Skip to main content
SpringerLink
Log in

Engineering Dandelion-Like Hollow TS-1@SiO2: Structural Design and Oxidation Application

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Inspired via the dandelion structure which has multi-dimensional channels facilitating the transport of fluids, bilayer TS-1@dandelion-SiO2 and hollow HTS@dandelion-SiO2 were successfully synthesized via an hydrothermal strategy including core TS-1 or HTS particles synthesis and an epitaxial growth of regular SiO2 shell. TS-1@dandelion-SiO2 or hollow HTS@dandelion-SiO2 possessed a ca. 300 nm core with ca. 100–200 nm of SiO2 shell with perpendicular channels, this hierarchical structure facilitated reactants/products transportation, and the structured SiO2 shell triggered the size of TS-1 or HTS and increased to ~ 800 nm, which was beneficial for nanosized crystals separation and recovery from the reaction system. Particularly, the epitaxial SiO2 shell increased Lewis acid sties on TS-1 and HTS external surface enhancing cyclohexene conversion. Further, the relationship between SiO2 shell morphology and catalytic activity was explored through the synthesis of HTS@inordinance-SiO2 with irregular SiO2 shell indicating the superiority of oriented channels originated from regular SiO2 shell.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Scheme 1

Similar content being viewed by others

References

  1. Přech J (2018) Catal Rev 60:71

    Article  Google Scholar 

  2. Kerstens D, Smeyers B, Waeyenberg JV, Zhang Q, Yu J, Sels BF (2020) Adv Mater 32:2004690

    Article  CAS  Google Scholar 

  3. Yang YQ, Zheng ZH, Yang MH, Chen JF, Li C, Zhang CH, Zhang XD (2020) J Hazard Mater 399:123070

    Article  CAS  PubMed  Google Scholar 

  4. Yang YQ, Ji WQ, Li XY, Lin HD, Chen HJ, Bi FK, Zheng ZH, Xu JC, Zhang XD (2022) J Hazard Mater 424:127640

    Article  CAS  PubMed  Google Scholar 

  5. Zhang XD, Xiang S, Du QX, Bi FK, Xie KL, Wang L (2022) Mol Catal 522:112226

    Article  CAS  Google Scholar 

  6. Jiang ST, Zhao ZY, Chen JF, Yang Y, Ding CY, Yang YQ, Wang YX, Liu N, Wang L, Zhang XD (2022) Surf Interfaces 30:101843

    Article  CAS  Google Scholar 

  7. Zhang K, Ostraat ML (2016) Catal Today 264:3

    Article  CAS  Google Scholar 

  8. Kim J, Chun J, Ryoo R (2015) Chem Commun 51:13102

    Article  CAS  Google Scholar 

  9. Zhong WZ, Qiao T, Dai J, Mao LQ, Xu Q, Zou GQ, Liu XX, Yin DL, Zhao FP (2015) J Catal 330:208

    Article  CAS  Google Scholar 

  10. Kim SK, Reddy BM, Park SE (2018) Ind Eng Chem Res 57:3567

    Article  CAS  Google Scholar 

  11. Feng X, Sheng N, Liu YB, Chen XB, Chen D, Yang CH, Zhou XG (2017) ACS Catal 7:2668

    Article  CAS  Google Scholar 

  12. Schmidt I, Krogh A, Wienberg K, Carlsson A, Brorson M, Jacobsen CJH (2000). Chem Commun. https://doi.org/10.1039/b006460m

    Article  Google Scholar 

  13. Laha SC, Kumar R (2002) J Catal 208:339

    Article  CAS  Google Scholar 

  14. Ok DY, Jiang NZ, Prasetyanto EA, Jin HL, Park SE (2011) Microporous Mesoporous Mater 141:2

    Article  CAS  Google Scholar 

  15. Mahmoudi H, Bagherzadeh M, Ataie S, Kia R, Moravej SH, Zare M, Raithby PR, Ferlin F, Vaccaro L (2020) Inorganic Chim Acta 511:119775

