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Nikolsky’s ion exchange theory versus Baucke’s dissociation mechanism of the glass electrode

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Abstract

The differences in Nikolsky’s ion exchange theory and Baucke’s dissociation mechanism of the glass electrode are analyzed and evaluated.

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Notes

  1. I give the equations here with the symbols used by Nikolsky, despite the fact that ψ is not the correct symbol for the Galvani potential difference.

  2. Equation 5 is wrong in the original publication of Nikolsky as the denominator RT is missing. This error has been corrected by Nikolsky in: Acta Physicochimica U. R. S. S. (1937) vol. 7, No 4, 597–610.

References

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Authors and Affiliations

  1. Institut für Biochemie, Universität Greifswald, Felix-Hausdorff-Straße 4, 17487, Greifswald, Germany

    Fritz Scholz

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  1. Fritz Scholz
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Correspondence to Fritz Scholz.

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Scholz, F. Nikolsky’s ion exchange theory versus Baucke’s dissociation mechanism of the glass electrode. J Solid State Electrochem 15, 67–68 (2011). https://doi.org/10.1007/s10008-010-1163-0

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  • DOI: https://doi.org/10.1007/s10008-010-1163-0

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