Abstract
The differences in Nikolsky’s ion exchange theory and Baucke’s dissociation mechanism of the glass electrode are analyzed and evaluated.
Similar content being viewed by others
Notes
I give the equations here with the symbols used by Nikolsky, despite the fact that ψ is not the correct symbol for the Galvani potential difference.
Equation 5 is wrong in the original publication of Nikolsky as the denominator RT is missing. This error has been corrected by Nikolsky in: Acta Physicochimica U. R. S. S. (1937) vol. 7, No 4, 597–610.
References
Baucke FGK (2010) Fundamental and applied electrochemistry at an industrial glass laboratory? An overview. J Solid State Electrochem. doi:10.1007/s10008-010-1123-8
Belyustin AA (2010) The centenary of glass electrode: from Max Cremer to F. G. K. Baucke. J Solid State Electrochem. doi:10.1007/s10008-010-1105-x
Bobacka J, Ivaska A, Lewenstam A (2008) Chem Rev 108:329–351
Sokalski T, Lingenfelter P, Lewenstam A (2001) J Phys Chem B 107:2443–2452
Nikolsky BP (1937) Zh Fiz Khim 10:495–503
Belyustin AA, Belinskaya FA (eds) Akademik B. P. Nikol’skiy. Zhizn’. Trudy. Shkola. Izd S.-Peterburgskogo universiteta (in Russian)
Baucke FGK (1974) J Non-Cryst Solids 14:13–31
Baucke FGK (1975) J Non-Cryst Solids 19:75–86
Bach H, Baucke F, Krause D (eds) (2001) Electrochemistry of glasses and glass melts, including glass electrodes. Springer, Berlin
Baucke FGK (1994) Fresenius J Anal Chem 349:582–596
Baucke FGK (1996) Ber Bunsenges Phys Chem 100:1466–1474
Baucke FGK (2001) Phys Chem Glasses 42:220–225
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Scholz, F. Nikolsky’s ion exchange theory versus Baucke’s dissociation mechanism of the glass electrode. J Solid State Electrochem 15, 67–68 (2011). https://doi.org/10.1007/s10008-010-1163-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-010-1163-0