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Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions with Mixtures of N-(Diphenylphosphoryl)-N'-propylureas with ω-Nitrogen-Containing Groups and Dinonylnaphthalenesulfonic Acid

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Abstract

Extraction of uranium, thorium, and lanthanide(III) ions from nitric acid solutions with mixtures of dinonylnaphthalenesulfonic acid and N-(diphenylphosphoryl)-N'-n-propylureas containing imidazolyl, diethylamino, pyrid-2-yl, and 2-oxopyrrolidine fragments has been studied in organic solvents. Considerable synergetic effect on extraction of metal ions with mixtures of dinonylnaphthalenesulfonic acid and N-(diphenylphosphoryl)-N'-[3-(2-oxopyrrolidino)propyl]urea has been revealed. Stoichiometry of extracted complexes has been determined. Effect of extractant strucuture, organic diluent nature, and HNO3 content in aqueous phase on extraction efficiency of metal cations into organic medium has been accessed.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation under the State Assignment of 2022 for the Osipyan Institute of Solid-State Physics, Russian Academy of Sciences, the Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences; and the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (Contract no. 075–00697–22–00).

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Authors and Affiliations

  1. Osipyan Institute of Solid-State Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    A. N. Turanov

  2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. K. Karandashev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    T. V. Baulina, E. I. Goryunov & V. K. Brel

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  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. T. V. Baulina
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  4. E. I. Goryunov
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  5. V. K. Brel
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Corresponding author

Correspondence to V. K. Brel.

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The authors declare no conflicts of interest.

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Translated by I. Kudryavtsev

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Turanov, A.N., Karandashev, V.K., Baulina, T.V. et al. Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions with Mixtures of N-(Diphenylphosphoryl)-N'-propylureas with ω-Nitrogen-Containing Groups and Dinonylnaphthalenesulfonic Acid. Russ. J. Inorg. Chem. 68, 587–592 (2023). https://doi.org/10.1134/S0036023623600399

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  • DOI: https://doi.org/10.1134/S0036023623600399

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