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Corrosion formation and phase transformation of nickel-iron hydroxide nanosheets array for efficient water oxidation

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Abstract

Designing earth-abundant electrocatalysts with high performance towards water oxidation is highly decisive for the sustainable energy technologies. This study develops a facile natural corrosion approach to fabricate nickel-iron hydroxides for water oxidation. The resulted electrode demonstrates an outstanding activity and stability with an overpotential of 275 mV to deliver 10 mA·cm−2. Experimental and theoretical results suggest the corrosion-induced formation of hydroxides and their transformation to oxyhydroxides would account for this excellent performance. This work not only provides an interesting corrosion approach for the fabrication of excellent water oxidation electrode, but also bridges traditional corrosion engineering and novel materials fabrication, which would offer some insights in the innovative principles for nanomaterials and energy technologies.

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Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (No. 22075092), China Postdoctoral Science Foundation (No. 2018M642810), and the Program for HUST Academic Frontier Youth Team (No. 2018QYTD15). We also acknowledge the support of Analytical and Testing Center of Huazhong University of Science and Technology for Raman, SEM, and TEM measurements.

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Authors and Affiliations

  1. Key laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), Hubei Key Laboratory of Material Chemistry and Service Failure, Wuhan National Laboratory for Optoelectronics, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan, 430074, China

    Lanqian Gong, Junlei Wang, Shenghua Chen, Bo You, Zehua Dong, Hongfang Liu & Bao Yu Xia

  2. School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430074, China

    Huan Yang

  3. Institute for Advanced Study, Nanchang University, Nanchang, 330000, China

    Hongming Wang

  4. Department of Information Science and Technology, East China Normal University, Shanghai, 200240, China

    Ruijuan Qi

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  1. Lanqian Gong
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  5. Junlei Wang
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  9. Hongfang Liu
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  10. Bao Yu Xia
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Correspondence to Bao Yu Xia.

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Gong, L., Yang, H., Wang, H. et al. Corrosion formation and phase transformation of nickel-iron hydroxide nanosheets array for efficient water oxidation. Nano Res. 14, 4528–4533 (2021). https://doi.org/10.1007/s12274-021-3366-3

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  • DOI: https://doi.org/10.1007/s12274-021-3366-3

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