Abstract
Vanadium pentoxide as the cathode material for sodium-ion batteries (SIBs) has attracted wide attention due to its high theoretical capacity, relatively low price, and easy preparation. However, the poor structural stability and bad electronic conductivity severely hamper its practical application. Herein, vanadium pentoxide/titanium dioxide (V2O5/TiO2) composite was prepared by a hydrothermal method with commercial vanadium pentoxide, hydrogen peroxide, and titanium dioxide as raw materials. Compared to pureV2O5, the V2O5/TiO2 composite exhibits higher sodium storage activity and better rate capability (with specific capacities of 141.7 and 31.6 mA h g−1 at 100 and 1000 mA g−1, respectively). SEM characterization shows that the V2O5 material changed from nanosheet morphology to nanorod morphology after compositing with TiO2. Cyclic voltammetry analysis reveals that the V2O5/TiO2 composite has obvious pseudocapacitive behavior during the discharge/charge processes. EIS analysis demonstrates that the introduction of TiO2 in V2O5 decreases the electrochemical reaction resistance upon repeated cycling. This work provides a simple and efficient method for the preparation of vanadium-based cathode material for SIBs.
Similar content being viewed by others
References
Hameer S, Van Niekerk JL (2015) A review of large-scale electrical energy storage. Int J Energy Res 39:1179–1195
Poullikkas A (2013) A comparative overview of large-scale battery systems for electricity storage. Renew Sustain Energy Rev 27:778–788
Gür TM (2018) Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage. Energy Environ Sci 11:2696–2767
Eftekhari A (2019) Lithium batteries for electric vehicles: from economy to research strategy. ACS Sustain Chem Eng 7(6):5602–5613
Zubi G, Dufo-López R, Carvalho M, Pasaoglu G (2018) The lithium-ion battery: state of the art and future perspectives. Renew Sustain Energy Rev 89:292–308
Li M, Lu J, Chen Z, Amine K (2018) 30 years of lithium-ion batteries. Adv Mater 30(33):1800561
Yi T, Qu J, Lai X, Han X, Chang H, Zhu Y (2021) Toward high-performance Li storage anodes: design and construction of spherical carbon-coated CoNiO2 materials. Mater Today Chem 19:100407
Massé RC, Uchaker E, Cao G (2015) Beyond Li-ion: electrode materials for sodium- and magnesium-ion batteries. Sci China Mater 58:715–766
Yi T, Sari HMK, Li X, Wang F, Zhu Y, Hu J, Zhang J, Li X (2021) A review of niobium oxides based nanocomposites for lithium-ion batteries, sodium-ion batteries and supercapacitors. Nano Energy 85:105955
Nayak PK, Yang L, Brehm W, Adelhelm P (2018) From lithium-ion to sodium-ion batteries: advantages challenges, and surprises. Angew Chem Int Ed 57:102–120
Delmas C (2018) Sodium and sodium-ion batteries: 50 years of research. Adv Energy Mater 8(17):1703137
Hwang JY, Myung ST, Sun YK (2017) Sodium-ion batteries: present and future. Chem Soc Rev 46:3529–3614
Xiang X, Zhang K, Chen J (2015) Recent advances and prospects of cathode materials for sodium-ion batteries. Adv mater 27(36):5343–5364
Luo W, Gaumet JJ, Mai L (2017) Nanostructured layered vanadium oxide as cathode for high-performance sodium-ion batteries: a perspective. MRS Commun 7(2):152–165
Yao J, Li Y, Massé RC, Uchaker E, Cao G (2018) Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond. Energy Storage Mater 11:205–259
Yan D, Zhu X, Wang K, Gao X, Feng Y, Sun K, Liu Y (2016) Facile and elegant self-organization of Ag nanoparticles and TiO2 nanorods on V2O5 nanosheets as a superior cathode material for lithium-ion batteries. J Mater Chem A 4:4900–4907
Yi T, Qiu L, Qu J, Liu H, Zhang J, Zhu Y (2021) Towards high-performance cathodes: design and energy storage mechanism of vanadium oxides-based materials for aqueous Zn-ion batteries. Coord Chem Rev 446:214124
Cai Y, Fang G, Zhou J, Liu S, Luo Z, Pan A, Cao G, Liang S (2017) Metal-organic framework-derived porous shuttle-like vanadium oxides for sodium-ion battery application. Nano Res 11:449–463
Uchaker E, Zheng Y, Li S, Candelaria SL, Hu S, Cao G (2014) Better than crystalline: amorphous vanadium oxide for sodium-ion batteries. J Mater Chem A 2:18208–18214
Tang H, Peng Z, Wu L, Xiong F, Pei C, An Q, Mai L (2018) Vanadium-based cathode materials for rechargeable multivalent batteries: challenges and opportunities. Electrochem Energy R 1:169–199
Wang G, Su D (2013) Single-crystalline bilayered v2o5 nanobelts for high-capacity sodium-ion batteries. ACS Nano 7(12):11218–11226
