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A library of carbon-supported ultrasmall bimetallic nanoparticles

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Abstract

Small-sized bimetallic nanoparticles that possess numerous accessible metal sites and optimal geometric/electronic structures show great promise for advanced synergetic catalysis but remain synthetic challenge so far. Here, an universial synthetic method is developed for building a library of bimetallic nanoparticles on mesoporous sulfur-doped carbon supports, consisting of 24 combinations of 3 noble metals (that is, Pt, Rh, Ir) and 7 other metals, with average particle sizes ranging from 0.7 to 1.4 nm. The synthetic strategy is based on the strong metal-support interaction arising from the metal-sulfur bonding, which suppresses the metal aggregation during the H2-reduction at 700 °C and ensure the formation of small-sized and alloyed bimetallic nanoparticles. The enhanced catalytic properties of the ultrasmall bimetallic nanoparticles are demonstrated in the dehydrogenation of propane at high temperature and oxidative dehydrogenations of N-heterocycles.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China (Nos. 2018YFA0702001 and 2019YFA0307900), the National Natural Science Foundation of China (Nos. 21671184, 11874334, and 21872128), Youth Innovation Promotion Association CAS (No. 2020458), the Fundamental Research Funds for the Central Universities (Nos. WK2060190103 and WK2060030030), the Joint Funds from Hefei National Synchrotron Radiation Laboratory (No. KY2060000107), and the Recruitment Program of Thousand Youth Talents.

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Authors and Affiliations

  1. Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China

    Shi-Long Xu, Shan-Cheng Shen, Shuai Zhao, Lu-Jie Zuo, Ming-Xi Chen, Lei Wang, Yan-Wei Ding, Yue Lin & Hai-Wei Liang

  2. Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, CAS Key Laboratory of Materials for Energy Conversion and Department of Chemical Physics, University of Science and Technology of China, Hefei, 230026, China

    Ze-Yue Wei & Kun Qian

  3. School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601, China

    Ping Chen

  4. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China

    Sheng-Qi Chu

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  1. Shi-Long Xu
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Correspondence to Yue Lin, Kun Qian or Hai-Wei Liang.

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Xu, SL., Shen, SC., Wei, ZY. et al. A library of carbon-supported ultrasmall bimetallic nanoparticles. Nano Res. 13, 2735–2740 (2020). https://doi.org/10.1007/s12274-020-2920-8

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  • DOI: https://doi.org/10.1007/s12274-020-2920-8

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