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Tailoring changes in the physical, structural and linear optical properties of SrCuTi2Fe14O27 W-type hexaferrite-doped PVA polymeric composite films

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Abstract

Physical, structural and optical properties of thin films of PVA and PVA with different content of SrCuTi2Fe14O27 W-type hexaferrite are investigated in the present work. The hexaferrite is prepared by the ceramic method, while the thin films are prepared by the casting method. The physical and structural features are studied by using X-ray diffraction patterns (XRD) and Fourier transform infrared spectroscopy (FTIR). The XRD indicates the formation of W-type hexagonal ferrite besides the M-type and spinel ferrite. The observed FTIR spectra indicate information about the vibration modes in this studied samples. The optical analysis is done and the calculated direct optical energy band gap is increased, while the indirect optical energy band gap is decreased. The Urbach tail (Eu) energy decreases with increasing SrCuTi2Fe14O27 to PVA, respectively. The band gap from ε′′ plot (Ego) and refractive index (n) values are calculated from the optical data for all investigated samples.

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Authors and Affiliations

  1. Physics Department, Faculty of Science, Tanta University, Tanta, 31527, Egypt

    M. M. Ali, O. M. Hemeda & A. M. A. Henaish

  2. NANOTECH Center, Ural Federal University, Ekaterinburg, 620002, Russia

    A. M. A. Henaish

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Ali, M.M., Hemeda, O.M. & Henaish, A.M.A. Tailoring changes in the physical, structural and linear optical properties of SrCuTi2Fe14O27 W-type hexaferrite-doped PVA polymeric composite films. J Mater Sci: Mater Electron 32, 16038–16051 (2021). https://doi.org/10.1007/s10854-021-06153-5

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