In the absence of segregation of nanodisperse graphite particles, obtained by electrolysis as a new filler of polyvinyl chloride (PVC), the viscoelastic phenomena dependent on the structural changes of a composite are investigated. The shear modulus and the volume compressibility caused by deviations of elements of the structure from the quasi-equilibrium state under the action of ultrasonic vibrations (ω = 0.4·106 0.4 · 10 s–1) are calculated at filler concentrations 0 ≤ φ ≤ 10.0 vol.% and temperatures 298 K ≤ T ≤ (Tg + 10) K. It is shown that the volume density of internal energy depends on the expectation time for the transition of structural elements through the energy barrier, the dynamic viscosity of the material, and temperature. The results of calculations serve as the basis for producing PVC systems with controllable of properties.
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References
H. R. and M. Salehi, “Experimental study on the mechanical, creep, and viscoelastic behavior of TiO2/glass/epoxy hybrid nanocomposites,” Mech. Compos. Mater., 52, No. 5, 623-636 (2016).
V. V. Zuev, S. V. Kostromin, and A. V. Shlykov, “ The effect of fullerene fillers on the mechanical properties of polymer nanocomposites,” Mech. Compos. Mater., 46, No. 2, 147-154 (2010).
B. B. Kolupaev, “Study on the viscoelastic properties of metal-filler PVC on the basis of the potential of inter- and intramolecular interaction,” Inzh.-Fiz. Zhurn., 80, No.1, 178-185 (2007).
M. M. Shokri and R. Rafiee, “A review of the mechanical properties of isolated carbon nanotubes and carbon nanotube composites,” Mech. Compos. Mater., 46, No. 2, 155-172 (2010).
B. B. Кolupaev, V. V. Klepko, and E. V. Lebedev, “The relaxation processes of a nanofilled PVC in sound range frequency,” Acoustic Bulletin, 15, No. 2,. 43-48 (2012).
S. K. Nechaev, “Problems of probalistic topology: statistics of nodes and noncommutative random walk,” Ispekhi Fiz. Nauk, 168, No. 4, 369-405 (1998).
A. Dixit and Harlal Singh Mali, “Modeling techniques for predicting the mechanical properties of woven-fabric textile composites,” Mech. Compos. Mater., 49, No. 1, 3-30 (2013).
V. F. Kuropatenko, “Model of a multicomponent medium,” Dokl. RAN, 403, No. 6, 761-763 (2005).
S. Ya. Frenkel, I. M. Tsigel’nyi, and B. S. Kolupaev, Molecular Cybernetics [in Russian], L., Svit (1990).
G. M. Bartenev and S. Ya. Frenkel, Polymer Physics [in Russian], L., Khimia (1990).
B. S. Kolupaev, Relaxation and Thermal Properties of Filled Polymer Systems [in Russian], eds. S. Ya. Frenkel, L., LGU (1980).
M. I. Ojovan, “Thermodynamic parameters of bonds in glassy materials from viscosity-temperature relationships,” J. Phys: Condensed Matter., 19, No. 41, 41-51 (2007).
Patent No. 92078 Ukraine, IPC C22B19/00, C01G9/00. Method of electrolytic preparation of fine zinc oxide / Yu. P. Lavorik, B. D. Nechiporuk, M. Yu. Novoselytsky, B. P. Rudik, V. V. Filonenko, O. V. Parasyuk. No. 200812571; stated on Oct. 27, 2008; publ. Feb. 25, 2009, Bull. No. 4.
A. L. Volynskii, Structural Self-Organization of Amorphous Polymers [in Russian], M., Fizmatlit (2005).
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Translated from Mekhanika Kompozitnykh Materialov, Vol. 54, No. 3, pp. 489-500 , May-June, 2018.
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Kolupaev, B.B., Kolupaev, B.S., Levchuk, V.V. et al. Effect of a Nanodisperse Graphite on the Viscoelastic Properties of Polyvinyl Chloride. Mech Compos Mater 54, 333–340 (2018). https://doi.org/10.1007/s11029-018-9743-7
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DOI: https://doi.org/10.1007/s11029-018-9743-7