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High-Performance Alkyl Diamide Amine and Water-soluble Diamide Ligand for Separating of Am(III) from Cm(III)

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Abstract

Alkyl diamide amine (ADAAM), a new high-performance reagent with a simple structure, was examined for the mutual separation of Am(III) and Cm(III). The combination of ADAAM and N,N,N′,N′-tetraethyldiglycolamide (TEDGA) as a masking agent shows selectivity for Am(III) over Cm(III) in highly acidic media with separation factors of up to 41.

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Acknowledgments

The authors acknowledge the staff of Chemicrea Industries for the organic synthesis and Mr. T. Kurosawa, M. Shibata, T. Kawasaki, H. Sagawa and S. Urabe of the JAEA for performing solvent extraction experiments.

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Authors and Affiliations

  1. Nuclear Science and Engineering Center, Japan Atomic Energy Agency (JAEA), Tokai-mura, Ibaraki, 319-1195, Japan

    Hideya Suzuki, Yasuhiro Tsubata & Tatsuro Matsumura

Authors
  1. Hideya Suzuki
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  2. Yasuhiro Tsubata
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  3. Tatsuro Matsumura
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Correspondence to Hideya Suzuki.

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Suzuki, H., Tsubata, Y. & Matsumura, T. High-Performance Alkyl Diamide Amine and Water-soluble Diamide Ligand for Separating of Am(III) from Cm(III). ANAL. SCI. 33, 239–242 (2017). https://doi.org/10.2116/analsci.33.239

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  • DOI: https://doi.org/10.2116/analsci.33.239

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