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Design of low-loaded NiRe bimetallic catalyst on N-doped mesoporous carbon for highly selective deoxygenation of oleic acid to n-heptadecane

  • Catalysis, Reaction Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Using nitrogen-doped mesoporous carbon (NMC) as the support, several NiRe bimetallic catalysts with low metal loading of 1 wt% were designed and prepared for the selective deoxygenation of oleic acid to n-heptadecane in the absence of hydrogen. Results showed that the Ni80Re20/NMC catalyst with a Ni/Re molar ratio of 80: 20 achieved the highest yield of n-heptadecane (92.3%) at 330 °C for 2 h in isopropanol solvent, and at a metal/oleic acid weight ratio of 1: 333. The catalyst can be reused at least five times with slight activity loss. Combined with the results of in-situ XRD, HRTEM, XPS and CO2-TPD, the formation of NiRe alloy, the very fine NiRe nanoparticle size at 2.30 nm, as well as the hydrophobic, mesoporous and weakly basic properties of the NMC support surface were demonstrated to contribute to the excellent catalytic performance of the catalyst.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China [21878269 and 21476211]; and the Zhejiang Provincial Natural Science Foundation of China [LY16B060004 and LY18B060016]; and Jiangxi Qilin Chemical Industry Co., Ltd [YX-[2012]008@].

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Authors and Affiliations

  1. Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Xihu District, Hangzhou, 310027, P. R. China

    Zuojun Wei & Yuran Cheng

  2. Institute of Zhejiang University-Quzhou, 78 Jinhua Boulevard North, Quzhou, 324000, P. R. China

    Zuojun Wei & Yuran Cheng

  3. Research and Development Base of Catalytic Hydrogenation, College of Pharmaceutical Science, Zhejiang University of Technology, 18 Chaowang Road, Xiacheng District, Hangzhou, 310014, P. R. China

    Mengting Chen, Yuhua Ye & Yingxin Liu

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  1. Zuojun Wei
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  2. Yuran Cheng
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  4. Yuhua Ye
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  5. Yingxin Liu
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Correspondence to Yingxin Liu.

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11814_2022_1079_MOESM1_ESM.pdf

Design of low-loaded NiRe bimetallic catalyst on N-doped mesoporous carbon for highly selective deoxygenation of oleic acid to n-heptadecane

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Wei, Z., Cheng, Y., Chen, M. et al. Design of low-loaded NiRe bimetallic catalyst on N-doped mesoporous carbon for highly selective deoxygenation of oleic acid to n-heptadecane. Korean J. Chem. Eng. 39, 1753–1761 (2022). https://doi.org/10.1007/s11814-022-1079-2

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  • DOI: https://doi.org/10.1007/s11814-022-1079-2

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