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Trisubstituted 1,3,5-Triazines. 6. Synthesis of 2,4,6-Tris(acetonyl)-1,3,5-triazine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Acylation of 2,4,6-tris(tert-butoxycarbonylmethyl)-1,3,5-triazine with acetic anhydride in the presence of lithium hydride with subsequent removal of the tert-butoxycarbonyl groups with trifluoroacetic acid leads to 2,4,6-tris(acetonyl)-1,3,5-triazine, the cyclic analog of α-cyanoacetone. The special spectral features of this compound compared with triazines obtained previously are discussed.

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Authors and Affiliations

  1. Russian Academy of Sciences, Institute of Problems of Chemical Physics, Chernogolovka, 142432, Moscow region

    A. V. Shastin

  2. Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, Moscow, 117913

    T. I. Godovikova & B. L. Korsunskii

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  1. A. V. Shastin
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  2. T. I. Godovikova
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  3. B. L. Korsunskii
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Shastin, A.V., Godovikova, T.I. & Korsunskii, B.L. Trisubstituted 1,3,5-Triazines. 6. Synthesis of 2,4,6-Tris(acetonyl)-1,3,5-triazine. Chemistry of Heterocyclic Compounds 39, 1037–1040 (2003). https://doi.org/10.1023/B:COHC.0000003521.99022.fb

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  • DOI: https://doi.org/10.1023/B:COHC.0000003521.99022.fb

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