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Enhancement of Catalytic Activity for Benzene Hydroxylation over Novel V2O5/HZSM-5 Catalyst

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Abstract

In this paper, a novel V2O5/HZSM-5 catalyst was prepared and characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, mapping, inductively coupled plasma spectrometry, nitrogen physical desorption and X-ray photoelectron spectroscopy in order to expound the structure-activity relationship. The results showed that the conversion of benzene was 73.5%, the selectivity of phenol was over 99.0% under the optimal reaction conditions, and the stability of catalyst was also effectively improved.

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Funding

We acknowledge financial support from the National Nature Science Foundation of China (grant nos. 212006065 and 21666018) and Gansu Province Science and Technology Program (20JR10RA190).

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Authors and Affiliations

  1. College of Petrochemical Engineering, Lanzhou University of Technology, 730050, Lanzhou, P.R. China

    C. Li, G. Li, P. Dong, H. Li, W. Meng & D. Zhang

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  1. C. Li
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  2. G. Li
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  3. P. Dong
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  4. H. Li
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  5. W. Meng
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Correspondence to G. Li or P. Dong.

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Li, C., Li, G., Dong, P. et al. Enhancement of Catalytic Activity for Benzene Hydroxylation over Novel V2O5/HZSM-5 Catalyst. Kinet Catal 62, 279–287 (2021). https://doi.org/10.1134/S0023158421020075

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  • DOI: https://doi.org/10.1134/S0023158421020075

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