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A study on high rate and high stable sodium vanadium phosphate electrode for sodium battery alongside air exposure treatment

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Abstract

The compound Na3V2(PO4)3/C (NVP) is an identical prevalent cathode for sodium-ion batteries (SIBs) because of its high Na+-ion mobility and structural stability. To the best of our knowledge, this is the first attempt deals with the comparison between the cathode materials (NVP) synthesized via the sol–gel method and the as-synthesized material exposed in air for 10 days (Air-NVP). To understand the impact of air exposure of NVP has been analyzed for structural and electrochemical performances. It reveals that the Air-NVP sample exhibits reduced specific capacity than NVP due to the sluggish diffusion kinetics without affecting the crystal structure and chemical valence state.

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Acknowledgements

All the authors from Alagappa University acknowledge the financial support by DST SERB, New Delhi under the Physical sciences, Grant sanctioned vide EMR/2016/006302, PURSE and FIST Programme, sponsored by Department of Science and Technology (DST), SAP by University Grants Commission (UGC), New Delhi, Govt. of India and Ministry of Human Resource Development RUSA- Phase 2.0 Grant sanctioned vide Lt.No.F-24-51/2014 U Policy (TNMulti Gen), Dept. of Education, Govt. of India.

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Authors and Affiliations

  1. #120 Energy Material Lab, Department of Physics, Alagappa University, Science Block, Karaikudi, Tamil Nadu, 630003, India

    K. Diwakar, P. Rajkumar, R. Subadevi, P. Arjunan & M. Sivakumar

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  1. K. Diwakar
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  2. P. Rajkumar
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  3. R. Subadevi
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  4. P. Arjunan
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Correspondence to R. Subadevi or M. Sivakumar.

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Diwakar, K., Rajkumar, P., Subadevi, R. et al. A study on high rate and high stable sodium vanadium phosphate electrode for sodium battery alongside air exposure treatment. J Mater Sci: Mater Electron 32, 14186–14193 (2021). https://doi.org/10.1007/s10854-021-05969-5

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