Skip to main content
SpringerLink
Log in

Features of Methyl Methacrylate Polymerization Mediated by Methylene Blue and Ethyl 2-Bromoisobutyrate under Photoirradiation Conditions

  • POLYMERIZATION
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

Using methyl methacrylate polymerization as an example, the features of polymer synthesis in the presence of the catalytic system [methylene blue + ethyl 2-bromoisobutyrate] at room temperature under visible light irradiation are investigated. The effect of polymerization conditions, including the light irradiation wavelength and various structure activators, on the monomer conversion and molecular weight characteristics of polymers is estimated. It is shown that polymerization can proceed in the controlled mode under mild temperature conditions according to the atom transfer mechanism (Metal Free Atom Transfer Radical Polymerization) to high conversions at low photocatalyst concentrations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. N. Corrigan, J. Yeow, P. Judzewitsch, J. Xu, and C. Boyer, Angew. Chem., Int. Ed. Engl. 58, 5170 (2019).

    Article  CAS  PubMed  Google Scholar 

  2. K. Jung, N. Corrigan, M. Ciftci, J. Xu, S. E. Seo, C. J. Hawker, and C. Boyer, Adv. Mater. 32, 1903850 (2020).

  3. S. de Avila Goncalves, P. R. Rodrigues, and R. Vieira Pioli, Macromol. Rapid Commun. 42, 2100221 (2021).

  4. N. Corrigan, K. Jung, G. Moad, C. J. Hawker, K. Matyjaszewski, and C. Boyer, Prog. Polym. Science 111, 101311 (2020).

  5. Y.-N. Zhou, J.-J. Li, T.-T. Wang, Y.-Y. Wu, and Z.‑H. Luo, Prog. Polym. Sci. 130, 101555 (2022).

  6. D. F. Grishin and I. D. Grishin, Russ. Chem. Rev. 90 (2), 231 (2021).

    Article  CAS  Google Scholar 

  7. J. C. Theriot, C.-H. Lim, H. Yang, M. D. Ryan, C. B. Musgrave, and G. M. Miyake, Science 352, 1082 (2016).

    Article  CAS  PubMed  Google Scholar 

  8. F. Dumur, Eur. Polym. J. 126, 109564 (2020).

  9. C. Wu, N. Corrigan, C.-H. Lim, W. Liu, G. Miyake, and C. Boyer, Chem. Rev. 122, 5476 (2022).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  10. A. J. Gordon and R. A. Ford, A Handbook of Practical Data. Techniques and References (Wiley, New York, 1972).

    Google Scholar 

  11. Polymer Characterization: Laboratory Techniques and Analysis, Ed. by N. P. Cheremisinoff (Westwood: Noyes Publications, 1996).

    Google Scholar 

  12. T. G. Ribelli, F. Lorandi, M. Fantin, and K. Matyjaszewski, Macromol. Rapid Commun. 40 (1), 1800616 (2019).

  13. D. F. Grishin, O. S. Lizyakina, L. B. Vaganova, A. A. Kaltenberg, and I. D. Grishin, Iran. Polym. J. 30 (11), 1117 (2021).

    Article  CAS  Google Scholar 

  14. N. J. Treat, H. Sprafke, J. W. Kramer, P. G. Clark, B. E. Barton, J. R. de Alaniz, B. P. Fors, and C. J. Hawker, J. Am. Chem. Soc. 136 (10), 16096 (2014).

    Article  CAS  PubMed  Google Scholar 

  15. X. Pan, C. Fang, M. Fantin, N. Malhotra, Y. W. So, A. Linda, L. A. Peteanu, A. A. Isse, A. Gennaro, P. Liu, and K. Matyjaszewski, J. Am. Chem. Soc. 138 (7), 2411 (2016).

    Article  CAS  PubMed  Google Scholar 

  16. P. Spencer, S. P. Pitre, C. D. McTiernan, and J. C. Scaiano, ACS Omega 1 (1), 66 (2016).

    Article  Google Scholar 

  17. A. Mills and J. Wang, J. Photochem. Photobiol., A 127, 123 (1999).

    Article  CAS  Google Scholar 

  18. N. A. Knyazeva and I. D. Grishin, Polym. Sci., Ser. B 64 (5), 590 (2022).

    Article  CAS  Google Scholar 

  19. O. Impert, A. Katafias, P. Kita, and A. Mill, A. Pictkiemicz-Graczyk, and G. Wrzeszcz, Dalton Trans., No. 3, 348 (2003).

  20. A. N. Morozov, G. N. Fadeev, and N. A. Bogatov, Her. Bauman Moscow State Tech. Univ., Ser. Nat. Sci., No. 1, 141 (2022).

  21. S.-K. Lee and A. Mills, Chem. Commun. 59, 2366 (2003).

    Article  Google Scholar 

  22. A. Fernández-Pérez, T. Valdés-Solis, and G. Marbán, Dyes Pigm. 161, 448 (2019).

    Article  Google Scholar 

  23. Y. Galagan and W.-F. Su, J. Photochem. Photobiol., A 195 (2–3), 378 (2008).

  24. K. Heclik, J. Duliban, B. Debska, and J. Lubczak, Int. J. Anal. Chem. Art. ID 2879869 (2019).

  25. R. H. Kayser and R. H. Young, Photochem. Photobiol. 24 (5), 395 (1976).

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation (project no. 23-23-00130).

Author information

Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, Russia

    O. S. Lizyakina, L. B. Vaganova & D. F. Grishin

Authors
  1. O. S. Lizyakina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. B. Vaganova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. F. Grishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. S. Lizyakina.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by T. Soboleva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lizyakina, O.S., Vaganova, L.B. & Grishin, D.F. Features of Methyl Methacrylate Polymerization Mediated by Methylene Blue and Ethyl 2-Bromoisobutyrate under Photoirradiation Conditions. Polym. Sci. Ser. B 65, 270–283 (2023). https://doi.org/10.1134/S1560090423700975

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090423700975

Search

Navigation