Wei Q, Liu J, Feng W, Sheng J, Tian X, He L, An Q, Mai L (2015) Hydrated vanadium pentoxide with superior sodium storage capacity. J Mater Chem A 3:8070–8075
Kim H, Kim RH, Lee SS, Kim Y, Kim DY, Park K (2014) Effects of Ni doping on the initial electrochemical performance of vanadium oxide nanotubes for Na-ion batteries. ACS Appl Mater Interfaces 6(14):11692–11697
Su D, Dou S, Wang G (2015) Hierarchical vanadium pentoxide spheres as high-performance anode materials for sodium-ion batteries. Chemsuschem 8(17):2877–2882
Li F, Zhou Z (2018) Micro/nanostructured materials for sodium ion batteries and capacitors. Small 14(6):1702961
Li Y, Liu C, Xie Z, Yao J, Cao G (2017) Superior sodium storage performance of additive-free V2O5 thin film electrodes. J Mater Chem A 5:16590–16594
Li Y, Yao J, Uchaker E, Zhang M, Tian J, Liu X, Cao G (2013) Sn-doped V2O5 film with enhanced lithium-ion storage performance. J Phys Chem C 117(45):23507–23514
Wang D, Cai P, Zou G, Hou H, Ji X, Tian Y, Long Z (2021) Ultra-stable carbon-coated sodium vanadium phosphate as cathode material for sodium-ion battery. Rare Met. https://doi.org/10.1007/s12598-021-01743-y
Ding G, Zhu L, Yang Q, Xie L, Cao X, Wang Y, Liu J, Yang X (2020) NaV3O8/poly(3,4-ethylenedioxythiophene) composites as high-rate and long-lifespan cathode materials for reversible sodium storage. Rare Met 39:865–873
Li Y, Ji J, Yao J, Zhang Y, Huang B, Cao G (2021) Sodium ion storage performance and mechanism in orthorhombic V2O5 single-crystalline nanowires. Sci China Mater 64:557–570
Liu C, Yao J, Zou Z, Li Y, Cao G (2019) Boosting the cycling stability of hydrated vanadium pentoxide by Y3+ pillaring for sodium-ion batteries. Mater Today Energy 11:218–227
Muller-Bouvet D, Baddour-Hadjean R, Tanabe M, Huynh LTN, Le MLP, Pereira-Ramos JP (2015) Electrochemically formed α’-NaV2O5: a new sodium intercalation compound. Electrochim Acta 176:586–593
Yao J, Li Y, Pan G, Jin X, Luo K, Le S (2021) Electrochemical property of hierarchical flower-like α-Ni(OH)2 as an anode material for lithium-ion batteries. Solid State Ion 363:115595
Chu B, Liu S, You L, Liu D, Huang T, Li Y, Yu A (2020) Enhancing the cycling stability of Ni-rich LiNi0.6Co0.2Mn0.2O2 cathode at a high cutoff voltage with Ta doping. ACS Sustain Chem Eng 8(8):3082–3090
Kurc B, Pigłowska M (2021) An influence of temperature on the lithium ions behavior for starch-based carbon compared to graphene anode for LIBs by the electrochemical impedance spectroscopy (EIS). J Power Sources 485:229323
Hong C, Leng Q, Zhu J, Zheng S, He H, Li Y, Liu R, Wan J, Yang Y (2020) Revealing the correlation between structural evolution and Li+ diffusion kinetics of nickel-rich cathode materials in Li-ion batteries. J Mater Chem A 8:8540–8547
Rui XH, Ding N, Liu J, Li C, Chen CH (2010) Analysis of the chemical diffusion coefficient of lithium ions in Li3V2(PO4)3 cathode material. Electrochim Acta 55(7):2384–2390
Yao J, Zhang Y, Yan J, Bin H, Li Y, Xiao S (2018) Nanoparticles-constructed spinel ZnFe2O4 anode material with superior lithium storage performance boosted by pseudocapacitance. Mater Res Bull 104:188–193
John W, Julien P, James L, Dunn B (2007) Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles. J Phys Chem C 111(40):14925–14931
Qi H, Cao L, Li J, Huang J, Xu Z, Cheng Y, Kong X, Yanagisawa K (2016) High pseudocapacitance in FeOOH/rGO composites with superior performance for high rate anode in Li-ion battery. ACS Appl Mater Interfaces 8(51):35253–35263
Pu X, Zhao D, Fu C, Chen Z, Cao S, Wang C, Cao Y (2021) Understanding and calibration of charge storage mechanism in cyclic voltammetry curves. Angew Chem Int Ed 60(39):21310–21318
Li H, Zhou L, Zhang L, Fan C, Fan H, Wu X, Sun H, Zhang J (2017) Co3O4 nanospheres embedded in a nitrogen-doped carbon framework: an electrode with fast surface-controlled redox kinetics for lithium storage. ACS Energy Lett 2(1):52–59
Xiao Y, Xu C, Wang P, Fang H, Sun X, Ma F, Pei Y, Zhen L (2018) Encapsulating MnO nanoparticles within foam-like carbon nanosheet matrix for fast and durable lithium storage. Nano Energy 50:675–684
Acknowledgements
This work was supported by the National Natural Science Foundation of China (No. 51664012 and 22065010) and Guangxi Natural Science Foundation of China (2015GXNSFGA139006).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhang, Y., Li, Y., Chi, G. et al. Preparation and sodium ions storage performance of vanadium pentoxide/titanium dioxide composite. Ionics 27, 5179–5186 (2021). https://doi.org/10.1007/s11581-021-04292-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-021-04292-7