acidic media provides also the effective extraction of the perrhenate anionic complexes. The europium complexes formed by mono- and tris-CMPO ligands in the solid state, as well as Eu(III) and Tb(III) complexes generated in solutions, possess intensive luminescence at 300K

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    Elena V. Sharova, Oleg I. Artyushin & Irina L. Odinets

  2. Institute of Solid State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    Alexander N. Turanov

  3. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    Vasilii K. Karandashev

  4. A.V. Bogatsky Physico-chemical Institute, National Academy of Sciences of Ukraine, 65080, Odessa, Ukraine

    Svetlana B. Meshkova & Zoya M. Topilova

Authors
  1. Elena V. Sharova
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  2. Oleg I. Artyushin
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  3. Alexander N. Turanov
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  4. Vasilii K. Karandashev
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  7. Irina L. Odinets
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Correspondence to Irina L. Odinets.

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Sharova, E.V., Artyushin, O.I., Turanov, A.N. et al. N-Tris[(2-aminoethyl)-2-(diphenylphosphoryl) acetamide)] — novel CMPO tripodand: synthesis, extraction studies and luminescent properties of lanthanide complexes. cent.eur.j.chem. 10, 146–156 (2012). https://doi.org/10.2478/s11532-011-0124-5

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