    Article  CAS  Google Scholar 

  16. Zhang HY, Xu LF, Chang XY, Miao SS, Sun YT, Jia MJ (2021) Chin J Catal 42:2265

    Article  CAS  Google Scholar 

  17. Du Q, Guo YP, Wu P, Liu HZ, Chen YJ (2019) Microporous Mesoporous Mater 275:61

    Article  CAS  Google Scholar 

  18. Song XJ, Yang XT, Zhang TJ, Zhang H, Zhang Q, Hu DW, Chang XY, Li YY, Chen ZY, Jia MJ, Zhang P, Yu JH (2020) Inorg Chem 59:13201

    Article  CAS  PubMed  Google Scholar 

  19. Přech J, Čejka J (2016) Catal Today 277:2

    Article  Google Scholar 

  20. Tang B, Dai WL, Sun XM, Guan NJ, Li LD, Hunger M (2014) Green Chem 16:2281

    Article  CAS  Google Scholar 

  21. Shi CF, Zhu B, Lin M, Long J (2009) Catal Lett 133:70

    Article  CAS  Google Scholar 

  22. Wang WW, Xue K, Pan P, Duan JH (2019) Microporous Mesoporous Mater 277:163

    Article  CAS  Google Scholar 

  23. Peng HG, Wang DR, Xu L, Wu P (2013) Chin J Catal 34:2057

    Article  CAS  Google Scholar 

  24. Zou HB, Sun QL, Fan DY, Fu WW, Liu LJ, Wang RW (2015) Catalysts 5:2134

    Article  CAS  Google Scholar 

  25. Liu XW, Gao F, Xu J, Zhou LH, Liu HL, Hu J (2016) Microporous Mesoporous Mater 222:113

    Article  CAS  Google Scholar 

  26. Ren YY, Yang XJ, Li LL, Li CL, Zhang XH, Lu ZM, Yu XF (2020) Catal Lett 150:3415

    Article  CAS  Google Scholar 

  27. Song ZN, Yuan JC, Cai ZP, Lin D, Feng X, Sheng N, Liu YB, Chen XB, Jin X, Chen D, Yang CH (2020) Green Energy Environ 5:473

