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Specific Features of the Catalytic Hydrogenation of the Norbornadiene-Based Carbocyclic Compounds

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Abstract

The gas- and liquid-phase hydrogenation of bicyclo[2.2.1]hepta-2,5-diene (norbornadiene) in the presence of the Pd/γ-Al2O3 (PK-25) industrial palladium catalyst in an n-heptane medium at 75–200°С is studied. The reaction products are identified, the main reaction routes are established, and the material balance is studied. The effect of preferable adsorption of norbornadiene compared to other components of the system on the palladium active site is confirmed. A relationship between possible modes of norbornadiene coordination and the product structure is considered. A parallel-sequential scheme is proposed for the mechanism of the process on the basis of the obtained experimental and theoretical data.

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ACKNOWLEDGMENTS

This work was carried out using equipment of the Center for Collective Use of the Russian Technological University MIREA supported by the Ministry of Education and Science of the Russian Federation.

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Authors and Affiliations

  1. MIREA—Russian Technological University, Institute of Fine Chemical Technologies, Moscow, Russia

    V. V. Zamalyutin, E. A. Katsman, V. Ya. Danyushevsky, V. R. Flid, V. V. Podol’skii & A. V. Ryabov

Authors
  1. V. V. Zamalyutin
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  2. E. A. Katsman
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  3. V. Ya. Danyushevsky
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  4. V. R. Flid
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  5. V. V. Podol’skii
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  6. A. V. Ryabov
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Corresponding authors

Correspondence to V. V. Zamalyutin or V. R. Flid.

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The authors declare that they have no conflicts of interest.

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Dedicated to blessed memory of outstanding scientist Il’ya Iosifovich Moiseev

Translated by E. Yablonskaya

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Zamalyutin, V.V., Katsman, E.A., Danyushevsky, V.Y. et al. Specific Features of the Catalytic Hydrogenation of the Norbornadiene-Based Carbocyclic Compounds. Russ J Coord Chem 47, 695–701 (2021). https://doi.org/10.1134/S1070328421100080

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  • DOI: https://doi.org/10.1134/S1070328421100080

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