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Extraction Properties of Diphenylposphorylureas with Aliphatic ω-Nitrogen-Containing Substituents

  • PHYSICAL CHEMISTRY OF SOLUTIONS
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Abstract

Extraction of lanthanides and actinides from nitric acid solutions with N-(diphenylphosphoryl)-N'-n-propylureas containing imidazolyl, diethylamino, pyrid-2-yl, 2-oxopyrrolidino fragments in the ω position of the alkyl substituent has been studied. It has been shown that Ho(III) and Yb(III) related to the yttrium subgroup of lanthanides are extracted much better than La(III) and Nd(III) related to the cerium subgroup. N-(Diphenylphosphoryl)urea containing ω-(2-oxopyrrolidino)propyl fragment at the terminal nitrogen atom shows the best extraction properties. This dependence has been theoretically explained by modeling complexation because the coordination of f-block element ion with amide oxygen atom is more preferable

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ACKNOWLEDGMENTS

This work was supported by the Ministry of Science and Higher Education of the Russian Federation using equipment of the Center for Molecular Structure Studies, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.

The computations were performed on a MVS-50K Supercomputer of the Joint Supercomputer Center, Russian Academy of Sciences (www.jscc.ru).

Funding

Computations were supported by the Russian Science Foundation (project no. 16–13–10451).

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Authors and Affiliations

  1. Bochvar High-Technology Research Institute of Inorganic Materials, 123098, Moscow, Russia

    A. M. Safiulina & A. V. Lizunov

  2. Moscow State University, 119991, Moscow, Russia

    N. E. Borisova

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    T. V. Baulina, E. I. Goryunov, I. B. Goryunova & V. K. Brel’

Authors
  1. A. M. Safiulina
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  2. A. V. Lizunov
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  3. N. E. Borisova
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  4. T. V. Baulina
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  5. E. I. Goryunov
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  6. I. B. Goryunova
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  7. V. K. Brel’
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Correspondence to A. M. Safiulina.

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Additional information

In memory of eminent Soviet and Russian organophosphorus chemist E. E. Nifant’ev, Corresponding Member of the RAS

Translated by I. Kudryavtsev

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Safiulina, A.M., Lizunov, A.V., Borisova, N.E. et al. Extraction Properties of Diphenylposphorylureas with Aliphatic ω-Nitrogen-Containing Substituents. Russ. J. Inorg. Chem. 66, 731–739 (2021). https://doi.org/10.1134/S0036023621050156

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