    Article  Google Scholar 

  28. Lv GJ, Wang T, Chen Y, Wang JZ, Zou XY, Lu J, Wang FM, Zhang XB, Zhai Y (2022) Colloids Surf A 633:127842

    Article  CAS  Google Scholar 

  29. Feng X, Duan XZ, Yang J, Qian G, Zhou XG, Chen D, Yuan WK (2015) Chem Eng J 278:234

    Article  CAS  Google Scholar 

  30. Hong YL, Ke LT, Li ZH, Huang JL, Zhan GW, Zhou Y, Sun DH, Zhang JL, Li QB (2020) Catal Lett 150:1798

    Article  CAS  Google Scholar 

  31. Khomane RB, Kulkarni BZ, Paraskar A, Sainkar SR (2002) Mater Chem Phys 76:99

    Article  CAS  Google Scholar 

  32. Xu L, Ren YJ, Wu HH, Liu YM, Wang ZD, Zhang YT, Xu JJ, Peng HG, Wu P (2011) J Mater Chem 21:10852

    Article  CAS  Google Scholar 

  33. Ricchiardi G, Damin A, Bordiga S, Lamberti C, Spanò G, Rivetti F, Zecchina A (2001) J Am Chem Soc 123:11409

    Article  CAS  PubMed  Google Scholar 

  34. Zhang FZ, Guo XW, Wang XS, Li G, Zhou JC, Yu JQ, Li C (2001) Catal Lett 72:235

    Article  CAS  Google Scholar 

  35. Sasaki M, Sato Y, Tsuboi Y, Inagaki S, Kubota Y (2014) ACS Catal 4:2653

    Article  CAS  Google Scholar 

  36. Liu M, Chang ZH, Wei HJ, Li BJ, Wang XY, Wen YQ (2016) Appl Catal A 525:59

    Article  CAS  Google Scholar 

  37. Zhang XD, Ke Y, Rao RZ, Chen JF, Liu Q, Yang Y, Bi FK, Wang YX, Xu JC, Liu N (2022) Appl Catal B 310:121300

    Article  CAS  Google Scholar 

  38. Niu QT, Liu GD, Lv ZG, Si CD, Han H, Jin MM (2021) Mol Catal 504:111465

    Article  CAS  Google Scholar 

  39. Yang XL, Dai WL, Gao RH, Fan KN (2007) J Catal 249:278

    Article  CAS  Google Scholar 

  40. Morlanés N, Notestein JM (2010) J Catal 275:191

    Article  Google Scholar 

  41. Maksimchuk NV, Lee JS, Solovyeva MV, Cho KH, Shmakov AN, Chesalov YA, Chang JS, Kholdeeva OA (2019) ACS Catal 9:9699

    Article  CAS  Google Scholar 

  42. Shen XH, Wang JJ, Liu MQ, Li MZ, Lu JJ (2019) Catal Lett 149:2586

    Article  CAS  Google Scholar 

  43. Jin MM, Wang JK, Wang B, Guo ZM, Lv ZG (2019) Microporous Mesoporous Mater 277:84

    Article  CAS  Google Scholar 

  44. Yang HQ, Zhang L, Wang P, Yang QH, Li C (2009) Green Chem 11:257

    Article  CAS  Google Scholar 

  45. Dai J, Zhong WZ, Yi WJ, Liu MQ, Mao LQ, Xu Q, Yin DL (2016) Appl Catal B 192:325

    Article  CAS  Google Scholar 

  46. Groen JC, Bach T, Ziese U, Donk AMPV, Jong KPD, Moulijn JA, Ramírez JP (2005) J Am Chem Soc 127:10792

    Article  CAS  PubMed  Google Scholar 

  47. Maheswari R, Pachamuthu MP, Ramanathan A, Subramaniam B (2014) Ind Eng Chem Res 53:18833

    Article  CAS  Google Scholar 

  48. Hulea V, Dumitriu E, Patcas F, Ropot R, Graffin P, Moreau P (1998) Appl Catal A 170:169

    Article  CAS  Google Scholar 

  49. Jiao Y, Adedigba AL, He Q, Miedziak P, Brett G, Dummer NF, Perdjon M, Liu J, Hutchings GJ (2018) Catal Sci Technol 8:2211

    Article  CAS  Google Scholar 

  50. Xiong G, Cao YY, Guo ZD, Jia QY, Tian FP, Liu LP (2016) Phys Chem Chem Phys 18:190

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This work was supported by grants from National College Student Innovation and Entrepreneurship Training Program [S202010454001]; Natural Science foundation of Shandong Province [ZR2021QB145, ZR2020QB025, ZR2020ME104]; National Natural Science Foundation of China [NSFC21376128]; Natural Science Foundation of Shandong Province, China. Young Innovative Talents Introduction & Cultivation Program for Colleges and Universities of Shandong Province: Innovative Research Team on Optoelectronic Functional Materials.

Author information

Author notes

  1. Jiayin Wang and Qingtao Niu contributed equally to this work.

Authors and Affiliations

  1. School of Chemistry, Chemical Engineering and Materials, Jining University, No.1 Xingtan Road, Qufu, 273155, China

    Jiayin Wang, Qingtao Niu, Guodong Liu, Chongdian Si, Hong Han & Manman Jin

  2. State Key Laboratory Base for Eco-Chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, No.53 Zhengzhou Road, Qingdao, 266042, China

    Zhiguo Lv

  3. Jining New Material Industrial Park, Jining, 272000, China

    Qiuyuan Liu

Authors
  1. Jiayin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qingtao Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guodong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chongdian Si
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zhiguo Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hong Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Qiuyuan Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Manman Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Qingtao Niu or Manman Jin.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 365 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, J., Niu, Q., Liu, G. et al. Engineering Dandelion-Like Hollow TS-1@SiO2: Structural Design and Oxidation Application. Catal Lett 153, 770–778 (2023). https://doi.org/10.1007/s10562-022-04005-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-022-04005-3

Keywords

Search

Navigation