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Neutral Red and Safranin Т in the Photopolymerization of Methyl Methacrylate and Other (Meth)Acrylate Monomers

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Abstract

Features of the polymerization of methyl methacrylate and a number of other (meth)acrylate monomers in the presence of catalytic systems based on phenazine dyes (Neutral Red and Safranin Т) under visible light irradiation are investigated. It is shown that amines of various structure as well as air oxygen affect the kinetic features of polymerization and the molecular weight characteristics of polymers. It is found that polymerization may proceed in the controlled mode up to high conversions at room temperature and a low photocatalyst concentration, among them without preliminary degassing of the reaction medium.

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REFERENCES

  1. N. Corrigan, K. Jung, G. Moad, G. Yawker, K. Matyjaszewski, and C. Boyer, Prog. Polym. Sci. 111, 101311 (2020).

  2. D. F. Grishin and I. D. Grishin, Rus. Chem. Rev. 90, 231 (2021).

    Article  CAS  Google Scholar 

  3. B. P. Fors and C. J. Hawker, Angew. Chem., Int. Ed. Engl. 51, 1 (2012).

    Article  Google Scholar 

  4. N. A. Romero and D. A. Nicewicz, Chem. Rev. 161 (17), 10075 (2016).

    Article  Google Scholar 

  5. L. Candish, K. D. Collins, G. C. Cook, J. J. Douglas, A. Gómez-Suárez, A. Jolit, and S. Keess, Chem. Rev. 122 (2), 2907 (2022).

    Article  CAS  PubMed  Google Scholar 

  6. N. J. Treat, H. Sprafke, J. W. Kramer, P. G. Clark, B. E. Barton, J. Read De Alaniz, B. P. Fors, and C. J. Hawker, J. Am. Chem. Soc. 136 (45), 16096 (2014).

    Article  CAS  PubMed  Google Scholar 

  7. N. Corrigan, S. Shanmugam, J. Xu, and C. Boyer, Chem. Soc. Rev. 45, 6165 (2016).

    Article  CAS  PubMed  Google Scholar 

  8. S. de Avila Gonzalves, P. R. Rodrigues, and R. Pioli Vieira, Macromol. Rapid. Commun. 42 (15), 2100221 (2021).

  9. D. A. Corbin and G. M. Miyake, Chem. Rev. 122 (2), 1830 (2022).

    Article  CAS  PubMed  Google Scholar 

  10. A. Allushi, C. Kutahya, C. Aydogan, J. Kreutzer, G. Yilmaz, and Y. Yagci, Polym. Chem. 8 (1), 1972 (2017).

    Article  CAS  Google Scholar 

  11. C. Kutahya, F. S. Aykac, G. Yilmaz, and Y. Yagci, Polym. Chem, No. 7, 6094 (2016).

  12. S. P. Pitre, C. D. McTiernan, H. Ismaili, and J. C. Scaiano, J. Am. Chem. Soc. 135 (36), 13286 (2013).

    Article  CAS  PubMed  Google Scholar 

  13. D. Leow, Org. Lett. 16 (21), 5812 (2014).

    Article  CAS  PubMed  Google Scholar 

  14. A. Aguirre-Soto, C.-H. Lim, A. T. Hwang, C. B. Musgrave, and J. W. Stansbury, J. Am. Chem. Soc. 136 (20), 7418 (2014).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  15. A. Gallastegui, M. B. Spesia, I. E. dell’Erba, C. A. Chesta, C. M. Previtali, R. E. Palacios, and M. L. Gomez, J. Mater. Sci. Eng. C 102, 896 (2019).

  16. D. F. Grishin, O. S. Lizyakina, L. B. Vaganova, A. A. Kaltenberg, and I. D. Grishin, Iran. Polym. J. 30 (11), 1117 (2021).

    Article  CAS  Google Scholar 

  17. O. S. Lizyakina, L. B. Vaganova, and D. F. Grishin, Polym. Sci., Ser. B, 65 (3), 270 (2023).

  18. A. J. Gordon and R. A. Ford, A Handbook of Practical Data, Techniques, and References (Wiley, New York, 1972).

    Google Scholar 

  19. Polymer Characterization: Laboratory Techniques and Analysis, Ed by N. P. Cheremisinoff (Noyes Publications, Westwood, 1997).

    Google Scholar 

  20. R. Pauliukaite and C. M. A. Brett, Electroanalysis 20 (12), 1275 (2008).

  21. G. T. Marks, E. D. Lee, D. A. Aikens, and H. H. Richto, J. Photochem. Photobiol. 39 (3), 323 (1984).

    Article  CAS  Google Scholar 

  22. A. N. Azarian, S. Berchmans, and V. Yegnaraman, Bull. Electrochem. 14 (10), 309 (1998).

    Google Scholar 

  23. A. C. Bhasikuttan and A. V. Sapre, J. Photochem. Photobiol. 69 (5), 529 (1999).

    Article  Google Scholar 

  24. M. V. Encinas, C. M. Previtali, S. G. Bertolotti, and M. G. Neumann, J. Photochem. Photobiol. 62 (1), 65 (1995).

    Article  CAS  Google Scholar 

  25. G. V. Porcal, E. M. Arbeloa, C. A. Chesta, S. G. Bertolotti, and C. M. Previtali, J. Photochem. Photobiol., A 257 (1), 60 (2013).

    Article  CAS  Google Scholar 

  26. V. S. F. Chew, J. R. Bolton, R. G. Brown, and G. Porter, J. Phys. Chem. 84 (15), 1909 (1980).

    Article  CAS  Google Scholar 

  27. C. E. Baumgartner, H. Richtol, and D. A. Aiken, J. Photochem. Photobiol. 34, 17 (1981).

    Article  CAS  Google Scholar 

  28. Padon K. Sirovatka and A. B. Scranton, J. Polym. Sci., Part A: Polym. Chem. 38 3336 (2000).

    Article  Google Scholar 

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Funding

This work was supported by the Russian Science Foundation (project no. 23-23-00130).

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Authors and Affiliations

  1. National Research Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, Russia

    O. S. Lizyakina, L. B. Vaganova & D. F. Grishin

Authors
  1. O. S. Lizyakina
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  2. L. B. Vaganova
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  3. D. F. Grishin
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Correspondence to O. S. Lizyakina.

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Translated by T. Soboleva

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Lizyakina, O.S., Vaganova, L.B. & Grishin, D.F. Neutral Red and Safranin Т in the Photopolymerization of Methyl Methacrylate and Other (Meth)Acrylate Monomers. Polym. Sci. Ser. B 65, 398–408 (2023). https://doi.org/10.1134/S1560090423701099

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  • DOI: https://doi.org/10.1134/S1560090423701099

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