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Kinetics and possible mechanism of hydrogen chloride oxidation over supported copper-containing salt catalysts: I. Kinetics of HCl oxidation in the deacon and methane oxychlorination reactions over a copper-potassium salt catalyst

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Abstract

The kinetics of HCl oxidation at 350–425°C over a (CuCl2-KCl)/support catalyst in two complementary processes—Deacon and methane oxychlorination reactions—has been investigated using a gradientless technique. This has allowed the range of \(P_{Cl_2 }\) in the reaction mixture to be markedly extended. New kinetic features of HCl oxidation under conditions such that this process does and does not depend on P HCl have been discovered. The kinetic equations obtained in this study fit experimental data in a wider range of conditions than the equations proposed earlier. The results of this study suggest the existence of two HCl oxidation pathways in the Deacon reaction.

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  1. Karpov Institute of Physical Chemistry, Moscow, 105064, Russia

    A. G. Aglulin

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Original Russian Text © A.G. Aglulin, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 5, pp. 599–609.

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Aglulin, A.G. Kinetics and possible mechanism of hydrogen chloride oxidation over supported copper-containing salt catalysts: I. Kinetics of HCl oxidation in the deacon and methane oxychlorination reactions over a copper-potassium salt catalyst. Kinet Catal 55, 571–581 (2014). https://doi.org/10.1134/S0023158414050012

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